| 727986-12-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• CAS: 727986-12-1
• 化学式: C₂H₃N*C₈H₂₀N*C₃₇H₂₆FeN₆O₂
• 分子量: 813.805
• InChiKey: XRHSDYKWPXNVET-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  iron(II) chloride tetrahydrate 、 氰化四乙基铵 、 2,2'-dibenzyl-N,N'-bis(8-quinolyl)malonamide 、 乙腈 在 C₆H₄FN₂PF₆ 、 (C₂H₅)3N 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以90%的产率得到
  参考文献：
  名称：

  Synthesis, structure and catalytic activity of low-spin dicyano iron(III) complexes of N,N′-bis(quinolyl)malonamide derivatives

  摘要：

  Two low-spin Fe(III) dicyano-dicarboxamido, complexes have been prepared from N,N'-bis(8-quinolyl)malonamide derivatives. Crystal structures show that the four nitrogen donors available to complex the metal are arranged in the equatorial plane with the two cyanides trans to each other in the axial positions when the malonyl moiety is disubstituted. In contrast, the unsubstituted malonyl results in only three nitrogens in the equatorial plane with the fourth in an apical position and the two cyanides occupying cis sites, one equatorial and the other axial. NMR analyses show that the solid state structure of both complexes is retained in solution. Both types of configurational complexes catalyze cyclic olefin oxidations with H2O2 but only the cis-dicyano complex catalyzes stilbene oxidation with formation of epoxides, diols and benzaldehyde. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.01.019