12-[3-(triethoxysilyl)propyl]-6,9,15,18-tetraoxa-12,25-diazatetracyclo[21.3.1.0(5,26).0(19,24)]heptacosa-1(26),2,4,19,21,23(27),24-heptaene | 1315451-44-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 12-[3-(triethoxysilyl)propyl]-6,9,15,18-tetraoxa-12,25-diazatetracyclo[21.3.1.0(5,26).0(19,24)]heptacosa-1(26),2,4,19,21,23(27),24-heptaene
• 英文别名: Triethoxy-[3-(6,9,15,18-tetraoxa-12,25-diazatetracyclo[21.3.1.05,26.019,24]heptacosa-1(27),2,4,19,21,23,25-heptaen-12-yl)propyl]silane；triethoxy-[3-(6,9,15,18-tetraoxa-12,25-diazatetracyclo[21.3.1.05,26.019,24]heptacosa-1(27),2,4,19,21,23,25-heptaen-12-yl)propyl]silane
• CAS: 1315451-44-5
• 化学式: C₃₀H₄₄N₂O₇Si
• 分子量: 572.774
• InChiKey: TWFRAIBWDBGZRB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.93
• 重原子数：
  40
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  80.7
• 氢给体数：
  0
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  1,11-bis(4-tolylsulphonyloxy)-6-(4-tolylsulphonyl)-3,9-dioxa-6-azaundecane 在 sodium 、 potassium carbonate 、 三乙胺 作用下， 以 丙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 85.0h， 生成 12-[3-(triethoxysilyl)propyl]-6,9,15,18-tetraoxa-12,25-diazatetracyclo[21.3.1.0(5,26).0(19,24)]heptacosa-1(26),2,4,19,21,23(27),24-heptaene
  参考文献：
  名称：

  Synthesis of silica gel-bound acridino-18-crown-6 ether and preliminary studies on its metal ion selectivity

  摘要：

  Starting from commercially available and relatively cheap chemicals a novel silica gel-bound acridino-18-crown-6 ether was prepared. Selectivity of the latter stationary phase toward different metal ions was studied. The stationary phase showed appreciable selectivity for Ag+, Cu2+, and Hg2+ ions. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2011.05.050

文献信息

• Synthesis of silica gel-bound acridino-18-crown-6 ether and preliminary studies on its metal ion selectivity
  作者：Júlia Kertész、Péter Huszthy、Attila Kormos、László Bezúr

  DOI：10.1016/j.tet.2011.05.050

  日期：2011.7

  Starting from commercially available and relatively cheap chemicals a novel silica gel-bound acridino-18-crown-6 ether was prepared. Selectivity of the latter stationary phase toward different metal ions was studied. The stationary phase showed appreciable selectivity for Ag+, Cu2+, and Hg2+ ions. (C) 2011 Elsevier Ltd. All rights reserved.