5,7-diethyl-undecan-6-one | 39516-86-4

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 5,7-diethyl-undecan-6-one
• 英文别名: 5,7-Diaethyl-undecan-6-on；5,7-diethylundecan-6-one；ethylamyl ketone
• CAS: 39516-86-4
• 化学式: C₁₅H₃₀O
• 分子量: 226.403
• InChiKey: USCUFUMWZTVVPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  16
• 可旋转键数：
  10
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.93
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-乙基-己酸稀土盐 在 硫酸 、 三氟化硼 、 乙酸酐 、 1,2-二氯乙烷 作用下， 生成 5,7-diethyl-undecan-6-one
  参考文献：
  名称：

  Formation of Symmetrical Ketones from Self-condensations of Anhydrides by Boron Fluoride¹

  摘要：

  DOI：

  10.1021/ja01163a523

文献信息

• Aspartates containing ketimine-groups and their use in coating compositions
  申请人：Bayer MaterialScience LLC

  公开号：EP1518852A1

  公开（公告）日：2005-03-30

  The present invention relates to novel aspartates, their method of production and the use of these aspartates as reactive components for polyisocyanates in two-component polyurethane coating compositions and for preparing polyurethane prepolymers. The aspartaes are prepared by first reacting a di- or polyamine with an unsaturated ester and then reacting the resultant product with a ketone.

  本发明涉及新型天冬氨酸盐，其生产方法以及将这些天冬氨酸盐作为双组分聚氨酯涂料组合物中聚异氰酸酯的反应组分和制备聚氨酯预聚物的用途。这些天冬氨酸盐是通过首先将二元或多元胺与不饱和酯反应，然后将所得产物与酮反应制备而成的。
• RESIST COMPOSITION, METHOD OF FORMING RESIST PATTERN, AND COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20200174365A1

  公开（公告）日：2020-06-04

  A resist composition containing a base material component of which solubility in a developing solution is changed due to an action of an acid and a compound represented by Formula (bd1); in the formula, R bd1 to R bd3 each independently represent an aryl group which may have a substituent, provided that one or more of R bd1 to R bd3 are aryl groups having a fluorinated alkyl group which may have a substituent, and at least one of the fluorinated alkyl groups which may have a substituent in these aryl groups is bonded to a carbon atom adjacent to a carbon atom that is bonded to a sulfur atom in the formula, and a total number of the fluorinated alkyl groups which may have a substituent is 2 or more; X − represents a counter anion.

  一种抗蚀组合物，含有基础材料组分，其在显影溶液中的溶解性由酸的作用和由化合物代表的公式（bd1）改变；在公式中，Rbd1到Rbd3各自独立地代表可能具有取代基的芳基，前提是Rbd1到Rbd3中的一个或多个是可能具有取代基的芳基，而这些芳基中至少有一个可能具有取代基的氟代烷基与公式中与硫原子相结合的碳原子相邻的碳原子结合，可能具有取代基的氟代烷基的总数为2或更多；X−代表一个对离子。
• Coating composition comprising an acetal-functional binder
  申请人：——

  公开号：US20030207104A1

  公开（公告）日：2003-11-06

  The invention relates to a coating composition comprising an acetal-functional binder and a thiol-functional cross-linker, wherein the acetal-functional binder is represented by the following formula 1 wherein P is a binder backbone, K is a divalent and/or trivalent organic moiety having 1 to 30 carbon atoms and having one or two links to the binder backbone, A is selected from oxygen, sulphur, and NR VII , wherein R VII is hydrogen or an alkyl group with 1 to 4 carbon atoms, m is an integer from 1 to 50, n is an integer from 1 to 10, and R and R′ may be the same or different and represent alkyl groups with 1 to 4 carbon atoms. In a further aspect, the invention relates to acetal-functional binders, acetal-functional monomers, a process for the preparation of said monomers, coating compositions comprising said acetal-functional binders, and to a process for the preparation of a coating composition comprising an acetal-functional polyurethane dispersion and a thiol-functional cross-linker.

