L-mannonic acid hydrazide | 147598-40-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: L-mannonic acid hydrazide
• 英文别名: l-Mannonsaeure-hydrazid；(2R,3R,4S,5S)-2,3,4,5,6-pentahydroxyhexanehydrazide
• CAS: 147598-40-1
• 化学式: C₆H₁₄N₂O₆
• 分子量: 210.187
• InChiKey: DSSOAANULUSBGQ-QMKXCQHVSA-N

物化性质

• 沸点：
  738.6±60.0 °C(predicted)
• 密度：
  1.665±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -4.4
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  156
• 氢给体数：
  7
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  L-mannonic acid hydrazide 、 苯甲醛 在 水 作用下， 生成 gulonic acid benzylidenehydrazide
  参考文献：
  名称：

  Weerman, Recueil des Travaux Chimiques des Pays-Bas, 1918, vol. 37, p. 34

  摘要：

  DOI：
• 作为产物：
  描述：

  L-甘露糖酸-1,4-内酯 在 肼 作用下， 以 乙醇 为溶剂， 生成 L-mannonic acid hydrazide
  参考文献：
  名称：

  Molecular recognition in polyols: the structure of L-mannonic acid hydrazide revealing a common packing motif in different acyclic sugars

  摘要：

  C6H14N2O6, M(r) = 210.19, tetragonal, P4(3), a 4.938 (1), c = 36.907 (8) angstrom, V = 899.93 angstrom3, Z = 4, D(x) = 1.551 g cm-3, lambda(Cu Kalpha) = 1.5418 angstrom, mu = 12.18 cm-1, F(000) = 448.0, T = 295 K, final R = 0.032 and wR = 0.029 for 759 observed reflections. The sugar chain of L-mannonic acid hydrazide shows the expected all-trans conformation. The hydrogen-bond pattern includes a homodromic cycle with a special connectivity that is also realized in several other open-chain sugar derivatives with different chirality. The relationship between the dimensions of the crystal lattice and the occurrence of this special cycle is discussed.

  DOI：

  10.1107/s0108768192010978

文献信息

• Kiliani, Chemische Berichte, 1925, vol. 58, p. 2349
  作者：Kiliani

  DOI：——

  日期：——
• Weerman, Recueil des Travaux Chimiques des Pays-Bas, 1918, vol. 37, p. 34
  作者：Weerman

  DOI：——

  日期：——
• Molecular recognition in polyols: the structure of <scp>L</scp>-mannonic acid hydrazide revealing a common packing motif in different acyclic sugars
  作者：C. André、P. Luger、J.-H. Fuhrhop、B. Rosengarten

  DOI：10.1107/s0108768192010978

  日期：1993.4.1

  C6H14N2O6, M(r) = 210.19, tetragonal, P4(3), a 4.938 (1), c = 36.907 (8) angstrom, V = 899.93 angstrom3, Z = 4, D(x) = 1.551 g cm-3, lambda(Cu Kalpha) = 1.5418 angstrom, mu = 12.18 cm-1, F(000) = 448.0, T = 295 K, final R = 0.032 and wR = 0.029 for 759 observed reflections. The sugar chain of L-mannonic acid hydrazide shows the expected all-trans conformation. The hydrogen-bond pattern includes a homodromic cycle with a special connectivity that is also realized in several other open-chain sugar derivatives with different chirality. The relationship between the dimensions of the crystal lattice and the occurrence of this special cycle is discussed.