| 126898-93-9

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• CAS: 126898-93-9
• 化学式: C₄₅H₅₇P₃Zr₃
• 分子量: 964.541
• InChiKey: DJPCSGNGHWILFU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 trimethyl(methylene)phosphorane 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Metallophosphaalkenes—from Exotics to Versatile Building Blocks in Preparative Chemistry

  摘要：

  AbstractThe chemistry of low‐valent organophosphorus compounds such as phosphaalkenes and phosphaalkynes has undergone rapid development in the last two decades. This development also includes the coordination chemistry of these species, which can act as versatile ligands in metal complexes. Metallophosphaalkenes are compounds in which one or more of the organic substituents on the PC unit is replaced by a transition metal complex fragment. Metallophosphaalkenes have emerged from an existence as laboratory curiosities to become a link between main group and organometallic complex chemistry. The great richness of their chemistry not only mirrors the specific properties of the individual building block, but also shows novel and individual traits. Particular examples are cycloadditions of these electron‐rich heteroalkenes with electron‐deficient alkenes, alkynes, azo, and diazo compounds. These often lead to novel types of reaction and compounds. Metallophosphaalkenes are also important as intermediates in all metal‐assisted cyclooligomerizations of phosphaalkynes.

  DOI：

  10.1002/anie.199602711
• 作为产物：
  描述：

  (2-tert-butyl-1-phosphaacetylene)zirconocene 以 not given 为溶剂， 生成
  参考文献：
  名称：

  Metallophosphaalkenes—from Exotics to Versatile Building Blocks in Preparative Chemistry

  摘要：

  AbstractThe chemistry of low‐valent organophosphorus compounds such as phosphaalkenes and phosphaalkynes has undergone rapid development in the last two decades. This development also includes the coordination chemistry of these species, which can act as versatile ligands in metal complexes. Metallophosphaalkenes are compounds in which one or more of the organic substituents on the PC unit is replaced by a transition metal complex fragment. Metallophosphaalkenes have emerged from an existence as laboratory curiosities to become a link between main group and organometallic complex chemistry. The great richness of their chemistry not only mirrors the specific properties of the individual building block, but also shows novel and individual traits. Particular examples are cycloadditions of these electron‐rich heteroalkenes with electron‐deficient alkenes, alkynes, azo, and diazo compounds. These often lead to novel types of reaction and compounds. Metallophosphaalkenes are also important as intermediates in all metal‐assisted cyclooligomerizations of phosphaalkynes.

  DOI：

  10.1002/anie.199602711

文献信息

• Binger, Paul; Biedenbach, Bruno; Herrmann, Albert T., Chemische Berichte, 1990, vol. 123, p. 1617 - 1624
  作者：Binger, Paul、Biedenbach, Bruno、Herrmann, Albert T.、Langhauser, Franz、Betz, Peter、et al.

  DOI：——

  日期：——
• Metallophosphaalkenes—from Exotics to Versatile Building Blocks in Preparative Chemistry
  作者：Lothar Weber

  DOI：10.1002/anie.199602711

  日期：1996.2.16

  AbstractThe chemistry of low‐valent organophosphorus compounds such as phosphaalkenes and phosphaalkynes has undergone rapid development in the last two decades. This development also includes the coordination chemistry of these species, which can act as versatile ligands in metal complexes. Metallophosphaalkenes are compounds in which one or more of the organic substituents on the PC unit is replaced by a transition metal complex fragment. Metallophosphaalkenes have emerged from an existence as laboratory curiosities to become a link between main group and organometallic complex chemistry. The great richness of their chemistry not only mirrors the specific properties of the individual building block, but also shows novel and individual traits. Particular examples are cycloadditions of these electron‐rich heteroalkenes with electron‐deficient alkenes, alkynes, azo, and diazo compounds. These often lead to novel types of reaction and compounds. Metallophosphaalkenes are also important as intermediates in all metal‐assisted cyclooligomerizations of phosphaalkynes.