[1-Trimethylsilanyl-meth-(E)-ylidene]-(2,4,6-tris-trifluoromethyl-phenyl)-phosphane | 156430-82-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [1-Trimethylsilanyl-meth-(E)-ylidene]-(2,4,6-tris-trifluoromethyl-phenyl)-phosphane
• CAS: 156430-82-9
• 化学式: C₁₃H₁₂F₉PSi
• 分子量: 398.283
• InChiKey: FNWSHOLLNBZXCD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.99
• 重原子数：
  24.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  dichloro-bis(triethylphosphine)-di-μ-chloro-diplatinum(II) 、 [1-Trimethylsilanyl-meth-(E)-ylidene]-(2,4,6-tris-trifluoromethyl-phenyl)-phosphane 以 四氢呋喃 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of some phospha-alkenes with the fluoromesityl (2,4,6-(CF3)3C6H2) group on phosphorus and of their complexes with [PtCl2(PEt3)]2

  摘要：

  The phospha-alkenes ArP=CR1R2, where Ar = 2,4,6-(CF3)3C6H2, and R1 = R2 = Cl (1), R1 = SiMe3, R2 = H (2), or R1 = Ph, R2 = H (3), have been synthesized. Compound 1 was isolated and fully characterized, but 3 could only be identified in solution. All three phospha-alkenes react with the dimeric species [PtCl2(PEt3)]2 in a 2:1 ratio to form eta1-bonded platinum(II) complexes, the structures of which may be readily deduced from the nuclear magnetic resonance data.

  DOI：

  10.1016/0022-328x(94)80087-1
• 作为产物：
  描述：

  Dichlor-<2,4,6-tris(trifluormethyl)phenyl>phosphan 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 、 cadmium(II) chloride 作用下， 以 四氢呋喃 为溶剂， 反应 5.0h， 生成 [1-Trimethylsilanyl-meth-(E)-ylidene]-(2,4,6-tris-trifluoromethyl-phenyl)-phosphane
  参考文献：
  名称：

  Synthesis of some phospha-alkenes with the fluoromesityl (2,4,6-(CF3)3C6H2) group on phosphorus and of their complexes with [PtCl2(PEt3)]2

  摘要：

  The phospha-alkenes ArP=CR1R2, where Ar = 2,4,6-(CF3)3C6H2, and R1 = R2 = Cl (1), R1 = SiMe3, R2 = H (2), or R1 = Ph, R2 = H (3), have been synthesized. Compound 1 was isolated and fully characterized, but 3 could only be identified in solution. All three phospha-alkenes react with the dimeric species [PtCl2(PEt3)]2 in a 2:1 ratio to form eta1-bonded platinum(II) complexes, the structures of which may be readily deduced from the nuclear magnetic resonance data.

  DOI：

  10.1016/0022-328x(94)80087-1