(E)-1-Amino-non-3-en-2-ol | 134486-51-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: (E)-1-Amino-non-3-en-2-ol
• 英文别名: (E)-1-aminonon-3-en-2-ol
• CAS: 134486-51-4
• 化学式: C₉H₁₉NO
• 分子量: 157.256
• InChiKey: NTFFRPXNAZVWHX-VOTSOKGWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.6
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  46.2
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (E)-1-Amino-non-3-en-2-ol 在 三氟化硼乙醚 、 sodium hydride 、 三乙胺 作用下， 以 二氯甲烷 为溶剂， 生成 2-Pentyl-2,5-dihydro-1H-pyrrole
  参考文献：
  名称：

  Decarboxylative cyclization of allylic cyclic carbamates: applications to the total synthesis of (-)-codonopsine

  摘要：

  Decarboxylative cyclization of allylic cyclic carbamates 1 leading to 2-substituted DELTA-3-piperidines and -pyrrolidines, as well as its application to the total synthesis of (-)-codonopsine, is described.

  DOI：

  10.1021/jo00014a004
• 作为产物：
  描述：

  反-2-辛烯醛 、 三甲基氰硅烷 在 lithium aluminium tetrahydride 、 zinc(II) iodide 作用下， 生成 (E)-1-Amino-non-3-en-2-ol
  参考文献：
  名称：

  Decarboxylative cyclization of allylic cyclic carbamates: applications to the total synthesis of (-)-codonopsine

  摘要：

  Decarboxylative cyclization of allylic cyclic carbamates 1 leading to 2-substituted DELTA-3-piperidines and -pyrrolidines, as well as its application to the total synthesis of (-)-codonopsine, is described.

  DOI：

  10.1021/jo00014a004

文献信息

• LUBRICATING OIL COMPOSITION, AND SLIDING MECHANISM USING LUBRICATING OIL COMPOSITION
  申请人：Idemitsu Kosan Co., Ltd

  公开号：EP2826845A1

  公开（公告）日：2015-01-21

  Disclosed is a lubricating oil composition for low-friction sliding materials, which is used in a sliding mechanism where a DLC film containing hydrogen in an amount of from 5 atom% to 50 atom% is formed on at least one sliding surface. The lubricating oil composition contains, in the lubricant base oil therein and based on the total amount of the composition, (A) an organic zinc dithiophosphate in an amount of from 0.005% by mass to 0.12% by mass in terms of the phosphorus concentration therein, (B) an amine-based friction-reducing agent in an amount of from 0.05% by mass to 5.0% by mass, and (C) an alkaline earth metal salicylate-based detergent and/or an alkaline earth metal sulfonate-based detergent in an amount of from 0.05% by mass to 0.5% by mass in terms of the alkaline earth metal concentration therein, wherein the component (A) contains, based on the total amount of the composition, a zinc primary dialkyldithiophosphate in an amount of from 0.005% by mass to 0.05% by mass in terms of the phosphorus concentration therein.

  本发明公开了一种用于低摩擦滑动材料的润滑油组合物，该组合物用于在至少一个滑动表面上形成含氢量为 5 原子％至 50 原子％的 DLC 膜的滑动机构中。该润滑油组合物在其中的润滑油基础油中，根据组合物的总量，含有 (A) 有机二硫代磷酸锌，以其中的磷浓度计，含量为 0.005% （质量百分比）至 0.12% （质量百分比）；(B) 基于胺的减摩剂，含量为 0.05% （质量百分比）至 5.(C) 碱土金属水杨酸酯类洗涤剂和/或碱土金属磺酸盐类洗涤剂，以其中碱土金属的浓度计，其用量为 0.05% (质量) 至 0.5% (质量)，其中组分 (A) 含有以组合物总量计，以其中磷的浓度计，其用量为 0.005% (质量) 至 0.05% (质量)的伯基二烷基二硫代磷酸锌。
• Golf ball layers formed of polyurethane-based and polyurea-based compositions incorporating block copolymers
  申请人：——

  公开号：US20040262808A1

  公开（公告）日：2004-12-30

  Golf equipment having improved cut and shear resistance that includes a polyurea-based composition or polyurethane-based composition, preferably saturated and/or water resistant, formed of a prepolymer, a functionalized block copolymer, and optionally further cured or chain extended with a curing agent, where the prepolymer is incorporated at the terminal end of the functionalized block copolymer.
• Golf Ball Layers Formed of Polyurethane-Based and Polyurea-Based Compositions Incorporating Block Copolymers
  申请人：Wu Shenshen

  公开号：US20090137342A1

  公开（公告）日：2009-05-28

  A golf ball including a core and a cover, wherein cover is formed from a composition comprising the reaction product of a prepolymer including a soft-segment comprising an amine-terminated polyether and a hard segment including a uretdione of hexamethylene diisocyanate; and an amine-terminated curing agent; wherein the amine-terminated polyether has the structure: where x and z have a combined value of 3.6-8 and y is 9-50, R is an alkyl group having 1-20 carbons, a phenyl group, a cyclic group, or mixtures thereof, R 1 is —(CH 2 ) a —, where a is 1-10, a phenylene group, a cyclic group, or a mixture thereof, and R 3 is hydrogen, a methyl group, or a mixture thereof.
• US7211624B2
  申请人：——

  公开号：US7211624B2

  公开（公告）日：2007-05-01
• US7214738B2
  申请人：——

  公开号：US7214738B2

  公开（公告）日：2007-05-08