1-[4-[[(4-Acetylphenyl)methyl-undec-10-enylamino]methyl]phenyl]ethanone | 1242054-48-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-[4-[[(4-Acetylphenyl)methyl-undec-10-enylamino]methyl]phenyl]ethanone
• 英文别名: 1-[4-[[(4-acetylphenyl)methyl-undec-10-enylamino]methyl]phenyl]ethanone
• CAS: 1242054-48-3
• 化学式: C₂₉H₃₉NO₂
• 分子量: 433.634
• InChiKey: JHFBXFPGKQAEAB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  32
• 可旋转键数：
  16
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.45
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  N,N-bis(4-(2-methyl-1,3-dioxolan-2-yl)benzyl)undec-10-en-1-amine 在 水 、 对甲苯磺酸 作用下， 以 丙酮 为溶剂， 反应 72.0h， 以90%的产率得到1-[4-[[(4-Acetylphenyl)methyl-undec-10-enylamino]methyl]phenyl]ethanone
  参考文献：
  名称：

  Preparation of multifunctional supported metallocene catalyst using organic multifunctional modifier for synthesizing polyethylene/clay nanocomposites via in situ intercalative polymerization

  摘要：

  A new type of multifunctional ammonium modifier with carbonyl group and vinyl group was synthesized to prepare multifunctional montmorillonites (F-MMTs), which were used as multifunctional catalyst supports for in situ ethylene polymerization. High loading of metallocene catalyst in the galleries of F-MMT had been achieved due to the presence of carbonyl group in the multifunctional modifier. XRD profiles and TEM images showed that polyethylene/montmorillonite (PE/F-MMT) nanocomposites with exfoliated structure could be synthesized using the intercalated catalyst described above, even when the content of MMT was very high (more than 15.1 wt%). The as-produced PE/F-MMTs nanocomposites were composed of flower-like particles with a diameter of about 5 pm. A thermal stable monoclinic phase was observed in PE/F-MMT nanocomposites. Comparatively, the resultant PE/F-MMT nanocomposites showed low gas permeability. Interfacial interaction between PE matrix and F-MMT was enhanced due to the chemical linking between the two components via copolymerization of ethylene with vinyl group of F-MMT. Thus the resultant PE/F-MMT nanocomposites showed good structural stability. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2010.05.041

文献信息

• Preparation of multifunctional supported metallocene catalyst using organic multifunctional modifier for synthesizing polyethylene/clay nanocomposites via in situ intercalative polymerization
  作者：Changyi Ren、Xiaohua Du、Li Ma、Yanhui Wang、Jun Zheng、Tao Tang

  DOI：10.1016/j.polymer.2010.05.041

  日期：2010.7

  A new type of multifunctional ammonium modifier with carbonyl group and vinyl group was synthesized to prepare multifunctional montmorillonites (F-MMTs), which were used as multifunctional catalyst supports for in situ ethylene polymerization. High loading of metallocene catalyst in the galleries of F-MMT had been achieved due to the presence of carbonyl group in the multifunctional modifier. XRD profiles and TEM images showed that polyethylene/montmorillonite (PE/F-MMT) nanocomposites with exfoliated structure could be synthesized using the intercalated catalyst described above, even when the content of MMT was very high (more than 15.1 wt%). The as-produced PE/F-MMTs nanocomposites were composed of flower-like particles with a diameter of about 5 pm. A thermal stable monoclinic phase was observed in PE/F-MMT nanocomposites. Comparatively, the resultant PE/F-MMT nanocomposites showed low gas permeability. Interfacial interaction between PE matrix and F-MMT was enhanced due to the chemical linking between the two components via copolymerization of ethylene with vinyl group of F-MMT. Thus the resultant PE/F-MMT nanocomposites showed good structural stability. (C) 2010 Elsevier Ltd. All rights reserved.