9-[3-(3-Formylphenanthren-9-yl)propyl]phenanthrene-3-carbaldehyde | 862305-59-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 9-[3-(3-Formylphenanthren-9-yl)propyl]phenanthrene-3-carbaldehyde
• 英文别名: 9-[3-(3-formylphenanthren-9-yl)propyl]phenanthrene-3-carbaldehyde
• CAS: 862305-59-7
• 化学式: C₃₃H₂₄O₂
• 分子量: 452.552
• InChiKey: XFOIQYGHPKFHBE-UHFFFAOYSA-N

物化性质

• 沸点：
  712.8±40.0 °C(Predicted)
• 密度：
  1.259±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  35
• 可旋转键数：
  6
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9-[3-(3-Formylphenanthren-9-yl)propyl]phenanthrene-3-carbaldehyde 在 sodium tetrahydroborate 、 4-甲基苯磺酸吡啶 作用下， 以 乙醇 、 1,2-二氯乙烷 为溶剂， 反应 240.0h， 生成 6-Oxaheptacyclo[21.7.1.14,30.18,12.111,19.013,18.024,29]tetratriaconta-1(30),2,4(32),8(34),9,11,13,15,17,19(33),23(31),24,26,28-tetradecaene
  参考文献：
  名称：

  Synthesis and Fluorescence Spectra of Oxa[3.n]phenanthrenophanes

  摘要：

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.

  DOI：

  10.1021/ol051047y
• 作为产物：
  描述：

  哌啶-1-甲醛 、 3-Bromo-9-[3-(3-bromophenanthren-9-yl)propyl]phenanthrene 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 以64%的产率得到9-[3-(3-Formylphenanthren-9-yl)propyl]phenanthrene-3-carbaldehyde
  参考文献：
  名称：

  Synthesis and Fluorescence Spectra of Oxa[3.n]phenanthrenophanes

  摘要：

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.

  DOI：

  10.1021/ol051047y

文献信息

• Synthesis and Fluorescence Spectra of Oxa[3.<i>n</i>]phenanthrenophanes
  作者：Yosuke Nakamura、Takuzo Yamazaki、Jun Nishimura

  DOI：10.1021/ol051047y

  日期：2005.7.1

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.