7-chloroquinoline-3,8-dicarboxylic acid | 90717-07-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7-chloroquinoline-3,8-dicarboxylic acid
• CAS: 90717-07-0
• 化学式: C₁₁H₆ClNO₄
• 分子量: 251.626
• InChiKey: ZYIDIAPHYHJMCU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  17
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  87.5
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  7-chloroquinoline-3,8-dicarboxylic acid 、 氢氟酸 生成 3-trifluoromethyl-7-chloroquinoline-8-carbonyl fluoride
  参考文献：
  名称：

  HAGEN, HELMUT;EICHENAUER, ULRICH;KOHLER, ROLF-DIETER;PLATH, PETER;LIESE, +

  摘要：

  DOI：

文献信息

• Aluminum Metal Organic Framework Materials
  申请人：TEXAS A&M UNIVERSITY SYSTEM

  公开号：US20150152123A1

  公开（公告）日：2015-06-04

  The invention relates to monocrystalline single crystals of metal-organic framework materials comprising at least one aluminium metal ion, processes for preparing the same, methods for employing the same, and the use thereof. The invention also relates to monocrystalline aluminium metal-organic frameworks.

  该发明涉及至少含有一种铝金属离子的金属-有机框架材料的单晶单晶体，以及其制备方法、使用方法和用途。该发明还涉及单晶铝金属-有机框架。
• 2 and/or 3-trifluoromethyl-substituted quinoline 8-carboxylic acid
  申请人：BASF Aktiengesellschaft

  公开号：US04804404A1

  公开（公告）日：1989-02-14

  Fluoroalkyl-substituted quinoline derivatives of the formula ##STR1## where R.sup.1 is chlorine, fluorine, hydroxyl, O.sup..crclbar. Met.sup..sym., C.sub.1 -C.sub.4 -alkoxy or a radical of the formula ##STR2## R.sup.2 and R.sup.3 independently of one another are each hydrogen, C.sub.1 -C.sub.3 -alkyl or C.sub.1 -C.sub.3 -fluoroalkyl, R.sup.4 is fluorine, chlorine or bromine, with the proviso that one or both of the radicals R.sup.2 and R.sup.3 are C.sub.1 -C.sub.3 -fluoroalkyl, herbicides containing these compounds as active ingredients, and their use for controlling unwanted plant growth.

  氟烷基取代的喹啉衍生物的化学式为##STR1##其中R.sup.1为氯、氟、羟基、O.sup..crclbar. Met.sup..sym.、C.sub.1-C.sub.4-烷氧基或化学式##STR2##的基团，R.sup.2和R.sup.3彼此独立地为氢、C.sub.1-C.sub.3-烷基或C.sub.1-C.sub.3-氟烷基，R.sup.4为氟、氯或溴，但要求R.sup.2和R.sup.3中的一个或两个为C.sub.1-C.sub.3-氟烷基，含有这些化合物作为活性成分的除草剂，以及它们用于控制不受欢迎的植物生长。
• [EN] Chromium Metal Organic Frameworks and Synthesis of Metal Organic Frameworks<br/>[FR] STRUCTURES ORGANOMÉTALLIQUES À BASE DE CHROME ET SYNTHÈSE DE STRUCTURES ORGANOMÉTALLIQUES
  申请人：TEXAS A & M UNIV SYS

  公开号：WO2015173553A1

  公开（公告）日：2015-11-19

  The present invention relates to monocrystalline metal organic frameworks comprising chromium ions and carboxylate ligands and the use of the same, for example their use for storing a gas. The invention also relates to methods for preparing metal organic frameworks comprising chromium, titanium or iron ions and carboxylate ligands. The methods of the invention allow such metal organic frameworks to be prepared in monocrystalline or polycrystalline forms.

  本发明涉及含有铬离子和羧酸配体的单晶金属有机框架，以及其用途，例如用于储存气体。该发明还涉及制备含有铬、钛或铁离子和羧酸配体的金属有机框架的方法。本发明的方法允许制备这些金属有机框架以单晶或多晶形式存在。
• [EN] PROCESS FOR THE PREPARATION OF A METAL-ORGANIC COMPOUND<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UN COMPOSÉ ORGANOMÉTALLIQUE
  申请人：UNIV BELFAST

  公开号：WO2014191725A1

  公开（公告）日：2014-12-04

  A process for the preparation of a metal-organic compound, said metal- organic compound comprising at least one metal ion and at least one organic ligand, wherein said organic ligand is capable of associating with said metal ion, comprising at least the steps of; providing a first reactant comprising at least one metal in ionic form; providing a second reactant comprising at least one organic ligand capable of associating with said metal in ionic form; and admixing said first and second reactants under conditions of prolonged and sustained pressure and shear sufficient to synthesise said metal-organic compound.

  一种制备金属有机化合物的方法，所述金属有机化合物包括至少一个金属离子和至少一个有机配体，其中所述有机配体能够与所述金属离子结合，包括至少以下步骤：提供包含至少一种金属的离子形式的第一反应物；提供包含至少一种能够与所述离子形式的金属结合的有机配体的第二反应物；并在持续和持续的压力和剪切条件下混合所述第一和第二反应物，以合成所述金属有机化合物。
• [EN] METHOD OF PREPARING A METAL ORGANIC FRAMEWORK<br/>[FR] PROCÉDÉ DE PRÉPARATION D'UNE STRUCTURE MÉTALLO-ORGANIQUE
  申请人：TEXAS A & M UNIV SYS

  公开号：WO2015177511A1

  公开（公告）日：2015-11-26

  The present invention relates to a method of preparing a metal organic framework comprising metal ions and carboxylate ligands; the method comprises: reacting (i) a source of metal ions, with (ii) a carboxylic acid precursor of a the carboxylate ligands, in an organic solvent consisting of one or more carboxylic acid solvents, at a temperature of about 75°C or greater, optionally in the presence of water. The present invention also relates to the same method for preparing monocrystalline metal organic frameworks as well as the metal organic frameworks obtained from such methods.

  本发明涉及一种制备金属有机框架的方法，包括金属离子和羧酸配体；该方法包括：在一个或多个羧酸溶剂组成的有机溶剂中，将（i）金属离子源与（ii）羧酸前体反应，反应温度为约75°C或更高，可选地在水的存在下。本发明还涉及用于制备单晶金属有机框架的相同方法，以及从这些方法中获得的金属有机框架。