3-戊基-2-硫代噻唑烷-4-酮 | 56347-25-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑烷类
• 中文名称: 3-戊基-2-硫代噻唑烷-4-酮
• 英文名称: 3-n-Pentyl-4-oxo-thiazolidin-2-thion
• 英文别名: 3-pentylrhodanin；3-pentyl-2-thioxo-thiazolidin-4-one；3-(n-Pentyl)-rhodanin；3-Pentyl-2-sulfanylidene-1,3-thiazolidin-4-one
• CAS: 56347-25-2
• 化学式: C₈H₁₃NOS₂
• 分子量: 203.329
• InChiKey: AKTPBPSFULBPGQ-UHFFFAOYSA-N

物化性质

• 沸点：
  110 °C(Press: 0.5 Torr)
• 密度：
  1.22±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.6
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  77.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  3-戊基-2-硫代噻唑烷-4-酮 在 selenium 作用下， 以 乙醇 、 乙酸酐 为溶剂， 反应 3.0h， 生成 3-pentyl-5-benzylidene-2-selenorhodanine
  参考文献：
  名称：

  Tejchman, W.; Korohoda, M. J., Polish Journal of Chemistry, 1999, vol. 73, # 8, p. 1315 - 1322

  摘要：

  DOI：
• 作为产物：
  描述：

  1-溴戊烷 、 2-thioxo-4-thiazolidinone N-potassium salt 以 N,N-二甲基甲酰胺 为溶剂， 以44.1%的产率得到3-戊基-2-硫代噻唑烷-4-酮
  参考文献：
  名称：

  Design, synthesis and photophysical properties of A-D-A-D-A small molecules for photovoltaic application

  摘要：

  A series of linear-conjugated small molecule compounds featured with the acceptor-donor-acceptor-donor-acceptor (A-D-A-D-A) structure were designed, synthesized and characterized. The films of the compounds showed a broad UV-Vis absorption range of 300-800 nm with high molar absorption coefficient of more than 1.0 x 10(4) cm(-1). Their hole-mobility can be as high as 1.0 x 10(-3) cm(2) V-1 s(-1). The compounds have a compatible HOMO energy level of -5.0 eV to PC71BM and a high solubility up to 20 mg mL(-1) in chloroform. Therefore, compounds can blend with PC71BM in the chloroform and form an active layer for a photovoltaic cell device by spin-coating of the blend solution. A maximum power conversion efficiency of 3.2% was achieved with the DERH3TT solar cell device. These results indicate that the A-D-A-D-A small molecules with electron-withdrawing dyes as terminals are promising candidates for the high efficiency solution processed organic photovoltaic cells. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2015.05.009

文献信息

• [EN] INHIBITORS OF BACTERIAL BIOFILM FORMATION<br/>[FR] INHIBITEURS DE LA FORMATION DE BIOFILM BACTÉRIEN
  申请人：MICROBIOTIX INC

  公开号：WO2009142720A1

  公开（公告）日：2009-11-26

  Organic compounds are described for use in inhibiting or preventing formation of bacterial biofilms.

  有机化合物被描述为用于抑制或预防细菌生物膜的形成。
• COMPOSITION, CURED FILM, NEAR INFRARED RAY ABSORPTION FILTER, SOLID-STATE IMAGING DEVICE, INFRARED SENSOR, AND COMPOUND
  申请人：FUJIFILM Corporation

  公开号：US20170137444A1

  公开（公告）日：2017-05-18

  It is possible to provide a composition that has absorption in a near infrared region and that can form a film having transparency in a visible region. Provided are a cured film, a near infrared ray absorption filter, a solid-state imaging device, an infrared sensor, and a compound. Provided is a composition including: a near infrared ray absorption substance of which a maximum absorption wavelength is in a wavelength range of 700 to 1,000 nm and a value obtained by dividing absorbance at a wavelength of 550 nm by absorbance at the maximum absorption wavelength is 0.015 or less. In the near infrared ray absorption substance, a half-width of the maximum absorption wavelength is preferably 60 nm or less. The near infrared ray absorption substance is preferably a compound having a pyrrolopyrrole skeleton and more preferably a pyrrolopyrrole boron compound.

  可以提供一种在近红外区域具有吸收并且可以形成具有可见区域透明度的薄膜的组合物。提供了一种固化膜、近红外线吸收滤光片、固态成像装置、红外线传感器和化合物。提供的组合物包括：一种近红外线吸收物质，其最大吸收波长位于700至1,000 nm的波长范围内，且在550 nm波长处的吸光度除以最大吸收波长处的吸光度的值为0.015或以下。在近红外线吸收物质中，最大吸收波长的半峰宽最好为60 nm或以下。近红外线吸收物质最好是具有吡咯吡咯骨架的化合物，更好的是吡咯吡咯硼化合物。
• Novel methine compound, material for organic luminescence element, and organic luminescence element using the same
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：US20030080323A1

  公开（公告）日：2003-05-01

  Disclosed is a novel methine compound, for examples, which is represented by the following formula (I): 1 wherein R 1 , R 2 , R 3 , R 4 and R 5 each represents a hydrogen atom or a substituent; X represents an oxygen atom, a sulfur atom, or N—R 6 ; Z represents —NR 7 R 8 , or —OG; R 6 , R 7 and R 8 each represents a hydrogen atom or a substituent; G represents a hydrogen atom, a cation or a substituent; L 1 , L 2 and L 3 each represents a substituted or unsubstituted methine group; n represents 1 or 2; and W represents an electron attractive group. Also, a material for organic luminescence element and organic luminescence element using the same are disclosed.

  本发明涉及一种新型的甲烷化合物，例如，其由以下公式（I）表示：其中R1、R2、R3、R4和R5分别表示氢原子或取代基；X表示氧原子、硫原子或N-R6；Z表示-NR7R8或-OG；R6、R7和R8各表示氢原子或取代基；G表示氢原子、阳离子或取代基；L1、L2和L3各表示取代或未取代的甲烷基；n表示1或2；W表示电子亲和力基团。此外，还公开了一种用于有机发光元件的材料和使用该材料的有机发光元件。
• INHIBITORS OF BACTERIAL BIOFILM FORMATION
  申请人：Opperman Timothy J.

  公开号：US20110098323A1

  公开（公告）日：2011-04-28

  Organic compounds are described for use in inhibiting or preventing formation of bacterial biofilms.

  有机化合物被描述为用于抑制或预防细菌生物膜的形成。
• Method for measurement of trace enzymes
  申请人：FUJI PHOTO FILM CO., LTD.

  公开号：EP0048834A1

  公开（公告）日：1982-04-07

  The amount of enzyme is determined by reacting an enzyme to be measured with a synthetic substrate having at least one structure to be specifically contacted with the enzyme and at least one spectral sensitizer structure, bringing either the reaction product having the spectral sensitizer structure or the unreacted synthetic substrate into contact with a silver halide emulsion layer, exposing the same to light of a spectral sensitizing wavelength region corresponding to the spectral sensitizer structure, developing the silver halide, and then measuring the optical density of developed silver and/or colored dye.

  酶量的测定方法是：将待测酶与具有至少一种与酶特异性接触的结构和至少一种光谱增感剂结构的合成底物反应，使具有光谱增感剂结构的反应产物或未反应的合成底物与卤化银乳剂层接触，将其暴露于与光谱增感剂结构相对应的光谱增感波长区域的光下，显影卤化银，然后测量显影银和/或有色染料的光密度。