2-硝基苯基-2-乙酰氨基-2-脱氧-α-D-吡喃半乳糖苷 | 23646-67-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 2-硝基苯基-2-乙酰氨基-2-脱氧-α-D-吡喃半乳糖苷
• 中文别名: 2-硝基苯基2-脱氧-2-乙酰氨基-Α-D-吡喃半乳糖苷；2-硝基苯基 2-脱氧-2-乙酰氨基-Α-D-吡喃半乳糖苷
• 英文名称: o-nitrophenyl 2-acetamido-2-deoxy-α-D-galactopyranoside
• 英文别名: o-nitrophenyl-N-acetyl-α-D-galactoside；2-Nitrophenyl 2-acetamido-2-deoxy-a-D-galactopyranoside；N-[(2R,3R,4R,5R,6R)-4,5-dihydroxy-6-(hydroxymethyl)-2-(2-nitrophenoxy)oxan-3-yl]acetamide
• CAS: 23646-67-5
• 化学式: C₁₄H₁₈N₂O₈
• mdl: MFCD00069784
• 分子量: 342.306
• InChiKey: PXMQUEGJJUADKD-RGDJUOJXSA-N

物化性质

• 熔点：
  107-109°C
• 沸点：
  685.2±55.0 °C(Predicted)
• 密度：
  1.51±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -1.2
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  154
• 氢给体数：
  4
• 氢受体数：
  8

安全信息

• WGK Germany：
  3

反应信息

• 作为反应物：
  描述：

  2-硝基苯基-2-乙酰氨基-2-脱氧-α-D-吡喃半乳糖苷 、 Α-D-乳酸吡喃糖苷甲酯 以5 mg的产率得到methyl 3-O-(2-acetamido-2-deoxy-α-D-galactopyranosyl)-α-D-galactopyranoside
  参考文献：
  名称：

  Enzymic synthesis of HexNAc-containing disaccharide glycosides

  摘要：

  The following disaccharide glycosides were obtained from the appropriate donor and acceptor glycosides by employing glycosidases from the mollusc Chamelea gallina as catalysts: alpha-D-Galp-OMe (N-acetyl-alpha-D- galactosaminidase), beta-D-GalpNAc-(1----3)-beta-D-Galp-OMe, beta-D-GlcpNAc-(1----3)-beta-D-Galp-OMe, and beta-D-GlcpNAc-(1----6)-alpha-D-Manp-OMe (N-acetyl-beta-D-hexosaminidase). The regioselectivity of the N-acetyl-beta-D-hexosaminidase-catalysed reactions depended on the anomeric configuration of the acceptor. Thus, alpha-D-Galp-OMe gave beta-D-GlcpNAc- (1----6)-alpha-D-Galp-OMe almost exclusively, whereas beta-D-Galp-OMe gave beta-D-GlcpNAc-(1----3)-beta-D-Galp-OMe and beta-D-GlcpNAc-(1----6)-beta-D-Galp-OMe in almost equal amounts. The isolation of the products by chromatography was straightforward.

  DOI：

  10.1016/0008-6215(90)84022-m

文献信息

• METHOD AND COMPOSITION FOR DETECTING BACTERIAL CONTAMINATION IN FOOD PRODUCTS
  申请人：BioControl Systems, Inc.

  公开号：EP0870054B1

  公开（公告）日：2008-07-30
• METHOD AND CULTURE DEVICE FOR DETECTING YEASTS AND MOLDS
  申请人：3M Innovative Properties Company

  公开号：EP2951279B1

  公开（公告）日：2020-12-09
• ARTICLE AND METHOD FOR DETECTING AEROBIC BACTERIA
  申请人：3M Innovative Properties Company

  公开号：EP3114209B1

  公开（公告）日：2019-06-12
• CARBOHYDRATE-BINDING PROTEIN
  申请人：The University Of Georgia Research Foundation, Inc

  公开号：EP3132031A1

  公开（公告）日：2017-02-22
• US6387650B1
  申请人：——

  公开号：US6387650B1

  公开（公告）日：2002-05-14