2-甲基-1-[(2-甲基咪唑-1-基)甲基]咪唑 | 111128-04-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 中文名称: 2-甲基-1-[(2-甲基咪唑-1-基)甲基]咪唑
• 英文名称: 1,1'-methylenebis[(2,2'-methyl)]imidazole
• 英文别名: bis(2-methyl-1H-imidazol-1-yl)methane；bis(2-medthylimidazol-1-yl)methane；Bis(2-methylimidazol-1-yl)methane；2-mBIM；1H-Imidazole, 1,1'-methylenebis[2-methyl-；2-methyl-1-[(2-methylimidazol-1-yl)methyl]imidazole
• CAS: 111128-04-2
• 化学式: C₉H₁₂N₄
• 分子量: 176.221
• InChiKey: NROHHURPLSQZLB-UHFFFAOYSA-N

物化性质

• 熔点：
  174-176 °C(Solv: chloroform (67-66-3); methanol (67-56-1))
• 沸点：
  410.0±28.0 °C(Predicted)
• 密度：
  1.17±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  35.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  silver(I) nitrite 、 2-甲基-1-[(2-甲基咪唑-1-基)甲基]咪唑 以 甲醇 、 乙腈 为溶剂， 以62%的产率得到[Ag(bis(2-methylimidazol-1-yl)methane)(NO2)]
  参考文献：
  名称：

  Ag(I) coordination polymers with flexible bis-imidazole ligands: 2D interwoven structure and wavy layer network based on silver–silver interactions

  摘要：

  Two new coordination polymers [Ag(BIM)SO3CF3](n) (1) and [Ag(2-mBIM)NO2](n) (2) [wherein BIM = bis(imidazol-1-yl)-methane, 2-mBIM=bis(2-methylimidazol-1-yl) methane], were synthesized by the reactions of AgSO3CF3 with BIM and AgNO2 With 2-mBIM, respectively. They were characterized by elemental analyses, IR, TGA and single crystal X-ray diffraction studies. Compound 1 is an example of silver coordination network with 2D fabric structure in a "one-over/one-under" fashion through weak Ag...Ag interactions. Compound 2 adopts a wavy 2D layer network constructed through the Ag... Ag interactions between each neighboring 1D zigzag chains. TGA measurements suggest that 1 and 2 are thermally quite stable, with decomposition temperatures being 355 degrees C and 230 degrees C, respectively. Solid state luminescent spectra of compounds 1 and 2 indicate weak fluorescent emissions at ca. 345 and 409 nm, respectively. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2008.12.033
• 作为产物：
  描述：

  2-甲基咪唑 、 二溴甲烷 在 四丁基溴化铵 、 potassium hydroxide 作用下， 以 水 为溶剂， 反应 24.25h， 以58%的产率得到2-甲基-1-[(2-甲基咪唑-1-基)甲基]咪唑
  参考文献：
  名称：

  相转移催化合成对称和不对称的双咪唑衍生物

  摘要：

  建立了制备对称和不对称联咪唑衍生物的简便方法。对称的双咪唑基甲烷衍生物1a–9a是使用2-取代的咪唑衍生物1–9作为反应材料制备的。但是，分别获得了对称和不对称的双咪唑基甲烷衍生物10a-12a和10b-12b。具有偶氮基团的4位咪唑衍生物10-12被用作反应材料。所有这些化合物均已通过NMR，ESI-MS和EA在结构上进行了表征。和图8A和12A中的特征还在于X射线单晶扩散。

  DOI：

  10.1002/jhet.2917

文献信息

• A mixed ligand route for the construction of tetrahedrally coordinated porous lithium frameworks
  作者：Xiang Zhao、Tao Wu、Xianhui Bu、Pingyun Feng

  DOI：10.1039/c1dt10859j

  日期：——

  Reported here are two 4-connected 3D frameworks based on monomeric lithium nodes, which are synthesized through a mixed ligand route. By combining a negatively charged imidazole ligand and a neutral bis(imidazolyl)methane ligand (or one of its derivatives), neutral frameworks adopting chiral quartz-dual and diamond topologies have been obtained. These materials have low framework density and can reversibly adsorb hydrogen gas.

