4-[2,5-dihexyl-4-[2-methyl-4-[4-(4-propylphenyl)anilino]phenyl]phenyl]-3-methyl-N-[4-(4-propylphenyl)phenyl]aniline | 1352615-39-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-[2,5-dihexyl-4-[2-methyl-4-[4-(4-propylphenyl)anilino]phenyl]phenyl]-3-methyl-N-[4-(4-propylphenyl)phenyl]aniline
• CAS: 1352615-39-4
• 化学式: C₆₂H₇₂N₂
• 分子量: 845.267
• InChiKey: AFICAJNXDWSQOD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  20.8
• 重原子数：
  64
• 可旋转键数：
  22
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  24.1
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  4-[2,5-dihexyl-4-[2-methyl-4-[4-(4-propylphenyl)anilino]phenyl]phenyl]-3-methyl-N-[4-(4-propylphenyl)phenyl]aniline 、 4-溴-4'-碘联苯 在 1,1'-双(二苯基膦)二茂铁 、 tris-(dibenzylideneacetone)dipalladium(0) 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 0.17h， 生成 N-[4-(4-bromophenyl)phenyl]-4-[4-[4-[N-[4-(4-bromophenyl)phenyl]-4-(4-propylphenyl)anilino]-2-methylphenyl]-2,5-dihexylphenyl]-3-methyl-N-[4-(4-propylphenyl)phenyl]aniline
  参考文献：
  名称：

  신규한 화합물, 이를 포함하는 코팅 조성물, 이를 이용한 유기 발광 소자 및 이의 제조방법

  摘要：

  这是关于包括化学式为1的化合物和标记为化学式1的化合物的涂层组合物，以及使用它制造有机发光器件的说明书。

  公开号：

  KR20220010426A
• 作为产物：
  描述：

  4-溴-3-甲基苯胺 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 tris-(dibenzylideneacetone)dipalladium(0) 、 四(三苯基膦)钯 、 三叔丁基膦 、 potassium acetate 、 甲基三辛基氯化铵 、 sodium carbonate 、 三氟乙酸 、 sodium t-butanolate 作用下， 以 二氯甲烷 、 N,N-二甲基甲酰胺 、 甲苯 为溶剂， 反应 98.0h， 生成 4-[2,5-dihexyl-4-[2-methyl-4-[4-(4-propylphenyl)anilino]phenyl]phenyl]-3-methyl-N-[4-(4-propylphenyl)phenyl]aniline
  参考文献：
  名称：

  [EN] SOLVENT-RESISTANT HOLE TRANSPORT LAYERS
  [FR] COUCHES DE TRANSPORT DE TROUS RÉSISTANTES AUX SOLVANTS

  摘要：

  提供一种具有以下化学式的空穴传输材料，化学式为I、Ia或II：在这些化学式中：A是含有至少一个三芳基胺基团的芳香基团；B'是一个芳香基团；E是末端基团，可以是H、D、烷基、芳基、卤素、氘代烷基或氘代芳基；G是G1、G2或其氘代物，星号代表连接点；n是大于0的整数；m1和m2代表非零摩尔分数，使得m1 + m2 = 1。

  公开号：

  WO2015089027A1

文献信息

• [EN] ELECTROACTIVE MATERIALS<br/>[FR] SUBSTANCES ÉLECTROACTIVES
  申请人：DU PONT

  公开号：WO2011159872A1

  公开（公告）日：2011-12-22

  There is disclosed a compound having Formula I or Formula I': In Formula I and Formula I': Ar1 and Ar2 are the same or different and are aryl groups; R1 through R5 are independently the same or different at each occurrence and are D, F, alkyl groups, aryl groups, alkoxy groups, silyl groups, or crosslinkable groups; R6 is H, D, or halogen; a through e are independently an integer from 0 to 4; f is 1 or 2; g is 0, 1 or 2; h is 1 or 2; and n is an integer greater than 0.

  披露了具有化学式I或化学式I'的化合物：在化学式I和化学式I'中：Ar1和Ar2相同或不同且为芳基基团；R1至R5在每次出现时独立相同或不同，为D、F、烷基基团、芳基基团、烷氧基团、硅基基团或交联基团；R6为H、D或卤素；a至e独立地为0至4的整数；f为1或2；g为0、1或2；h为1或2；n为大于0的整数。
• [EN] SOLVENT-RESISTANT HOLE TRANSPORT LAYERS<br/>[FR] COUCHES DE TRANSPORT DE TROUS RÉSISTANTES AUX SOLVANTS
  申请人：DU PONT

  公开号：WO2015089027A1

  公开（公告）日：2015-06-18

  There is provided a hole transport material having Formula I, Formula Ia, or Formula II: In the formulae: A is an aromatic moiety including at least one triarylamino group; B' is an aromatic moiety; E is an end group which is H, D, alkyl, aryl, halide, deuterated alkyl, or deuterated aryl; G is G1, G2, or a deuterated analog thereof where the asterisk represents the point of attachment; n is an integer greater than 0; and m1 and m2 represent non-zero mole fractions, such that m1 + m2 = 1.

