3,7-dimethyl-6-oxooctanal | 58223-41-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 3,7-dimethyl-6-oxooctanal
• 英文别名: 3,7-dimethyl-6-oxo-octanal；2.6-Dimethyl-octanon-(3)-al-(8)
• CAS: 58223-41-9
• 化学式: C₁₀H₁₈O₂
• 分子量: 170.252
• InChiKey: QMGXVXFKXOTDMW-UHFFFAOYSA-N

物化性质

• 沸点：
  264.4±23.0 °C(Predicted)
• 密度：
  0.901±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  12
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  34.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  对薄荷-3-烯 在 臭氧 作用下， 生成 3,7-dimethyl-6-oxooctanal
  参考文献：
  名称：

  Semmler, Chemische Berichte, 1907, vol. 40, p. 2961

  摘要：

  DOI：

文献信息

• Thiourea, A convenient reagent for the reductive cleavage of olefin ozonolysis products
  作者：Deepa Gupta、Raghavan Soman、Sukh Dev

  DOI：10.1016/0040-4020(82)80187-7

  日期：1982.1

  A convenient procedure for the preparation of aldehydes, in good to excellent yields, from suitable olefins by ozonolysis in methanol, followed by exposure of the resulting products to thiourea, is described.

  描述了一种通过合适的烯烃在甲醇中进行臭氧分解，然后将所得的产物暴露于硫脲中，以良好的产率至优异的产率制备醛的简便方法。
• Electrogenerated acid as a powerful catalyst for transformation of epoxides to ketones and acetonides
  作者：Kenji Uneyama、Akihiro Isimura、Kazuyuki Fujii、Sigeru Torii

  DOI：10.1016/s0040-4039(00)88043-0

  日期：——

  Electrochemical Transformation of epoxides to ketones and acetonides were achieved by using an electrogenerated acid-catalyst. A combination of M(ClO4)n [ M; Li, Na, Mg, n = 1, 2] with polar aprotic solvents [CH2Cl2, ClCH2CH2Cl, THF, CH3COCH3, AcOEt, (MeO)2CO ] is useful for the electrochemical transformation.

  通过使用电生成的酸催化剂，可将环氧化合物电化学转化为酮和丙酮化物。M（ClO 4）n [M; 具有极性非质子溶剂[CH 2 Cl 2，ClCH 2 CH 2 Cl，THF，CH 3 COCH 3，AcOEt，（MeO）2 CO]的Li，Na，Mg，n = 1、2 ]可用于电化学转化。
• Organic peroxide stabilization with beta-dicarbonyl or cyclic alpha-diketone compounds
  申请人：WITCO CORPORATION

  公开号：EP0810213A2

  公开（公告）日：1997-12-03

  Organic peroxide compositions which contain a β-dicarbonyl compound or a cyclic α-diketone compound to retard the rate of decomposition of the peroxide compound are disclosed.

  本发明公开了含有β-二羰基化合物或环α-二酮化合物的有机过氧化物组合物，可延缓过氧化物化合物的分解速度。
• ——
  作者：O. I. Yarovaya、O. V. Salomatina、D. V. Korchagina、M. P. Polovinka、V. A. Barkhash

  DOI：10.1023/a:1022501815715

  日期：——

  The transformations of 6,7-epoxy derivatives of widely spread in the nature unsaturated aldehydes, citral and citronellal, in various acidic media both under conditions of homogeneous and heterogeneous catalysis were investigated. A number of previously unknown products belonging to different classes of organic compounds was obtained. Probable mechanisms of the products formation are discussed.
• GUPTA, D.;SOMAN, R.;DEV, S., TETRAHEDRON, 1982, 38, N 20, 3013-3018
  作者：GUPTA, D.、SOMAN, R.、DEV, S.

  DOI：——

  日期：——