2,9,16,23-tetrakis[4-[4-(trifluoromethyl)phenoxy]phenoxy]phthalocyaninato cobalt(II) | 1357284-50-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 2,9,16,23-tetrakis[4-[4-(trifluoromethyl)phenoxy]phenoxy]phthalocyaninato cobalt(II)
• CAS: 1357284-50-4
• 化学式: C₈₄H₄₄CoF₁₂N₈O₈
• 分子量: 1580.3
• InChiKey: AMMRNQPCMHTAEV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-(4-[4-(trifluoromethyl)phenoxy]phenoxy)phthalonitrile 在 cobalt(II) chloride 作用下， 以 N,N-二甲基乙醇胺 为溶剂， 反应 48.0h， 生成 、 、 2,9,16,23-tetrakis[4-[4-(trifluoromethyl)phenoxy]phenoxy]phthalocyaninato cobalt(II) 、
  参考文献：
  名称：

  Synthesis and electronic absorption studies of novel (trifluoromethyl)phenoxy-substituted phthalocyanines

  摘要：

  The reaction of 4-[4-(trifluoromethyl)phenoxy]phenol with 4-nitrophthalonitrile in the presence of K2CO3 leads to formation of 4-[4-[4-(trifluoromethyl)phenoxy]phenoxy]phthalonitrile. Tetrakis[4-[4-(trifluoromethyl)phenoxy]phenoxy]-substituted metal-free phthalocyanine was achieved by tetramerization of the phthalonitrile in 2-(dimethylamino)ethanol, whereas metallophthalocyanines were prepared in the presence of zinc, cobalt, or copper salts. These compounds show high solubility in weakly and medium polar solvents, in strongly polar solvents (dimethylformamide, dimethylsulfoxide), and in aromatic hydrocarbons (toluene, benzene). The new phthalocyanines were characterized by elemental analyses, H-1 nuclear magnetic resonance (NMR), C-13 NMR, F-19 NMR, ultraviolet-visible (UV-Vis), Fourier-transform infrared (FT-IR), and mass spectroscopic methods.

  DOI：

  10.1007/s00706-011-0614-3