2-hydroxy-5-benzyloxyphenyl-O-β-D-glucopyranoside | 1053700-12-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-hydroxy-5-benzyloxyphenyl-O-β-D-glucopyranoside
• 英文别名: (2R,3S,4S,5R,6S)-2-(hydroxymethyl)-6-(2-hydroxy-5-phenylmethoxyphenoxy)oxane-3,4,5-triol
• CAS: 1053700-12-1
• 化学式: C₁₉H₂₂O₈
• 分子量: 378.379
• InChiKey: WEHUJYWBAJDXTC-UJWQCDCRSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.1
• 重原子数：
  27
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.37
• 拓扑面积：
  129
• 氢给体数：
  5
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  2-hydroxy-5-benzyloxyphenyl-O-β-D-glucopyranoside 在 palladium dihydroxide 、 环己烯 作用下， 以 乙醇 为溶剂， 反应 3.0h， 生成 2,5-dihydroxyphenyl-O-β-D-glucopyranoside
  参考文献：
  名称：

  Polyphenolic Glycosides from African Proteaceae

  摘要：

  The phytochemical investigation of members of the genus Protea afforded a series of polyphenolic compounds (1-5) that were identified by 1D and 2D NMR experiments. Of these, 2-5 are new compounds. Chemical syntheses of 1-3 were performed in order to confirm the structures and to prepare additional material for biological evaluation.

  DOI：

  10.1021/np9902237
• 作为产物：
  描述：

  5-(苄氧基)-2-甲氧基苯酚 在 sodium hydroxide 、 sodium thioethoxide 、 苄基三乙基溴化铵 作用下， 以 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 13.0h， 生成 2-hydroxy-5-benzyloxyphenyl-O-β-D-glucopyranoside
  参考文献：
  名称：

  Polyphenolic Glycosides from African Proteaceae

  摘要：

  The phytochemical investigation of members of the genus Protea afforded a series of polyphenolic compounds (1-5) that were identified by 1D and 2D NMR experiments. Of these, 2-5 are new compounds. Chemical syntheses of 1-3 were performed in order to confirm the structures and to prepare additional material for biological evaluation.

  DOI：

  10.1021/np9902237

文献信息

• Polyphenolic Glycosides from African Proteaceae
  作者：L. Verotta、F. Orsini、F. Pelizzoni、G. Torri、C. B. Rogers

  DOI：10.1021/np9902237

  日期：1999.11.1

  The phytochemical investigation of members of the genus Protea afforded a series of polyphenolic compounds (1-5) that were identified by 1D and 2D NMR experiments. Of these, 2-5 are new compounds. Chemical syntheses of 1-3 were performed in order to confirm the structures and to prepare additional material for biological evaluation.