2-(1-(2,6-diisopropylphenylimino)ethylidene)quinoline | 220001-09-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2-(1-(2,6-diisopropylphenylimino)ethylidene)quinoline
• 英文别名: 2,6-diisopropyl-N-(1-(quinolin-2-yl)ethylidene) benzenamine；N-[2,6-di(propan-2-yl)phenyl]-1-quinolin-2-ylethanimine
• CAS: 220001-09-2
• 化学式: C₂₃H₂₆N₂
• 分子量: 330.473
• InChiKey: KZAWGZLYQHRSIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.3
• 重原子数：
  25
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  25.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2-(1-(2,6-diisopropylphenylimino)ethylidene)quinoline 、 cobalt(II) chloride 以 乙醇 为溶剂， 以93%的产率得到2-(1-(2,6-diisopropylphenylimino)ethylidene)quinolylcobalt dichloride
  参考文献：
  名称：

  Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines

  摘要：

  A series of 2-(1-aryliminoethylidene)quinolines (L) were synthesized and used as bidentate N boolean AND N ligands in coordinating with metal (cobalt and iron) chlorides to form complexes of the type LMCl(2), cobalt(II) (Co1-Co5) and iron(II) (Fe1-Fe5). All organic compounds and metal complexes were fully characterized, and the molecular structures of the representative complexes Co3 center dot DMF and Fe4 center dot DMF were confirmed as distorted bipyramidal geometry at the metal by single-crystal X-ray diffraction. Upon activation with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO) under 10 atm ethylene, all complexes showed high activities in ethylene dimerization with activities of up to 1.82 x 10(6) g mol(-1) (Co) h(-1) and 5.89 x 10(5) g mol(-1) (Fe) h(-1), respectively. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.06.003
• 作为产物：
  描述：

  1-(喹啉-2-基)乙酮 、 2,6-二异丙基苯胺 在 对甲苯磺酸 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以84%的产率得到2-(1-(2,6-diisopropylphenylimino)ethylidene)quinoline
  参考文献：
  名称：

  Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines

  摘要：

  A series of 2-(1-aryliminoethylidene)quinolines (L) were synthesized and used as bidentate N boolean AND N ligands in coordinating with metal (cobalt and iron) chlorides to form complexes of the type LMCl(2), cobalt(II) (Co1-Co5) and iron(II) (Fe1-Fe5). All organic compounds and metal complexes were fully characterized, and the molecular structures of the representative complexes Co3 center dot DMF and Fe4 center dot DMF were confirmed as distorted bipyramidal geometry at the metal by single-crystal X-ray diffraction. Upon activation with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO) under 10 atm ethylene, all complexes showed high activities in ethylene dimerization with activities of up to 1.82 x 10(6) g mol(-1) (Co) h(-1) and 5.89 x 10(5) g mol(-1) (Fe) h(-1), respectively. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2011.06.003

文献信息

• 2-(1-Arylimino)quinolylnickel halides: Synthesis, characterization and catalytic behavior towards ethylene
  作者：Shengju Song、Tianpengfei Xiao、Lin Wang、Carl Redshaw、Fosong Wang、Wen-Hua Sun

  DOI：10.1016/j.jorganchem.2011.11.001

  日期：2012.2

  A series of 2-(1-arylimino) quinolylnickel halides were synthesized and characterized by IR and elemental analyses. Distorted trigonal bipyramidal geometries are adopted for the nickel complexes C1, C4, C7 and C11 as crystallized from either DMF or methanol solution. When activated by Et2AlCl, the nickel precatalysts exhibited good to high catalytic activities in ethylene oligomerization. (C) 2011 Elsevier B.V. All rights reserved.
• Synthesis, characterization and catalytic behavior toward ethylene of cobalt(II) and iron(II) complexes bearing 2-(1-aryliminoethylidene)quinolines
  作者：Shengju Song、Weizhen Zhao、Lin Wang、Carl Redshaw、Fosong Wang、Wen-Hua Sun

  DOI：10.1016/j.jorganchem.2011.06.003

  日期：2011.9

  A series of 2-(1-aryliminoethylidene)quinolines (L) were synthesized and used as bidentate N boolean AND N ligands in coordinating with metal (cobalt and iron) chlorides to form complexes of the type LMCl(2), cobalt(II) (Co1-Co5) and iron(II) (Fe1-Fe5). All organic compounds and metal complexes were fully characterized, and the molecular structures of the representative complexes Co3 center dot DMF and Fe4 center dot DMF were confirmed as distorted bipyramidal geometry at the metal by single-crystal X-ray diffraction. Upon activation with either methylaluminoxane (MAO) or modified methylaluminoxane (MMAO) under 10 atm ethylene, all complexes showed high activities in ethylene dimerization with activities of up to 1.82 x 10(6) g mol(-1) (Co) h(-1) and 5.89 x 10(5) g mol(-1) (Fe) h(-1), respectively. (C) 2011 Elsevier B. V. All rights reserved.