  提供一种具有以下化学式的空穴传输材料，化学式为I、Ia或II：在这些化学式中：A是含有至少一个三芳基胺基团的芳香基团；B'是一个芳香基团；E是末端基团，可以是H、D、烷基、芳基、卤素、氘代烷基或氘代芳基；G是G1、G2或其氘代物，星号代表连接点；n是大于0的整数；m1和m2代表非零摩尔分数，使得m1 + m2 = 1。
• Electroactive materials
  申请人：LG Chem, Ltd.

  公开号：US10897025B2

  公开（公告）日：2021-01-19

  There is provided a compound having Formula I In Formula I: Ar1 and Ar2 are the same or different and are aryl, heteroaryl, or deuterated analogs thereof; L1 and L2 are the same or different and are H, D, halogen, aryl, arylamino, crosslinkable groups, deuterated aryl, deuterated arylamino, or deuterated crosslinkable groups; R1-R4 are the same or different at each occurrence and are D, F, CN, hydrocarbon aryl, heteroaryl, aryloxy, fluoroaryl, alkyl, fluoroalkyl, alkoxy, fluoroalkoxy, amino, silyl, siloxane, siloxy, germyl, deuterated hydrocarbon aryl, deuterated heteroaryl, deuterated aryloxy, deuterated fluoroaryl, deuterated alkyl, deuterated fluoroalkyl, deuterated alkoxy, deuterated fluoroalkoxy, deuterated amino, deuterated silyl, deuterated siloxane, deuterated siloxy, or deuterated germyl, wherein adjacent groups selected from R1-R4 can be joined together to form a fused ring; a is 0 or 1; b is 0 or 1; x and x1 are the same or different and are an integer from 0-5; y and y1 are the same or different and are an integer from 0-4; n is an integer greater than 0, with the proviso that when n=1, L1 and L2 are selected from Cl, Br, crosslinkable groups and deuterated crosslinkable groups; and BzF is benzofluorene.

  提供了一种具有式 I 的化合物 在式 I 中Ar1 和 Ar2 相同或不同，并且是芳基、杂芳基或其氚代类似物；L1 和 L2 相同或不同，并且是 H、D、卤素、芳基、芳基氨基、可交联基团、氚代芳基、氚代芳基氨基或氚代可交联基团；R1-R4 在每次出现时相同或不同，并且是 D、F、CN、烃芳基、杂芳基、芳氧基、氟芳基、烷基、氟烷基、烷氧基、氟烷氧基、氨基、硅烷基、硅氧烷基、硅氧基、胚芽基、氚代烃芳基、氚代杂芳基、氚代芳氧基、氚代氟芳基、氚代杂芳基、氚代芳酰胺基、氚代芳酰胺基、氚代芳酰胺基、氚代芳酰胺基、氚代芳酰胺基、氚代芳酰胺基、氚代可交联基团氚代氟芳基、氚代烷基、氚代氟烷基、氚代烷氧基、氚代氟烷氧基、氚代氨基、氚代硅烷基、氚代硅氧烷、氚代硅氧基或氚代胚芽基，其中选自 R1-R4 的相邻基团可连接在一起形成熔合环；a 为 0 或 1；b 为 0 或 1；x 和 x1 相同或不同，且为 0-5 的整数；y 和 y1 相同或不同，且为 0-4 的整数；n 为大于 0 的整数，但当 n=1 时，L1 和 L2 选自 Cl、Br、可交联基团和氚代可交联基团；以及 BzF 为苯并芴。
• ELECTROACTIVE MATERIALS
  申请人：Park Kyung-Ho

  公开号：US20130082251A1

  公开（公告）日：2013-04-04

  There is disclosed a compound having Formula I or Formula I′: In Formula I and Formula I′: Ar 1 and Ar 2 are the same or different and are aryl groups; R 1 through R 5 are independently the same or different at each occurrence and are D, F, alkyl groups, aryl groups, alkoxy groups, silyl groups, or crosslinkable groups; R 6 is H, D, or halogen; a through e are independently an integer from 0 to 4; f is 1 or 2; g is 0, 1 or 2; h is 1 or 2; and n is an integer greater than 0.
• HOLE TRANSPORT MATERIALS
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20160329497A1

  公开（公告）日：2016-11-10

  There is provided a copolymer having Formula I In Formula I: A is a monomeric unit containing at least one triarylamine group; B′ is a monomeric unit having at least three points of attachment in the copolymer; C′ is an aromatic monomeric unit or a deuterated analog thereof; E is the same or different at each occurrence and can be H, D, halide, alkyl, silyl, germyl, aryl, arylamino, siloxane, a crosslinkable group, deuterated alkyl, deuterated silyl, deuterated germyl, deuterated aryl, deuterated arylamino, deuterated siloxane, or a deuterated crosslinkable group; a, b, and c are the same or different and are mole fractions, such that a+b+c=1, and a and b are non-zero.