2-t-butoxyadamantane | 53561-89-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-t-butoxyadamantane
• 英文别名: 2-t.-Butoxyadamantan；2-[(2-Methylpropan-2-yl)oxy]adamantane
• CAS: 53561-89-0
• 化学式: C₁₄H₂₄O
• 分子量: 208.344
• InChiKey: GVWMXCORNGGGHA-UHFFFAOYSA-N

物化性质

• 沸点：
  258.1±8.0 °C(Predicted)
• 密度：
  0.97±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  4.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-金刚烷醇 、 异丁烯 在 硫酸 作用下， 以 二氯甲烷 为溶剂， 反应 12.0h， 生成 2-t-butoxyadamantane
  参考文献：
  名称：

  Beckwith,A.L.J. et al., Australian Journal of Chemistry, 1974, vol. 27, p. 1693 - 1710

  摘要：

  DOI：

文献信息

• Dimensiosolvatic Effects. III. Quantification of Dimensiosolvatic Effects by Solvolyses of 2-Bromoadamantane in Water–Alcohol Mixtures
  作者：Michinori Oki、Hiroshi Ikeda、Shinji Toyota

  DOI：10.1246/bcsj.71.749

  日期：1998.3

  Solvolyses of 2-bromoadamantane in aqueous alcohols were carried out to find the selectivities, kether/kalcohol, at various concentrations of water in an alcohol and at various temperatures. While the observed ratios contain a large error or fluctuate at low concentrations of water, they were almost constant for 1.0 : 0.8 alcohol/water mixtures. The selectivity was also independent of temperatures of the reaction. The significance of the selectivity, which is determined by the ease of solvent intervention into contact ion pairs, is discussed. D values, which are obtained by taking reciprocals of the selectivity for the 1.0 : 0.8 mixture, are proposed as a measure of the dimensiosolvatic effects when a solvent molecule intervenes into the contact ion pair.

  在水性醇中进行2-溴金刚烷的溶剂分解，以发现在醇中不同浓度的水和不同温度下的选择性，酮/醇。虽然观察到的比率在低浓度水下存在较大误差或波动，但对于 1.0:0.8 的酒精/水混合物，它们几乎保持不变。选择性也与反应温度无关。讨论了选择性的重要性，选择性是由溶剂介入接触离子对的难易程度决定的。 D 值是通过取 1.0:0.8 混合物的选择性倒数获得的，建议作为溶剂分子介入接触离子对时维度溶剂化效应的量度。
• CALIXRESORCINARENE COMPOUND, PHOTORESIST BASE COMPRISING THE SAME, AND COMPOSITION THEREOF
  申请人：Watanabe, Takeo

  公开号：EP1886989A1

  公开（公告）日：2008-02-13

  A calixresorcinarene compound represented by the following formula (1): wherein eight Rs are n (n is an integer of 1 to 7) substituents that are one or more types of substituents selected from groups represented by the following formula (2), and m (m is an integer shown by 8-n) hydrogen atoms; and R's, which may be the same or different, are each a straight-chain aliphatic hydrocarbon group having 2 to 12 carbon atoms, a branched aliphatic hydrocarbon group having 3 to 12 carbon atoms, a phenyl group, a p-phenylphenyl group, a p-tert-butylphenyl group, and an aromatic group represented by the following formula (3), or a substituent formed by combining two or more of these substituents: wherein R" is a hydrogen atom or a substituent selected from the substituents represented by the formula (2).

  以下是一个由下式（1）表示的calixresorcinarene化合物： 其中，八个Rs是n（n是1到7的整数）取代基，是从以下式（2）所代表的基团中选择的一种或多种类型的取代基，m（m是8-n所示的整数）个氢原子；而R'可以相同也可以不同，每个都是具有2到12个碳原子的直链脂肪烃基，具有3到12个碳原子的支链脂肪烃基，苯基，p-苯基苯基，p-叔丁基苯基和由以下式（3）所代表的芳基或两个或更多这些取代基组合形成的取代基： 其中，R"是氢原子或从式（2）所代表的取代基中选择的取代基。
• Solvolysis of 2-adamantyl trifluoromethanesulfonate: a YOTf scale
  作者：Dennis N. Kevill、Steven W. Anderson

  DOI：10.1021/jo00218a017

  日期：1985.9
• Beckwith,A.L.J. et al., Australian Journal of Chemistry, 1974, vol. 27, p. 1693 - 1710
  作者：Beckwith,A.L.J. et al.

  DOI：——

  日期：——