6-Hexyl-2-methylcyclohepta-1,4-diene | 921819-66-1

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 6-Hexyl-2-methylcyclohepta-1,4-diene
• 英文别名: 6-hexyl-2-methylcyclohepta-1,4-diene
• CAS: 921819-66-1
• 化学式: C₁₄H₂₄
• 分子量: 192.345
• InChiKey: PJQIOAMOCZYODL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  14
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  以 N,N-二甲基甲酰胺 为溶剂， 反应 1.0h， 生成 6-Hexyl-2-methylcyclohepta-1,4-diene 、 (5E)-3-methylidenetrideca-1,5-diene
  参考文献：
  名称：

  Cyclopropyl carbenoid insertion into alkenylzirconocenes—a convergent synthesis of alkenylcyclopropanes and alkylidenecyclopropanes

  摘要：

  The insertion of cyclopropyl carbenoids into alkenylzirconocenes, derived by hydrozirconation of terminal alkynes, affords allylzirconium species which react with protons and isonitriles to afford alkenylcyclopropanes, and with aldehydes to afford alkylidene cyclopropanes. The addition of lithium carbenoid to zirconium occurs with the inversion of the organolithium centre. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2006.10.132

文献信息

• Cyclopropyl carbenoid insertion into alkenylzirconocenes—a convergent synthesis of alkenylcyclopropanes and alkylidenecyclopropanes
  作者：Emma Thomas、Alexander N. Kasatkin、Richard J. Whitby

  DOI：10.1016/j.tetlet.2006.10.132

  日期：2006.12

  The insertion of cyclopropyl carbenoids into alkenylzirconocenes, derived by hydrozirconation of terminal alkynes, affords allylzirconium species which react with protons and isonitriles to afford alkenylcyclopropanes, and with aldehydes to afford alkylidene cyclopropanes. The addition of lithium carbenoid to zirconium occurs with the inversion of the organolithium centre. (c) 2006 Elsevier Ltd. All rights reserved.