2-甲基壬烷-4,6-二酮 | 5336-74-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-甲基壬烷-4,6-二酮
• 英文名称: 2-methyl-nonane-4,6-dione
• 英文别名: 2-Methyl-nonan-4,6-dion；Butyryl-isovaleryl-methan；2-Methylnonane-4,6-dione
• CAS: 5336-74-3
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: DDCLOUWVUPDZCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2914190090

反应信息

• 作为反应物：
  描述：

  2-甲基壬烷-4,6-二酮 生成 2-methyl-nonane-4,6-dione 4-enol tautomer
  参考文献：
  名称：

  Effect of Substituents on the Keto-Enol Equilibrium of Alkyl-substituted β-Diketones

  摘要：

  DOI：

  10.1246/bcsj.46.632
• 作为产物：
  描述：

  2-methyl-nonane-4,6-dione 4-enol tautomer 生成 2-甲基壬烷-4,6-二酮
  参考文献：
  名称：

  Effect of Substituents on the Keto-Enol Equilibrium of Alkyl-substituted β-Diketones

  摘要：

  DOI：

  10.1246/bcsj.46.632

文献信息

• METHOD FOR PRODUCING BIPHENYLTETRACARBOXYLIC ACID TETRAESTER
  申请人：Nishio Masayuki

  公开号：US20110137069A1

  公开（公告）日：2011-06-09

  Disclosed is a method for producing a biphenyltetracarboxylic acid ester by oxidative coupling a phthalic acid ester by using a catalyst comprising at least a palladium salt, a copper salt and a β-dicarbonyl compound in the presence of a molecular oxygen, wherein the β-dicarbonyl compound is supplied into a reaction mixture liquid intermittently at an interval of less than 30 minutes, or continuously. This method allows, in particular, the selective and economical production of an asymmetric biphenyltetracarboxylic acid tetraester such as 2,3,3′,4′-biphenyltetracarboxylic acid tetraester.

  揭示了一种通过在存在至少一种钯盐、一种铜盐和一种β-二羰基化合物的催化剂的情况下，通过氧化偶联邻苯二甲酸酯来制备二苯四羧酸酯的方法，其中β-二羰基化合物间歇地以小于30分钟的间隔或连续地供给到反应混合液中。该方法特别允许选择性和经济地生产不对称的二苯四羧酸四酯，如2,3,3′,4′-二苯四羧酸四酯。
• TWO-PACK CURABLE URETHANE ADHESIVE
  申请人：Sanyo Chemical Industries, Ltd.

  公开号：EP3896136A1

  公开（公告）日：2021-10-20

  The present invention aims to provide a two-component curable urethane adhesive that is easy to handle while it is substantially solvent-free, having weak to strong adhesive properties, and being capable of forming a cured film having excellent physical properties. The present invention provides a two-component curable urethane adhesive containing: a main agent; and a curing agent, the main agent containing at least one of a hydroxy group-containing urethane prepolymer (P1) or a polyol component (A), the hydroxy group-containing urethane prepolymer (P1) being a reaction product between the polyol component (A) and an organic polyisocyanate component (B), the curing agent containing at least one of an isocyanate group-containing urethane prepolymer (P2) or an organic polyisocyanate component (B), the isocyanate group-containing urethane prepolymer (P2) being a reaction product between the polyol component (A) and the organic polyisocyanate component (B), wherein the two-component curable urethane adhesive satisfies the following properties (1) to (5): (1) at least one of the polyol component (A) used in the hydroxy group-containing urethane prepolymer (P1) or the polyol component (A) used as the main agent contains a polyol (A1) having at least one of a group represented by a formula (1) or a group represented by a formula (2) at a molecular end thereof, and a total number of groups represented by the formula (1) in the polyol (A1) accounts for 40% or more based on a total number of groups represented by the formulas (1) and (2) in the polyol (A1) ; (2) an average total unsaturation degree of all the polyol components (A) used in the two-component curable urethane adhesive is 0.010 meq/g or less; (3) a weight average molecular weight of each of the urethane prepolymer (P1) and the urethane prepolymer (P2) is 1,000 to 100,000; (4) a chemical formula weight or number average molecular weight of each of the polyol component (A) and the organic polyisocyanate component (B) is 20,000 or less; and (5) a total weight of solvents in the main agent (excluding the polyol component (A)) and solvents in the curing agent (excluding the organic polyisocyanate component (B)) accounts for 5 wt% or less based on a total weight of the main agent and the curing agent, wherein in the formulas (1) and (2), each a is independently an integer of 0 or greater.

  本发明旨在提供一种双组分可固化聚氨酯粘合剂，该粘合剂易于操作，同时基本上不含溶剂，具有弱到强的粘合性能，并能形成具有优异物理性能的固化膜。本发明提供了一种双组分可固化聚氨酯粘合剂，它含有主剂主剂含有至少一种含羟基的聚氨酯预聚物 (P1) 或多元醇组分 (A)，含羟基的聚氨酯预聚物 (P1) 是多元醇组分 (A) 和有机多异氰酸酯组分 (B) 的反应产物、固化剂含有含异氰酸酯基的聚氨酯预聚物（P2）或有机多异氰酸酯组分（B）中的至少一种，含异氰酸酯基的聚氨酯预聚物（P2）是多元醇组分（A）和有机多异氰酸酯组分（B）之间的反应产物，其中双组分可固化聚氨酯胶粘剂满足以下特性（1）至（5）： (1) 含羟基聚氨酯预聚物 (P1) 中使用的多元醇组分 (A) 或作为主剂使用的多元醇组分 (A) 中至少有一种含有多元醇 (A1)，其分子末端至少有一个由式 (1) 所代表的基团或一个由式 (2) 所代表的基团、且多元醇（A1）中由式（1）代表的基团总数占多元醇（A1）中由式（1）和（2）代表的基团总数的 40%或以上； (2) 双组分固化型聚氨酯胶粘剂中使用的所有多元醇组分（A）的平均总不饱和度为 0.010 meq/g 或以下； (3) 聚氨酯预聚物（P1）和聚氨酯预聚物（P2）各自的重量平均分子量为 1 000 至 100 000； (4) 多元醇组分(A)和有机多异氰酸酯组分(B)各自的化学式重量或数均分子量为 20,000 或以下；以及 (5) 基于主剂和固化剂的总重量，主剂（不包括多元醇组分（A））和固化剂 （不包括有机多异氰酸酯组分（B））中溶剂的总重量占 5 wt%或以下、 其中，在式 (1) 和 (2) 中，每个 a 独立地为 0 或更大的整数。
• Adams; Hauser, Journal of the American Chemical Society, 1944, vol. 66, p. 1222
  作者：Adams、Hauser

  DOI：——

  日期：——
• The Acylation of Ketones with Aliphatic Anhydrides by Means of Boron Trifluoride. Synthesis of β-Diketones¹
  作者：Joe T. Adams、Charles R. Hauser

  DOI：10.1021/ja01218a041

  日期：1945.2
• US8541615B2
  申请人：——

  公开号：US8541615B2

  公开（公告）日：2013-09-24