8-(quinolin-8-ylmethoxy)quinoline | 1374784-16-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 8-(quinolin-8-ylmethoxy)quinoline
• 英文别名: 8-(Quinolin-8-ylmethoxy)quinoline
• CAS: 1374784-16-3
• 化学式: C₁₉H₁₄N₂O
• 分子量: 286.333
• InChiKey: NVUGKCUCPIYIJG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  35
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  trichlorotris(tetrahydrofuran)chromium(III) 、 8-(quinolin-8-ylmethoxy)quinoline 以 二氯甲烷 为溶剂， 以45%的产率得到CrCl3(8-(quinolin-8-ylmethoxy)quinoline)
  参考文献：
  名称：

  Synthesis, structures and ethylene polymerization activity of chromium(III) complexes with N,O,N′-tridentate ligands

  摘要：

  This paper reports the synthesis and characterization of four neutral chromium(III) complexes bearing N,O,N'-tridentate ligands, [LCrCl3], (L = 2-[(2-pyridylmethoxy)methyl]pyridine, 1; L = 8-(2-pyridylmethoxy) quinoline, 2; L = 8-[(2-pyridylmethoxy)methyl]quinoline, 3; L = 8-(quinolin-8-ylmethoxy)quinoline,4). Molecular structures of 1-3 have been determined by X-ray crystallography, which show that L-1 and L-3 exhibit facial configuration in 1 and 3 while L-2 adopts meridional arrangement in 2. The ethylene polymerization experiments show that complexes 1-4 are moderately active precatalysts for ethylene polymerization with activation with MAO. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.02.037
• 作为产物：
  描述：

  8-羟基喹啉 、 8-溴甲基喹啉 在 potassium hydroxide 作用下， 以 乙腈 为溶剂， 反应 5.0h， 以51%的产率得到8-(quinolin-8-ylmethoxy)quinoline
  参考文献：
  名称：

  Synthesis, structures and ethylene polymerization activity of chromium(III) complexes with N,O,N′-tridentate ligands

  摘要：

  This paper reports the synthesis and characterization of four neutral chromium(III) complexes bearing N,O,N'-tridentate ligands, [LCrCl3], (L = 2-[(2-pyridylmethoxy)methyl]pyridine, 1; L = 8-(2-pyridylmethoxy) quinoline, 2; L = 8-[(2-pyridylmethoxy)methyl]quinoline, 3; L = 8-(quinolin-8-ylmethoxy)quinoline,4). Molecular structures of 1-3 have been determined by X-ray crystallography, which show that L-1 and L-3 exhibit facial configuration in 1 and 3 while L-2 adopts meridional arrangement in 2. The ethylene polymerization experiments show that complexes 1-4 are moderately active precatalysts for ethylene polymerization with activation with MAO. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2012.02.037