di(n-propyl)gallium chloride | 55681-97-5

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: di(n-propyl)gallium chloride
• 英文别名: dipropylgallium chloride；Chloro(dipropyl)gallane
• CAS: 55681-97-5
• 化学式: C₆H₁₄ClGa
• 分子量: 191.353
• InChiKey: AQXDPNBKLHZHHT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.04
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  di(n-propyl)gallium chloride 在 air 作用下， 以 neat (no solvent) 为溶剂， 生成 gallium(III) oxide
  参考文献：
  名称：

  摘要：

  The thermal decomposition of dipropylaluminum, dipropylgallium, and dipropylindium chlorides was investigated by thermal analysis, The growth kinetics of oxide films on silicon and gallium arsenide were studied, using dipropylaluminum, dipropylgallium, and dipropylindium chlorides: propylaluminum and propylgallium dichlorides ethylaluminum dichloride; and diethylaluminum and diethylindium chlorides as metalorganic precursors, The resultant films were characterized by IR and x-ray spectroscopics and electrical measurements.

  DOI：

  10.1023/a:1015454518259

文献信息

• The reactions of dialkylgallium hydrides with tert-butylethynylbenzenes—a systematic investigation into the course of hydrogallation reactions
  作者：Werner Uhl、Michael Claesener、Sima Haddadpour、Beate Jasper、Alexander Hepp

  DOI：10.1039/b614003c

  日期：——

  the formation of one-dimensional coordination polymers. In contrast secondary reactions with the release of the corresponding trialkylgallium derivatives GaR(3) (R = Et, nPr, iPr, CH(2)tBu, tBu) were observed for all hydrogallation reactions involving the trisalkyne 1,3,5-tris(tert-butylethynyl)benzene. A similar reaction was observed upon treatment of the 1,4-bisalkyne with a dialkylgallium hydride

  双和三（叔丁基乙炔基）苯与氢化二烷基镓的反应可提供两种不同类型的产物。1,4-二（叔丁基乙炔基）苯和二烷基氢化镓R（2）GaH带有相对较小的取代基（R = Et，nPr）得到预期的加成产物，每个C三键C三键插入Ga-H键。完整的GaR（2）基团连接到苯环的α位上的碳原子上，并且分子间的Ga-C相互作用导致形成一维配位聚合物。相比之下，对于涉及三炔1,3,5-三（所有）的加氢加氢反应，观察到具有相应三烷基镓衍生物GaR（3）（R = Et，nPr，iPr，CH（2）tBu，tBu）释放的二级反应。叔丁基乙炔基）苯。用带有相对大取代基的氢化二烷基镓处理1，4-双炔烃时，观察到类似的反应（R =新戊基）。在所有这些情况下，形成环烷型分子，两个苯环之间的桥连位置带有两个或三个镓原子。
• Novel intramolecularly stabilized organogallium and organoindium compounds and their use in MOVPE
  作者：Herbert Schumann、Uwe Hartmann、Wilfried Wassermann

  DOI：10.1016/s0277-5387(00)80590-2

  日期：1990.1
• Schumann, Herbert; Hartmann, Uwe; Wassermann, Wilfried, Chemische Berichte, 1990, vol. 123, p. 2093 - 2100
  作者：Schumann, Herbert、Hartmann, Uwe、Wassermann, Wilfried、Dietrich, Andreas、Goerlitz, Frank H.、et al.

  DOI：——

  日期：——
• SCHUMANN, HERBERT;HARTMANN, UWE;WASSERMANN, WILFRIED, POLYHEDRON, 9,(1990) N-3, C. 253-360
  作者：SCHUMANN, HERBERT、HARTMANN, UWE、WASSERMANN, WILFRIED

  DOI：——

  日期：——
• ——
  作者：O. N. Mittov、N. I. Ponomareva、I. Ya. Mittova

  DOI：10.1023/a:1015454518259

  日期：——

  The thermal decomposition of dipropylaluminum, dipropylgallium, and dipropylindium chlorides was investigated by thermal analysis, The growth kinetics of oxide films on silicon and gallium arsenide were studied, using dipropylaluminum, dipropylgallium, and dipropylindium chlorides: propylaluminum and propylgallium dichlorides ethylaluminum dichloride; and diethylaluminum and diethylindium chlorides as metalorganic precursors, The resultant films were characterized by IR and x-ray spectroscopics and electrical measurements.