3-Bromo-9-[3-(3-bromophenanthren-9-yl)propyl]phenanthrene | 265137-32-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 菲及其衍生物
• 英文名称: 3-Bromo-9-[3-(3-bromophenanthren-9-yl)propyl]phenanthrene
• CAS: 265137-32-4
• 化学式: C₃₁H₂₂Br₂
• 分子量: 554.324
• InChiKey: HBNYHHNAYJLDET-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.1
• 重原子数：
  33
• 可旋转键数：
  4
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  3-Bromo-9-[3-(3-bromophenanthren-9-yl)propyl]phenanthrene 在 sodium tetrahydroborate 、 正丁基锂 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 生成 {9-[3-(3-Hydroxymethyl-phenanthren-9-yl)-propyl]-phenanthren-3-yl}-methanol
  参考文献：
  名称：

  Synthesis and Fluorescence Spectra of Oxa[3.n]phenanthrenophanes

  摘要：

  Novel photostable oxa[3.n](3,9)- and (3.3](3,10)phenanthrenophanes (n = 3, 4) bearing trimethylene-type linkage(s) were successfully synthesized by the intramolecular acid-catalyzed etherification of the corresponding precursor diols. syn-Oxa[3.3](3,10)phenanthrenophane afforded the most red-shifted excimer fluorescence (lambda(max) = 432 nm) among the phenanthrenophanes so far prepared.

  DOI：

  10.1021/ol051047y
• 作为产物：
  描述：

  1-bromo-4-[7-(4-bromophenyl)-2,6-diphenylhepta-1,6-dienyl]benzene 在 碘 作用下， 以 环己烷 为溶剂， 以30%的产率得到3-Bromo-9-[3-(3-bromophenanthren-9-yl)propyl]phenanthrene
  参考文献：
  名称：

  Synthesis and fluorescence emission behavior of novel anti-[2.n](3,9)phenanthrenophanes

  摘要：

  Novel syn- and anti-[2.n](3,9)phenanthrenophanes (n=3,4) were successfully prepared by the intramolecular [2+2] photocycloaddition of alpha,omega-bis(3-vinyl-9-phenanthryl)alkanes. The anti-isomer of n=3 was found to give excimer fluorescence in spite of the only partially overlapping phenanthrene rings, although that of n=4 gave monomer fluorescence. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(99)02306-0