bis(quinoline-8-yl)mercury | 33327-55-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: bis(quinoline-8-yl)mercury
• 英文别名: Di-[8]chinolyl-quecksilber；bis(8-quinolyl)mercury；di-[8]quinolyl-mercury
• CAS: 33327-55-8
• 化学式: C₁₈H₁₂HgN₂
• 分子量: 456.897
• InChiKey: OXCOBQLARHRGHM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.82
• 重原子数：
  21
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  tetrakis(acetonitrile)copper(I) perchlorate 、 bis(quinoline-8-yl)mercury 以 四氢呋喃 为溶剂， 反应 1.0h， 以71%的产率得到[(quinoline-8-yl)₂Hg·Cu]·ClO₄
  参考文献：
  名称：

  亲金属相互作用：观察到封闭壳（d10d10，d10d8，d8d8）金属离子之间最短的亲金属相互作用[MM'M = Hg（ii）和Pd（ii）且M'= Cu（i），Ag（i），Au（ i）和Pd（ii）]。

  摘要：

  两当量的8-硫代喹啉（C 6 H 6 NLi）与HgBr 2的盐复分解反应得到双（喹啉-8-基）汞[（C 6 H 6 N）2 Hg]。双（喹啉-8-基）汞已用于合成一系列[（C 6 H 6 N）2 M·M']·X - n [M = Hg; {M'=铜，X - = CLO 4 ; X =我; X - = CF 3 SO 3 }，{M'=银，X - = CLO 4 ; X − = CF 3SO 3 ; X - = BF 4 }，{M'=金，X - = CF 3 SO 3 }; {M'=钯，X - = CF 3 CO 2 }]，[M = PD; M'=钯，X - = CF 3 CO 2 ; n = 2]。所有配合物均通过多核NMR（1 H，13 C，19 F，11 B，199Hg）光谱分析。它们的结构通过单晶X射线衍射研究确定，显示出最短的Hg⋯M'（M'= Cu，Ag，Au，Pd）嗜金属相互作

  DOI：

  10.1039/d0dt01008a
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 sodium thiosulfate 作用下， 生成 bis(quinoline-8-yl)mercury
  参考文献：
  名称：

  Ukai, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1928, vol. 48, p. 172

  摘要：

  DOI：

文献信息

• Preparation of RHgCl via transmetalation of (8-quinolyl)SnMe₃and redistribution to R₂Hg (R = 8-quinolyl): a highly distorted diorganomercury(<scp>ii</scp>) with 84 degree C–Hg–C angle
  作者：Sem Raj Tamang、Jung-Ho Son、James D. Hoefelmeyer

  DOI：10.1039/c4dt00384e

  日期：——

  Transmetalation occurs upon addition of HgCl2 to (8-quinolyl)SnMe3 to yield (8-quinolyl)HgCl. The molecule features a frustrated Hg–N Lewis pair; however the mercury(II) center showed low affinity for sulfur Lewis bases, S8 or thiophene. In the presence of NH4SCN, ligand redistribution led to R2Hg. The molecule was found as linear or bent polymorphs, depending on the solvent of recrystallization. The geometry about Hg(II) in the bent polymorph is distorted trigonal prismatic that features a C–Hg–C angle of 84°, weak intramolecular Hg–N contacts, and two intermolecular η2-quinoline contacts in which the neighboring R2Hg molecule participates as a bis-η2-bidentate ligand.

  在将HgCl2添加到(8-喹啉基)SnMe3中时会发生过渡金属化反应，生成(8-喹啉基)HgCl。该分子具有惰性Hg-N路易斯对；然而，汞(II)中心对硫路易斯碱、S8或噻吩的亲和力较低。在NH4SCN的存在下，配体的重新分布导致R2Hg的形成。根据重结晶溶剂的不同，该分子可以呈线性或弯曲多晶型。弯曲多晶型中Hg(II)的几何结构是扭曲的三棱柱，其C-Hg-C角为84°，分子内Hg-N接触较弱，分子间存在两个η2-喹啉接触，相邻的R2Hg分子作为双η2-双齿配体参与其中。
• Osmium complexes containing either chelating or non-chelating 8-quinolyl ligands
  作者：Alex M. Clark、Clifton E.F. Rickard、Warren R. Roper、L. James Wright

  DOI：10.1016/s0022-328x(97)00409-9

  日期：1997.1

  The reaction of Qn(2)Hg (Qn = 8-quinolyl) with OsHCl(CO)(PPh(3))(3) gives Os(eta(2)-Qn)Cl(CO)(PPh(3))(2) (1), in which the 8-quinolyl ligand binds through both N and C-8 forming a 4-membered chelate ring. Reaction of 1 with AgPF(6) to remove chloride, followed by addition of either NaI or NaS(2)CNMe(2), gives the neutral compounds Os(eta(2)-Qn)I(CO)(PPh(3))(2) (2) or Os(eta(1)-Qn)(eta(2)-S(2)CNMe(2))(CO)(PPh(3))(2) (3), respectively, while reaction with AgPF(6) followed by CO gives [Os(eta(2)-Qn)(CO)(2)(PPh(3))(2)](+)PF(6)(-) (4). Single crystal X-ray structures of 2 and 3 have been determined. In 2, the 8-quinolyl ligand is chelated through C-8 and N, but in 3 it is coordinated only through C-8. (C) 1997 Elsevier Science S.A.
• Metallophilic interactions: observations of the shortest metallophilicinteractions between closed shell (d¹⁰⋯d¹⁰, d¹⁰⋯d⁸, d⁸⋯d⁸) metal ions [M⋯M′ M = Hg(<scp>ii</scp>) and Pd(<scp>ii</scp>) and M′ = Cu(<scp>i</scp>), Ag(<scp>i</scp>), Au(<scp>i</scp>), and Pd(<scp>ii</scp>)]
  作者：Saravanan Raju、Harkesh B. Singh、Ray J. Butcher

  DOI：10.1039/d0dt01008a

  日期：——

  [M = Pd; M′ = Pd, X− = CF3CO2; n = 2]. All the complexes were well characterized by multinuclear NMR (1H, 13C, 19F, 11B, 199Hg) spectroscopic analysis. Their structures were determined by single crystal X-ray diffraction studies, which displayed the shortest Hg⋯M′ (M′ = Cu, Ag, Au, Pd) metallophilic interactions. The electronic properties of the molecular structures were determined by DFT calculations

  两当量的8-硫代喹啉（C 6 H 6 NLi）与HgBr 2的盐复分解反应得到双（喹啉-8-基）汞[（C 6 H 6 N）2 Hg]。双（喹啉-8-基）汞已用于合成一系列[（C 6 H 6 N）2 M·M']·X - n [M = Hg; M'=铜，X - = CLO 4 ; X =我; X - = CF 3 SO 3 }，M'=银，X - = CLO 4 ; X − = CF 3SO 3 ; X - = BF 4 }，M'=金，X - = CF 3 SO 3 }; M'=钯，X - = CF 3 CO 2 }]，[M = PD; M'=钯，X - = CF 3 CO 2 ; n = 2]。所有配合物均通过多核NMR（1 H，13 C，19 F，11 B，199Hg）光谱分析。它们的结构通过单晶X射线衍射研究确定，显示出最短的Hg⋯M'（M'= Cu，Ag，Au，Pd）嗜金属相互作
• Ukai, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1928, vol. 48, p. 172
  作者：Ukai

  DOI：——

  日期：——