1,4-bis(quinoxalinyloxy)benzene | 1105708-06-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1,4-bis(quinoxalinyloxy)benzene
• 英文别名: 2-(4-Quinoxalin-2-yloxyphenoxy)quinoxaline；2-(4-quinoxalin-2-yloxyphenoxy)quinoxaline
• CAS: 1105708-06-2
• 化学式: C₂₂H₁₄N₄O₂
• 分子量: 366.379
• InChiKey: TXOYEIABCCSREF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  28
• 可旋转键数：
  4
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  70
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  copper(l) iodide 、 1,4-bis(quinoxalinyloxy)benzene 以 二氯甲烷 、 乙腈 为溶剂， 生成 (1,4-bis(2-quinoxalinyloxy)benzene)Cu2I2
  参考文献：
  名称：

  Pyrazine-bridged copper(I) iodide coordination polymers: Control of chain separation through ligand design

  摘要：

  Syntheses are described of two new ligands that contain a central benzene to which are attached via oxygen atoms two pyrazine or quinoxaline rings. These react with copper(l) iodide to form complexes, whose crystal structures reveal coordination polymers consisting of ladders of Cu2I2 rings crosslinked into two-dimensional sheets by the new bridging ligands. The ligands separate the ladders by a distance of ca. 1.6 nm. (c) 2007 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2007.07.021
• 作为产物：
  描述：

  2-氯喹恶啉 、 对苯二酚 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 生成 1,4-bis(quinoxalinyloxy)benzene
  参考文献：
  名称：

  Sakata, Gozyo; Makino, Kenzi; Hashiba, Isao, Heterocycles, 1984, vol. 22, # 11, p. 2581 - 2585

  摘要：

  DOI：

文献信息

• Sakata, Gozyo; Makino, Kenzi; Hashiba, Isao, Heterocycles, 1984, vol. 22, # 11, p. 2581 - 2585
  作者：Sakata, Gozyo、Makino, Kenzi、Hashiba, Isao

  DOI：——

  日期：——
• Pyrazine-bridged copper(I) iodide coordination polymers: Control of chain separation through ligand design
  作者：Christopher M. Fitchett、Peter J. Steel

  DOI：10.1016/j.inoche.2007.07.021

  日期：2007.11

  Syntheses are described of two new ligands that contain a central benzene to which are attached via oxygen atoms two pyrazine or quinoxaline rings. These react with copper(l) iodide to form complexes, whose crystal structures reveal coordination polymers consisting of ladders of Cu2I2 rings crosslinked into two-dimensional sheets by the new bridging ligands. The ligands separate the ladders by a distance of ca. 1.6 nm. (c) 2007 Elsevier B.V. All rights reserved.