4-(2-(hept-2-ynyl)non-4-ynyloxy)but-2-yn-1-ol | 1311201-90-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 4-(2-(hept-2-ynyl)non-4-ynyloxy)but-2-yn-1-ol
• 英文别名: 4-(2-Hept-2-ynylnon-4-ynoxy)but-2-yn-1-ol；4-(2-hept-2-ynylnon-4-ynoxy)but-2-yn-1-ol
• CAS: 1311201-90-7
• 化学式: C₂₀H₃₀O₂
• 分子量: 302.457
• InChiKey: MCHCHHNPFSSFHD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  22
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  29.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-(hept-2-yn-1-yl)non-4-yn-1-ol 在 正丁基锂 、 sodium hydride 作用下， 以 四氢呋喃 、 正己烷 、 N,N-二甲基甲酰胺 、 mineral oil 为溶剂， 反应 16.0h， 生成 4-(2-(hept-2-ynyl)non-4-ynyloxy)but-2-yn-1-ol
  参考文献：
  名称：

  Chain-Growth Cycloaddition Polymerization via a Catalytic Alkyne [2 + 2 + 2] Cyclotrimerization Reaction and Its Application to One-Shot Spontaneous Block Copolymerization

  摘要：

  A cobalt-catalyzed alkyne [2 + 2 + 2] cycloaddition reaction has been applied to polymerizations yielding linear polymers via selective cross-cyclotrimerization of yne-diyne monomers, which occurs in a chain-growth manner. Additionally, through control of the alkyne reactivity of the two monomers, this method was efficiently applied to the spontaneous block copolymerization of their mixture. Here we present the proposed mechanism of the catalyst transfer process of this cycloaddition polymerization.

  DOI：

  10.1021/ja203584c

文献信息

• Chain-Growth Cycloaddition Polymerization via a Catalytic Alkyne [2 + 2 + 2] Cyclotrimerization Reaction and Its Application to One-Shot Spontaneous Block Copolymerization
  作者：Yu-ki Sugiyama、Rei Kato、Tetsuya Sakurada、Sentaro Okamoto

  DOI：10.1021/ja203584c

  日期：2011.6.29

  A cobalt-catalyzed alkyne [2 + 2 + 2] cycloaddition reaction has been applied to polymerizations yielding linear polymers via selective cross-cyclotrimerization of yne-diyne monomers, which occurs in a chain-growth manner. Additionally, through control of the alkyne reactivity of the two monomers, this method was efficiently applied to the spontaneous block copolymerization of their mixture. Here we present the proposed mechanism of the catalyst transfer process of this cycloaddition polymerization.