1-(3'-cyclohexenyl)cyclohexane | 20247-93-2

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 1-(3'-cyclohexenyl)cyclohexane
• 英文别名: 4-cyclohexyl-cyclohexene；4-Cyclohexyl-cyclohexen；4-cyclohexyl-1-cyclohexene；Bicyclohexyl-3-ene；4-cyclohexylcyclohexene
• CAS: 20247-93-2
• 化学式: C₁₂H₂₀
• 分子量: 164.291
• InChiKey: NHEQDCVKZARUJD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.9
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  4-环已基环已醇 在 硫酸 、 sodium sulfate 作用下， 以 5,5-dimethyl-1,3-cyclohexadiene 、 水 为溶剂， 以90%的产率得到1-(3'-cyclohexenyl)cyclohexane
  参考文献：
  名称：

  CYCLOHEXENE OXIDE COMPOUND HAVING CYCLOHEXYL GROUP OR BRANCHED LONG-CHAIN ALKYL GROUP AND USE THEREOF

  摘要：

  公开号：

  EP1798251B1

文献信息

• Selective dimerization of higher cycloolefins in the presence of micro- and micromesoporous zeolite catalysts
  作者：N. G. Grigor’eva、S. V. Bubennov、A. N. Khazipova、L. M. Khalilov、B. I. Kutepov

  DOI：10.1007/s11172-013-0061-x

  日期：2013.2

  Selective synthesis of dimers of cycloolefins C6-C8 was carried out in the presence of highly dispersed zeolite catalysts HY, HBeta, and HZSM-12 and granulated zeolite HY-WB, which differ in acidic properties and pore structure. The high selectivity of microporous zeolite HZSM-12 in cyclohexene dimerization (100%) and micromesoporous zeolite HY-WB in cycloheptene and cyclooctene dimerization (90–95%)

  在酸性性质和孔结构不同的高度分散的沸石催化剂 HY、HBeta 和 HZSM-12 和粒状沸石 HY-WB 存在下，选择性合成了环烯烃 C6-C8 的二聚体。微孔沸石 HZSM-12 在环己烯二聚 (100%) 中的高选择性和微孔沸石 HY-WB 在环庚烯和环辛烯二聚 (90-95%) 中的高选择性被建立。
• Cyclohexene Oxide Compound Having Cyclohexyl Group or Long-Chain Alkyl Group, and Use Thereof
  申请人：Kato Hisao

  公开号：US20080108725A1

  公开（公告）日：2008-05-08

  An object of the present invention is to provide a cyclohexene oxide compound that gives a cured resin having a low refractive index and excellent transparency, curability, mold release properties, and mechanical properties, and that can be used as a component of an actinic radiation curing composition and/or heat curing composition. The present invention is a cyclohexene oxide compound having a cyclohexyl group or a long-chain alkyl group, represented by Formula (1) below (in Formula (1), A denotes a cyclohexyl group, Formula (2) below, or an optionally branched alkyl group having 8 to 16 carbons) (in Formula (2), R 1 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons and R 2 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons).

  本发明的目的是提供一种环己烯氧化物化合物，该化合物能够产生具有低折射率和优异透明度、可固化性、模具脱模性和机械性能的固化树脂，并可用作光敏辐射固化组合物和/或热固化组合物的组分。本发明是一种具有环己基或长链烷基的环己烯氧化物化合物，由下式（1）表示（在式（1）中，A表示环己基、下式（2）或具有8至16个碳的可选支链烷基）（在式（2）中，R1表示氢原子或具有1至4个碳的可选支链烷基，R2表示氢原子或具有1至4个碳的可选支链烷基）。
• Cyclohexene oxide compound having cyclohexyl group or long-chain alkyl group, and use thereof
  申请人：Toagosei Co., Ltd.

  公开号：US07612123B2

  公开（公告）日：2009-11-03

  An object of the present invention is to provide a cyclohexene oxide compound that gives a cured resin having a low refractive index and excellent transparency, curability, mold release properties, and mechanical properties, and that can be used as a component of an actinic radiation curing composition and/or heat curing composition. The present invention is a cyclohexene oxide compound having a cyclohexyl group or a long-chain alkyl group, represented by Formula (1) below (in Formula (1), A denotes a cyclohexyl group, Formula (2) below, or an optionally branched alkyl group having 8 to 16 carbons) (in Formula (2), R1 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons and R2 denotes a hydrogen atom or an optionally branched alkyl group having 1 to 4 carbons).

  本发明的目的是提供一种环己烯氧化合物，该化合物能产生具有低折射率和优异透明度、可固化性、模具释放性能和机械性能的固化树脂，并可用作光致固化组合物和/或热固化组合物的组分。本发明是一种具有环己基或长链烷基的环己烯氧化合物，由下式（1）表示（在式（1）中，A表示环己基、下式（2）或具有8到16个碳的可选支链烷基）（在式（2）中，R1表示氢原子或具有1到4个碳的可选支链烷基，R2表示氢原子或具有1到4个碳的可选支链烷基）。
• Schrauth; Goerig, Chemische Berichte, 1923, vol. 56, p. 1904
  作者：Schrauth、Goerig

  DOI：——

  日期：——
• v. Braun; Irmisch; Nelles, Chemische Berichte, 1933, vol. 66, p. 1471,1474
  作者：v. Braun、Irmisch、Nelles

  DOI：——

  日期：——