Pt(II)(8-quinolinethiolato)2 | 15554-79-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Pt(II)(8-quinolinethiolato)2
• 英文别名: Pt(8-mercaptoquinoline(-1H)2)2；Platinum(2+);quinoline-8-thiolate
• CAS: 15554-79-7
• 化学式: C₁₈H₁₂N₂PtS₂
• 分子量: 515.519
• InChiKey: PWAHEJXUXMCCTO-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  4.28
• 重原子数：
  23
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  27.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  Pt(II)(8-quinolinethiolato)2 、 pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene 以 氯仿 为溶剂， 以0%的产率得到dichloropentaphenoxy(2-pyridylmethylamino)cyclotriphosphazeneplatinum(II)
  参考文献：
  名称：

  Reactions of platinum nitrile complexes with cyclotriphosphazenes containing pyridylalkylamino groups

  摘要：

  Reactions of platinum(II) and platinum(IV) nitrile complexes with polydentate ligands, such as pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene, pentaphenoxy(3-pyridylmethylamino)cyclotriphosphazene, and pentaphenoxy(2-pyridylethylamino)cyclotriphosphazene, were studied. Platinum(IV) is reduced to platinum(II) upon complex formation; the pyridine and alkylamine nitrogen atoms coordinate to platinum(II) to form chelate rings. The compounds obtained were characterized by H-1 and P-31 NMR and IR spectroscopy, FAB mass spectrometry, and other methods.

  DOI：

  10.1134/s1070363206040074

文献信息

• Reactions of platinum nitrile complexes with cyclotriphosphazenes containing pyridylalkylamino groups
  作者：S. A. Simanova、T. V. Kuznetsova、U. Diefenbach、V. N. Demidov

  DOI：10.1134/s1070363206040074

  日期：2006.4

  Reactions of platinum(II) and platinum(IV) nitrile complexes with polydentate ligands, such as pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene, pentaphenoxy(3-pyridylmethylamino)cyclotriphosphazene, and pentaphenoxy(2-pyridylethylamino)cyclotriphosphazene, were studied. Platinum(IV) is reduced to platinum(II) upon complex formation; the pyridine and alkylamine nitrogen atoms coordinate to platinum(II) to form chelate rings. The compounds obtained were characterized by H-1 and P-31 NMR and IR spectroscopy, FAB mass spectrometry, and other methods.