  本文报道了两种基于单体锂节点的四连接三维框架，它们通过混合配体路线合成。通过结合带负电的咪唑配体和中性的双咪唑基甲烷配体（或其衍生物），获得了采用手性石英双晶和金刚石拓扑结构的中性框架。这些材料具有低框架密度，并且能够可逆地吸附氢气。
• Syntheses of Methylene‐bridged Symmetric Bisimidazolium Picrates as High‐energetic Salts
  作者：Xiao‐Gang Du、Jun‐Qiang Zhou、Meng Zhong、Xue‐Mei Zhu、Fan Yun、Chuan‐Ming Jin

  DOI：10.1002/jhet.3459

  日期：2019.3

  new picrate salts were confirmed by 1H and 13C NMR spectral analysis and ESI‐MS. The structures of compounds 3a and 4a were also confirmed by X‐ray single crystal diffusion. The thermal properties of the compounds were determined by differential scanning calorimetry and thermogravimetric analysis. The picrates showed better thermal stabilities than did traditional azolium‐based ionic salts, with higher

  通过双咪唑基亚甲基的季铵化和与苦味银的复分解反应合成对称的双咪唑鎓苦味酸盐。1 H和13 C NMR光谱分析和ESI-MS证实了新的苦味酸盐的对称结构。X射线单晶扩散也证实了化合物3a和4a的结构。化合物的热性质通过差示扫描量热法和热重分析法确定。苦味素显示出比传统的基于氮鎓的离子盐更好的热稳定性，分解温度更高，且3b具有最低的熔点。这些结果表明，取代基的电子效应明显影响了季铵化和高能性质。
• Water-Soluble IrIII N-Heterocyclic Carbene Based Catalysts for the Reduction of CO2 to Formate by Transfer Hydrogenation and the Deuteration of Aryl Amines in Water
  作者：Arturo Azua、Sergio Sanz、Eduardo Peris

  DOI：10.1002/chem.201002907

  日期：2011.3.28

  higher σ‐electron‐donor character of the ligand. Remarkably, the activities obtained for the reduction of CO2 under the transfer hydrogenation conditions are the best reported to date in terms of TON value (max. TON=2700). The two new complexes have also shown very good activity in the selective deuteration of arylamines, a process that is known to proceed through a chelate assisted N‐directed process

  合成了两种新的具有磺酸盐官能团的水溶性[IrI 2（AcO）（bis-NHC）]络合物（NHC = N-杂环卡宾）。已经测试了两种络合物在用H 2和i PrOH还原CO 2中的作用，并且将它们的活性与没有磺酸盐部分的类似物质进行了比较。在这两个反应中，由于配体的σ电子给体特征较高，具有两个非正常结合的NHC的配合物显示出最佳的催化效率。显着地，为减少CO 2而获得的活性在转移氢化条件下，就TON值（最大TON = 2700）而言，是迄今为止报道得最好的。两种新的配合物在芳基胺的选择性氘化中也显示出非常好的活性，该过程已知是通过螯合辅助的N定向过程进行的。
• Preparation method for zeolitic imidazolate frameworks
  申请人：China University of Petroleum-Beijing

  公开号：US10815253B2

  公开（公告）日：2020-10-27

  The present invention provides a preparation method for zeolitic imidazolate frameworks. The preparation method comprises: adding a metal carbonate or oxide, an organic ligand to a hydrophilic liquid to obtain a mixture; introducing an acidic gas to reach a reaction pressure of 0.1 MPa to 2.0 MPa, and reacting for a predetermined time; heating to 30° C.-60° C. and vacuuming to obtain the zeolitic imidazolate framework. The present invention also provides a zeolitic imidazolate framework obtained by the above preparation method. The preparation method according to the present invention is environmentally friendly and has a high yield.

  本发明提供了一种沸石咪唑酸盐框架的制备方法。所述制备方法包括：将金属碳酸盐或氧化物、有机配体加入到亲水性液体中以获得混合物；引入酸性气体以达到0.1 MPa至2.0 MPa的反应压力，并进行预定时间的反应；加热至30°C至60°C并进行真空处理以获得沸石咪唑酸盐框架。本发明还提供了通过上述制备方法获得的沸石咪唑酸盐框架。本发明的制备方法环保且产率高。
• A new infinite inorganic [n]catenane from silver and bis(2-methylimidazolyl)methane ligand
  作者：Chuan-Ming Jin、Huan Lu、Ling-Yan Wu、Jing Huang

  DOI：10.1039/b612885h

  日期：——

  A new type of 1D infinite inorganic [n]catenane framework was self-assembled by silver nitrate and bis(2-methylimidazolyl)methane, while a comparatively one-dimensional zigzag cationic chain was generated by AgNO3 and bis(imidazol-1-yl)methane

  硝酸银和双(2-甲基咪唑基)甲烷自组装出一种新型的一维无限无机[n]烯烃框架，而 AgNO3 和双(咪唑-1-基)甲烷则生成了相对一维的之字形阳离子链