2-phenylacridine | 5949-65-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2-phenylacridine
• 英文别名: 2-Phenyl-acridin；o-Phenylacridin
• CAS: 5949-65-5
• 化学式: C₁₉H₁₃N
• 分子量: 255.319
• InChiKey: PIXOMBPMAWPFKV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  20
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  Cyclohexanone-2-carbaldehyde 在 selenium 、 乙醇 、 zinc(II) chloride 作用下， 生成 2-phenylacridine
  参考文献：
  名称：

  147.杂环化合物的新合成。第一部分。2：3-二烷基喹啉

  摘要：

  DOI：

  10.1039/jr9420000693

文献信息

• Cu-Catalyzed Cascade Reaction of Isoxazoles with Diaryliodonium Salts for the Synthesis of Acridines
  作者：Shangrong Zhu、Xuechen Lu、Qiuneng Xu、Jian Li、Shenghu Yan

  DOI：10.2174/1570178617666200225125427

  日期：2020.12.8

  A straightforward and efficient synthesis of acridine derivatives via a copper-catalyzed cascade reaction among isoxazoles and diaryliodonium salts is achieved. Various mono-, multi-substituted and 9-substituted acridine derivatives could be obtained in moderate to good yields. The process has gone through tandem double arylation and Friedel-Crafts reactions.

  通过异恶唑和二芳基碘鎓盐之间的铜催化的级联反应，可以直接有效地合成a啶衍生物。可以以中等至良好的产率获得各种单，多取代和9-取代的cr啶衍生物。该过程经历了串联双芳基化和Friedel-Crafts反应。
• Synthesis of acridines <i>via</i> copper-catalyzed amination/annulation cascades between arylboronic acids and anthranils
  作者：Yuge Li、Liang Xu、Yu Wei

  DOI：10.1039/d2ob01705a

  日期：——

  Copper-catalyzed tandem cyclization reactions between arylboronic acids and anthranils have been established, providing new approaches for one-pot assembly of azacycle acridines. This one-pot protocol features simple operation, precious-metal-free conditions and good functional group compatibility, thus providing an efficient approach for the synthesis of a variety of acridines in moderate to good

  已经建立了铜催化的芳基硼酸和邻氨基苯甲酸之间的串联环化反应，为氮杂环吖啶的一锅法组装提供了新途径。该一锅法操作简单，无贵金属条件，官能团相容性好，为多种吖啶的中等收率合成提供了一种有效途径。
• Quinizarin compound, method for production thereof, and use therefor
  申请人：NIPPON SHOKUBAI CO., LTD.

  公开号：EP0661350A1

  公开（公告）日：1995-07-05

  This invention is to provide a novel quinizarin compound which has a quinizarin structure represented by a following formula (1) having one to four of the 5, 6, 7, and 8 positions and at least either the 6 or 7 position formed of at least one member selected from the class consisting of secondary amino groups, alkylthio groups, and optionally substituted phenylthio groups, and having the remaining positions thereof formed of at least one member selected from the class consisting of hydrogen atom, halogen atoms, amino group, hydroxy group, alkoxy groups, and optionally substituted phenoxy groups, a method for the produciton thereof, and a dye, an electrophotographic grade color toner composition, a thermal-transfer recording sheet, an optical recording medium, an ink jet grade ink composition and a color filter severally comprising the quinizarin compound.

  本发明旨在提供一种新型喹嗪啉化合物，该化合物具有下式(1)所代表的喹嗪啉结构，其5、6、7和8位中的一至四个位以及至少6或7位上的至少一个位由选自仲氨基、烷硫基和任选取代的苯硫基组成的类别中的至少一个成员构成、其剩余位置由至少一个选自氢原子、卤素原子、氨基、羟基、烷氧基和任选取代的苯氧基组成的类别的成员构成；其生产方法；以及包含该喹吖啶化合物的染料、电子照相级彩色调色剂组合物、热转印记录片、光学记录介质、喷墨级墨水组合物和彩色滤光片。
• US5608091A
  申请人：——

  公开号：US5608091A

  公开（公告）日：1997-03-04
• US5817843A
  申请人：——

  公开号：US5817843A

  公开（公告）日：1998-10-06