Process for controlling the polymer composition of an ethylene copolymer obtained by a catalyst system comprising a transition metal catalyst component and a Ziegler catalyst component
申请人:Basell Polyolefine GmbH
公开号:EP2607391A1
公开(公告)日:2013-06-26
A method of controlling the polymer composition of an ethylene copolymer in a process for preparing ethylene copolymers by copolymerizing ethylene and at least one other olefin in the presence of a polymerization catalyst system comprising
- at least one late transition metal catalyst component (A),
- at least one Ziegler catalyst component (B), and
- at least one activating compound (C)
by adding an alkyl alkoxy silane or a dialkyl ether for increasing the relative portion of the ethylene copolymer component obtained from polymerization by late transition metal catalyst component (A), or
by adding a saturated halogenated hydrocarbon for increasing the relative portion of the ethylene copolymer component obtained from polymerization by Ziegler catalyst component (B),
processes for copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system comprising utilizing the controlling method, a method for altering the polymer composition of an ethylene copolymer obtained by copolymerizing ethylene and at least one other olefin in the presence of such a polymerization catalyst system and a method for transitioning from one ethylene copolymer grade to another by using the method for altering the polymer composition.
一种在制备乙烯共聚物的工艺中控制乙烯共聚物的聚合物组成的方法,该工艺是在聚合催化剂体系存在下将乙烯和至少一种其他烯烃进行共聚,聚合催化剂体系包括
- 至少一种晚过渡金属催化剂组分 (A)
- 至少一种齐格勒催化剂组分(B),以及
- 至少一种活化化合物 (C)
加入烷基烷氧基硅烷或二烷基醚,以增加后期过渡金属催化剂组分(A)聚合得到的乙烯共聚物组分的相对比例,或
加入饱和卤代烃,以增加通过齐格勒催化剂组分(B)聚合得到的乙烯共聚物组分的相对比例、
在这种聚合催化剂体系存在下乙烯和至少一种其他烯烃共聚的工艺,包括利用控制方法、改变在这种聚合催化剂体系存在下乙烯和至少一种其他烯烃共聚得到的乙烯共聚物的聚合物组成的方法,以及利用改变聚合物组成的方法从一种乙烯共聚物等级过渡到另一种乙烯共聚物等级的方法。