7-ethoxy-oxepan-2-one | 170438-05-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 7-ethoxy-oxepan-2-one
• 英文别名: 7-Aethoxy-oxepan-2-on；7-Ethoxyoxepan-2-one
• CAS: 170438-05-8
• 化学式: C₈H₁₄O₃
• 分子量: 158.197
• InChiKey: GFLVKWZWBMSCLW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  甲醇 、 7-ethoxy-oxepan-2-one 在 盐酸 作用下， 反应 3.0h， 生成 6,6-dimethoxyhexanoic acid
  参考文献：
  名称：

  镍(II)配合物催化α-烷氧基环酮与分子氧氧化制备缩醛羧酸的简便方法

  摘要：

  在催化量的镍(II)配合物存在下，各种α-烷氧基环酮在常温常压下，通过分子氧和醛的联合使用，顺利氧化成缩醛内酯。用醇中的氯化氢连续处理形成的缩醛内酯，以良好到定量的产率提供相应的缩醛羧酸。

  DOI：

  10.1246/cl.1994.535
• 作为产物：
  描述：

  2-乙氧基环己酮 在 Ni(dmp)2 、 氧气 、 异戊醛 作用下， 以 1,2-二氯乙烷 为溶剂， 生成 7-ethoxy-oxepan-2-one
  参考文献：
  名称：

  镍(II)配合物催化α-烷氧基环酮与分子氧氧化制备缩醛羧酸的简便方法

  摘要：

  在催化量的镍(II)配合物存在下，各种α-烷氧基环酮在常温常压下，通过分子氧和醛的联合使用，顺利氧化成缩醛内酯。用醇中的氯化氢连续处理形成的缩醛内酯，以良好到定量的产率提供相应的缩醛羧酸。

  DOI：

  10.1246/cl.1994.535

文献信息

• Chip resistant coating composition II
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0230774A1

  公开（公告）日：1987-08-05

  A hydroxy functional urethane modified polyester resin and solvent-based thermosetting coating composition comprising said resin and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction nixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.

  一种羟基功能脲改性聚酯树脂和基于溶剂的热固性涂料组合物，包括所述树脂和阻化聚异氰酸酯交联剂。该涂料组合物可以制成热喷涂，高固含量的涂料组合物，适用于用作防石击的汽车车身底漆，适用于车身板件易受石头、碎石和其他路面碎片破损的区域。或者，该组合物可以制成高固含量的涂料组合物，可用常规喷涂设备进行喷涂。羟基功能脲改性聚酯树脂是在含有羟基的脲改性聚酯前体的存在下，通过内酯单体的聚合反应制得。聚合反应混合物包括约10至80重量％的含羟基的脲改性聚酯前体和约90至20重量％的内酯单体。
• Chip resistant coating composition III
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0271972A2

  公开（公告）日：1988-06-22

  This invention is directed to thermosetting coating compositions comprising hydroxy functional urethane modified polyester resin, blocked polyisocyanate crosslinking agent, diol modified blocked diisocyanate and polyamine having at least two amine groups selected from primary and secondary amine groups. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor (i) having a number average molecular weight ( Mn) between about 1,000 and about 10,000, (ii) having a hydroxy number between about 30 and about 300, and (iii) containing between about 1 and about 10 urethane groups per molecule.

  本发明涉及热固性涂料组合物，包括羟基官能聚氨酯改性聚酯树脂、封端多异氰酸酯交联剂、二元醇改性封端二异氰酸酯和至少有两个胺基团的聚胺，胺基团选自伯胺和仲胺。羟基官能聚氨酯改性聚酯树脂是内酯单体在以下含羟基聚氨酯改性聚酯前体存在下聚合的产物：(i) 平均分子量（Mn）在约 1,000 到约 10,000 之间；(ii) 羟基数在约 30 到约 300 之间；(iii) 每个分子含有约 1 到约 10 个聚氨酯基团。
• Solid solution
  申请人：CANON KABUSHIKI KAISHA

  公开号：EP0308852A2

  公开（公告）日：1989-03-29

  An organic guest compound having both an electron attractive group and an electron donative group is blended with a host polymer selected from a lactone polymer and a copolymer nylon to form a solid solution. The solid solution shows good mechanical strength and processability and may be suitably formed into a nonlinear optical device. Even if the guest compound is a compound, such as p-nitroaniline, which has a large non-linearity but is by itself liable to form a centrosymmetrical crystal thus showing no SHG activity, the solid solution obtained by blending it with the host polymer can show a uniform and large SHG activity.

  将同时具有引电子基团和供电子基团的有机客体化合物与选自内酯聚合物和共聚尼龙的主聚合物混合，形成固溶体。该固溶体具有良好的机械强度和加工性能，可适当地制成非线性光学器件。即使客体化合物是一种化合物，例如对硝基苯胺，它具有很大的非线性，但其本身容易形成中心对称晶体，因而不显示 SHG 活性，但将其与主聚合物混合后得到的固溶体可以显示出均匀而大的 SHG 活性。
• Bulk process for producing cyclic ester-modified polymers without use of catalyst
  申请人：S.C. JOHNSON & SON, INC.

  公开号：EP0339477A2

  公开（公告）日：1989-11-02

  The present invention provides for a bulk process for the formation of hydroxyl or carboxylic acid containing polymeric compositions characterized by the reaction of a hydroxyl or carboxylic acid group containing ethylenic polymer with a cyclic ester in the absence of a solvent or catalyst. The compositions have enhanced film-forming characteristics including flexibility, resistance to corrosion, and the like.

  本发明提供了一种用于形成含羟基或羧酸聚合物组合物的散装工艺，其特征在于含羟基或羧酸基团的乙烯聚合物与环酯在无溶剂或催化剂的情况下发生反应。这种组合物具有更强的成膜特性，包括柔韧性、抗腐蚀性等。
• Catalyzed bulk process for producing cyclic ester-modified acrylic polymers
  申请人：S.C. JOHNSON & SON, INC.

  公开号：EP0339472A2

  公开（公告）日：1989-11-02

  The present invention provides for a bulk process for the formation of hydroxyl or carboxylic acid containing polymeric compositions characterized by the reaction of a hydroxyl or carboxylic acid group containing ethylenic polymer with a cyclic ester in the absence of a solvent or catalyst. The compositions have enhanced film-forming characteristics including flexibility, resistance to corrosion, and the like.

  本发明提供了一种用于形成含羟基或羧酸聚合物组合物的散装工艺，其特征在于含羟基或羧酸基团的乙烯聚合物与环酯在无溶剂或催化剂的情况下发生反应。这种组合物具有更强的成膜特性，包括柔韧性、抗腐蚀性等。