  本发明涉及一种涂层组合物，包括一个醛缩功能粘合剂和一个硫醇交联剂，其中所述醛缩功能粘合剂由以下公式1表示： 其中，P是粘合剂骨架，K是一种具有1至30个碳原子并且具有一到两个链接到粘合剂骨架的二价和/或三价有机基团，A选自氧、硫和NRVII，其中RVII是氢或具有1至4个碳原子的烷基基团，m是1至50的整数，n是1至10的整数，R和R'可以相同或不同，代表具有1至4个碳原子的烷基基团。此外，本发明还涉及醛缩功能粘合剂、醛缩功能单体、制备所述单体的方法、包括所述醛缩功能粘合剂的涂层组合物，以及制备包括醛缩功能聚氨酯分散体和硫醇交联剂的涂层组合物的方法。
• Process for preparing peroxides using mixed anhydrides
  申请人：——

  公开号：US20040049070A1

  公开（公告）日：2004-03-11

  The invention relates to a process for the preparation of a peracid, perester or diacylperoxide and is characterized in that a mixed anhydride of formula R 1 [C(O)OC(O)OR 2 ] n or [R 3 C(O)OC(O)O] p R 4 is contacted with a hydroperoxide of formula R 5 [OOH] m in the presence of a base, wherein R 1 represents a mono-, di-, tri- or tetravalent C 1 -C 19 hydrocarbon group, optionally containing one or more hetero atoms, n is 1-4, R 2 represents a C 1 -C 20 hydrocarbon group, optionally containing one or more hetero atoms, R 3 represents a C 1 -C 19 hydrocarbon group, optionally containing one or more hetero atoms, R 4 represents a di-, tri- or tetravalent C 1 -C 20 hydrocarbon group, optionally containing one or more hetero atoms, p is 2-4, R 5 represents hydrogen or a mono- or divalent C 3 -C 18 tertiary alkyl or C 2 -C 20 acyl group, in which the tertiary alkyl or acyl group may optionally contain one or more hetero atoms, m is 1 or 2, and if R 5 represents hydrogen, m is 1, provided that if the hydroperoxide is an &agr;,&agr;′-dihydroperoxyperoxide, the reaction is not carried out in an inert two-phase solvent system comprising a polar solvent and an apolar solvent. The invention also relates to a hydroxyperacid, hydroxyperester, and hydroxydiacylperoxide obtainable by said process and the use of said hydroxyperoxides.

  本发明涉及一种制备过酸、过酯或双酰过氧化物的方法，其特征在于将式R1[C(O)OC(O)OR2]n或[R3C(O)OC(O)O]pR4的混合酸酐与式R5[OOH]的过氧化氢在碱的存在下接触，其中R1表示一个单、双、三或四价的C1-C19烃基，可选地含有一个或多个杂原子，n为1-4，R2表示一个C1-C20烃基，可选地含有一个或多个杂原子，R3表示一个C1-C19烃基，可选地含有一个或多个杂原子，R4表示一个双、三或四价的C1-C20烃基，可选地含有一个或多个杂原子，p为2-4，R5表示氢或一个单价或双价的C3-C18三级烷基或C2-C20酰基，其中该三级烷基或酰基可选地含有一个或多个杂原子，m为1或2，如果R5表示氢，则m为1，但如果过氧化氢是α，α'-二过氧基过氧化物，则不在惰性双相溶剂系统中进行反应，该系统包括一个极性溶剂和一个非极性溶剂。本发明还涉及通过该方法获得的羟基过酸、羟基过酯和羟基双酰过氧化物以及所述羟基过氧化物的用途。
• Water-solubilizable epoxy resin and coating composition comprising the resin for metal food contact surfaces
  申请人：MOBIL OIL CORPORATION

  公开号：EP0009526A1

  公开（公告）日：1980-04-16

  A resin is provided which is the adduct of a monocarboxylic acid and a diglycidyl ether of a bisphenol or of a monocarboxylic acid, a bisphenol and a diglycidyl ether of a bisphenol, reacted with an anhydride to an Acid No. of 35 to 150. This resin is solubilized with a volatile amine, ammonia or NH4OH in a solvent mixture of water, alkoxyethanols, alcohols and alkyl ethers of diethylene glycol and combined with an aminoplast to produce a coating composition utilizable to coat surfaces that will contact a food or beverage, such as in metal packaging containers.

  提供了一种树脂，它是单羧酸和双酚二缩水甘油醚的加合物，或者是单羧酸、双酚和双酚二缩水甘油醚的加合物，与酸酐反应生成酸值为 35 至 150 的酸酐。 这种树脂在水、烷氧基乙醇、醇和二甘醇烷基醚的混合溶剂中与挥发性胺、氨或 NH4OH 溶合，并与氨基树脂结合，生成一种涂料组合物，可用于涂覆与食品或饮料接触的表面，如金属包装容器。