2-Ethenyloctanal | 87745-60-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-Ethenyloctanal
• CAS: 87745-60-6
• 化学式: C₁₀H₁₈O
• 分子量: 154.252
• InChiKey: VIXDDNWAOPMQOI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  11
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-Diethoxymethyl-non-1-ene 在 甲酸 作用下， 以 正戊烷 为溶剂， 反应 1.0h， 以70%的产率得到2-Ethenyloctanal
  参考文献：
  名称：

  Preparation of 3-Alkenals and 3-Alkynals by Hydrolysis of the Corresponding Acetals

  摘要：

  DOI：

  10.1055/s-1983-30461

文献信息

• WO2007/108999
  申请人：——

  公开号：——

  公开（公告）日：——
• Copper-Catalyzed Rearrangement of Vinyl Oxiranes
  作者：Lindsay A. Batory、Christine E. McInnis、Jon T. Njardarson

  DOI：10.1021/ja067073o

  日期：2006.12.1

  A novel copper-catalyzed vinyl oxirane ring expansion protocol has been developed. A wide range of vinyl oxiranes can be rearranged to 2,5-dihydrofurans in excellent yields in the presence of electrophilic copper(II) acetylacetonate catalysts. Regioisomeric vinyl oxiranes can be converted to a single dihydrofuran product using these conditions. This method uses low catalyst loadings (0.5-5 mol %), has good tolerance of substitution patterns, and can be done in the absence of solvent.
• BARBOT, F.;MIGINIAC, PH., SYNTHESIS, BRD, 1983, N 8, 651-654
  作者：BARBOT, F.、MIGINIAC, PH.

  DOI：——

  日期：——
• PASTE COMPOSITION, GREEN CERAMIC BODY, AND METHODS FOR MANUFACTURING CERAMIC STRUCTURE
  申请人：TAKASE Hiroyuki

  公开号：US20080233416A1

  公开（公告）日：2008-09-25

  A paste composition comprises inorganic particles; and a binder containing a copolymer made by copolymerizing a mixture. The mixture comprises a first (meth)acrylic ester whose homopolymer has a first glass transition temperature Tg[h]; and a second (meth)acrylic ester whose homopolymer has a second glass transition temperature Tg[l] lower than the first glass transition temperature Tg[h]. The total molar fraction of the first and second (meth) acrylic esters in the mixture is 80 mol % or more. The first and the second glass transition temperatures Tg[h] and Tg[L] satisfy the relationships Tg[h]≧100° C. and Tg[h]−Tg[l]≧50° C.