2,6-di-n-propyl-4H-pyran-4-ylidenemalononitrile | 184713-09-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡喃
• 英文名称: 2,6-di-n-propyl-4H-pyran-4-ylidenemalononitrile
• 英文别名: (2,6-Dipropyl-4H-pyran-4-ylidene)propanedinitrile；2-(2,6-dipropylpyran-4-ylidene)propanedinitrile
• CAS: 184713-09-5
• 化学式: C₁₄H₁₆N₂O
• 分子量: 228.294
• InChiKey: LYQCPPRMWMTPLK-UHFFFAOYSA-N

物化性质

• 沸点：
  313.8±42.0 °C(Predicted)
• 密度：
  1.052±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  17
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  56.8
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-butyryl-4-hydroxy-6-propyl-2H-pyran-2-one 在 盐酸 、 乙酸酐 作用下， 反应 14.0h， 生成 2,6-di-n-propyl-4H-pyran-4-ylidenemalononitrile
  参考文献：
  名称：

  Design of optimized photorefractive polymers: A novel class of chromophores

  摘要：

  It is demonstrated that the microscopic mechanism of the photorefractive (PR) effect in organic composites with low glass transition temperatures involves the formation of refractive index gratings through a space-charge field-modulated Kerr effect. A tensorial formulation of the macroscopic aspects of the PR Kerr effect and its microscopic interpretation is presented. The second-order dipole orientation term containing the anisotropy of the first-order optical polarizability α(−ω;ω) is shown to yield the dominant contribution to the Kerr susceptibility χ(3)(−ω;ω,0,0). A class of special chromophores having negligible second-order polarizabilities β(−ω;ω,0) and large dipole moments μ has been identified in order to optimize this term. These chromophores are not subject to the efficiency-transparency tradeoff typically encountered with second-order nonlinear optical (NLO) chromophores, providing highly transparent materials with large PR Kerr response. Contrary to previous approaches in this field, the best-performing PR polymers are then expected to employ chromophores that would be useless for second- order applications (negligible β). We report PR of the material 30% 2,6-di-n-propyl-4H-pyran-4-ylidenemalononitrile (DPDCP): 15% N,N′-bis(3-methylphenyl)- N,N′-bis(phenyl)benzidine (TPD):55% poly(methyl methacrylate) (PMMA):0.3% C60 as an illustration of this principle. A 100 μm thick film of this material exhibits a steady-state diffraction efficiency of η=25% and net two-beam coupling of Γ=50 cm−1 at a bias field of 100 V/μm and a wavelength of 676 nm. The macroscopic Kerr susceptibility of the material is related to molecular electronic properties of the chromophore DPDCP which were independently determined by experiments in solution and by quantum chemical calculations.

  DOI：

  10.1063/1.472950

文献信息

• Design of optimized photorefractive polymers: A novel class of chromophores
  作者：Rüdiger Wortmann、Constantina Poga、Robert J. Twieg、Christian Geletneky、Christopher R. Moylan、Paul M. Lundquist、Ralph G. DeVoe、Patricia M. Cotts、Hans Horn、Julia E. Rice、Donald M. Burland

  DOI：10.1063/1.472950

  日期：1996.12.15

  It is demonstrated that the microscopic mechanism of the photorefractive (PR) effect in organic composites with low glass transition temperatures involves the formation of refractive index gratings through a space-charge field-modulated Kerr effect. A tensorial formulation of the macroscopic aspects of the PR Kerr effect and its microscopic interpretation is presented. The second-order dipole orientation term containing the anisotropy of the first-order optical polarizability α(−ω;ω) is shown to yield the dominant contribution to the Kerr susceptibility χ(3)(−ω;ω,0,0). A class of special chromophores having negligible second-order polarizabilities β(−ω;ω,0) and large dipole moments μ has been identified in order to optimize this term. These chromophores are not subject to the efficiency-transparency tradeoff typically encountered with second-order nonlinear optical (NLO) chromophores, providing highly transparent materials with large PR Kerr response. Contrary to previous approaches in this field, the best-performing PR polymers are then expected to employ chromophores that would be useless for second- order applications (negligible β). We report PR of the material 30% 2,6-di-n-propyl-4H-pyran-4-ylidenemalononitrile (DPDCP): 15% N,N′-bis(3-methylphenyl)- N,N′-bis(phenyl)benzidine (TPD):55% poly(methyl methacrylate) (PMMA):0.3% C60 as an illustration of this principle. A 100 μm thick film of this material exhibits a steady-state diffraction efficiency of η=25% and net two-beam coupling of Γ=50 cm−1 at a bias field of 100 V/μm and a wavelength of 676 nm. The macroscopic Kerr susceptibility of the material is related to molecular electronic properties of the chromophore DPDCP which were independently determined by experiments in solution and by quantum chemical calculations.