6-t-butoxyhexylcyclopentadiene | 670222-33-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 6-t-butoxyhexylcyclopentadiene
• 英文别名: 1-[6-[(2-Methylpropan-2-yl)oxy]hexyl]cyclopenta-1,3-diene
• CAS: 670222-33-0
• 化学式: C₁₅H₂₆O
• 分子量: 222.371
• InChiKey: HWMIOMALDFHJLL-UHFFFAOYSA-N

物化性质

• 沸点：
  295.3±19.0 °C(Predicted)
• 密度：
  0.891±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  16
• 可旋转键数：
  8
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  6-t-butoxyhexylcyclopentadiene 在 四氢吡咯 作用下， 以 四氢呋喃 、 甲醇 为溶剂， 生成 2-(6-t-butoxyhexylcyclopentadienyl)-2-(fluorenyl)propane
  参考文献：
  名称：

  The effect that 6-tert-butoxyhexyl functionalization has on ethylene polymerization in ansa-zirconocene dichlorides

  摘要：

  New ansa-zirconocene dichloride derivatives have been prepared, which have a 6-t-butoxyhexyl pendant introduced either on a Cp-ring-carbon or at the silicon and carbon ansa-bridging atom. Ethylene polymerization studies have been carried out with novel precatalysts of the type: [(eta(5)-C13H8)-X(t-BuOC6H12)Me-(eta(5)-C5H4)]ZrCl, [X=C [1a], Si [2a]], [(eta(5)-C13H8)-XMe2-(eta(5)-(t-BuOC6H12C5H3))] ZrCl, [X = C [3a], Si [4a]] in the presence of excess methylalumoxane (MAO) to compare their catalytic activity and to delineate the effect of the 6-t-butoxyhexyl functionality on ethylene polymerization. The precatalysts [1a] and [2a] with the bridge functionality showed higher activity in ethylene polymerization than the corresponding complexes [3a] and [4a] which have it on the Cp ring moiety. On the other hand the silyl bridged complexes [2a] and [4a] produced a higher molecular weight polyethylene than the carbon-bridged one, regardless of the location of functional group. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.10.006
• 作为产物：
  描述：

  6-t-butoxyhexyl chloride 、 lithium cyclopentadienylide 以 四氢呋喃 为溶剂， 以83%的产率得到6-t-butoxyhexylcyclopentadiene
  参考文献：
  名称：

  The effect that 6-tert-butoxyhexyl functionalization has on ethylene polymerization in ansa-zirconocene dichlorides

  摘要：

  New ansa-zirconocene dichloride derivatives have been prepared, which have a 6-t-butoxyhexyl pendant introduced either on a Cp-ring-carbon or at the silicon and carbon ansa-bridging atom. Ethylene polymerization studies have been carried out with novel precatalysts of the type: [(eta(5)-C13H8)-X(t-BuOC6H12)Me-(eta(5)-C5H4)]ZrCl, [X=C [1a], Si [2a]], [(eta(5)-C13H8)-XMe2-(eta(5)-(t-BuOC6H12C5H3))] ZrCl, [X = C [3a], Si [4a]] in the presence of excess methylalumoxane (MAO) to compare their catalytic activity and to delineate the effect of the 6-t-butoxyhexyl functionality on ethylene polymerization. The precatalysts [1a] and [2a] with the bridge functionality showed higher activity in ethylene polymerization than the corresponding complexes [3a] and [4a] which have it on the Cp ring moiety. On the other hand the silyl bridged complexes [2a] and [4a] produced a higher molecular weight polyethylene than the carbon-bridged one, regardless of the location of functional group. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2003.10.006

文献信息

• Hybrid supported catalyst system and method of preparing polyolefin using the same
  申请人：LG CHEM, LTD.

  公开号：US10189920B2

  公开（公告）日：2019-01-29

  Provided are a hybrid supported catalyst system and a method of preparing a polyolefin using the same. The hybrid supported catalyst system according to the present invention may be used to perform oligomerization and copolymerization of olefin monomers in a single reactor at the same time with high efficiency without a separate process of preparing alpha-olefin. Therefore, costs for preparing or purchasing comonomers which are expensive raw materials may be reduced, thereby reducing the production cost of a final product.

  本发明提供了一种混合支撑催化剂体系及其制备聚烯烃的方法。根据本发明的混合支撑催化剂体系可在单个反应器中同时高效地进行烯烃单体的寡聚和共聚反应，而无需单独准备α-烯烃的过程。因此，可以减少准备或购买昂贵原材料共聚单体的成本，从而降低最终产品的生产成本。
• METHOD FOR PREPARING POLYOLEFIN
  申请人：LG Chem, Ltd.

  公开号：EP3246343A1

  公开（公告）日：2017-11-22

  The present invention provides a method for preparing a polyolefin having a broad molecular weight distribution. More specifically, the present invention provides a method for preparing a polyolefin having a broad molecular weight distribution and an ultra-high molecular weight in which an organometallic complex containing a specific Ti-Al complex structure is used as a molecular weight controller (i.e., molecular weight enhance) in the polymerization of an olefin monomer, thereby enabling both solution polymerization and slurry polymerization, particularly enabling the molecular weight distribution to be more readily and effectively controlled.

  本发明提供了一种制备具有宽分子量分布的聚烯烃的方法。更具体地说，本发明提供了一种制备具有宽分子量分布和超高分子量的聚烯烃的方法，其中在烯烃单体的聚合过程中，将含有特定钛-铝络合物结构的有机金属络合物用作分子量控制剂（即分子量增强剂），从而实现溶液聚合和浆料聚合，特别是使分子量分布更容易得到有效控制。
• POLYOLEFIN
  申请人：LG CHEM, LTD.

  公开号：EP3812406A1

  公开（公告）日：2021-04-28

  The present invention relates to polyolefin. More specifically, the present invention relates to polyolefin having excellent dart drop impact strength, and exhibiting improved transparency.

  本发明涉及聚烯烃。更具体地说，本发明涉及的聚烯烃具有极佳的落镖冲击强度，并具有更好的透明度。
• Method for preparing polyolefin
  申请人：LG CHEM, LTD.

  公开号：US10870712B2

  公开（公告）日：2020-12-22

  The present invention provides a method for preparing a polyolefin having a broad molecular weight distribution. More specifically, the present invention provides a method for preparing a polyolefin having a broad molecular weight distribution and an ultra-high molecular weight in which an organometallic complex containing a specific Ti—Al complex structure is used as a molecular weight controller (i.e., molecular weight enhance) in the polymerization of an olefin monomer, thereby enabling both solution polymerization and slurry polymerization, particularly enabling the molecular weight distribution to be more readily and effectively controlled.

  本发明提供了一种制备具有宽分子量分布的聚烯烃的方法。更具体地说，本发明提供了一种制备具有宽分子量分布和超高分子量的聚烯烃的方法，其中在烯烃单体的聚合过程中，将含有特定钛-铝络合物结构的有机金属络合物用作分子量控制剂（即分子量增强剂），从而实现溶液聚合和浆料聚合，特别是使分子量分布更容易得到有效控制。
• SUPPORTED HYBRID METALLOCENE CATALYST, METHOD FOR PREPARING THE SAME, AND METHOD FOR PREPARING POLYOLEFIN USING THE SAME
  申请人：LG Chem Ltd.

  公开号：EP1517928B1

  公开（公告）日：2010-11-10