[Mn2(4-chlorophenyloxyacetic acid)4(1,10-phenanthroline)2] | 1454271-03-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Mn2(4-chlorophenyloxyacetic acid)4(1,10-phenanthroline)2]
• 英文别名: dimanganese(II)(4-chlorophenyloxyacetic acid)₄(1,10-phenanthroline)₂；[Mn₂(4-chlorophenyloxyacetic acid)₄(1,10-phenanthroline)₂]
• CAS: 1454271-03-4
• 化学式: C₅₆H₄₀Cl₄Mn₂N₄O₁₂
• 分子量: 1212.64
• InChiKey: SAKQJZWOJPHCCK-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  对氯苯氧乙酸 、 1,10-菲罗啉 、 manganese(II) chloride tetrahydrate 在 水 、 sodium hydroxide 作用下， 以 乙醇 为溶剂， 反应 72.0h， 以65%的产率得到[Mn2(4-chlorophenyloxyacetic acid)4(1,10-phenanthroline)2]
  参考文献：
  名称：

  Hydrothermal Synthesis, Crystal Structure of Five Novel Complexes Based on 4-Chlorophenyloxyacetic Acid

  摘要：

  Five new metalorganic complexes of the formula [Pb3L5(2,2-bipy)(2)(NO3)(H2O)] (n) 1, [Cd2L4(1,10-Phenanthroline)(2)] 2, [Mn2L4(1,10-Phenanthroline)(2)] 3, [Mn3L6(2,2-bipy)(2)] 4, and [PbL2(H2O)] (n) 5 [HL = 4-chlorophenyloxyacetic acid] have been synthesized and characterized by IR method, elemental analysis, X-ray powder diffraction (XRPD) analysis, fluorescence spectroscopy method, and single-crystal X-ray diffraction techniques. X-ray structure analysis reveals that complex 1 is 1D chain polymer, complex 5 is 2D network polymer, while complex 2, 3, and 4 are all 0D structure. The L ligand have many kinds of coordination mode, which make these complexes have different configuration. The weak CH center dot center dot center dot O and interactions are also very important, the mononuclear or multinuclear crystal units of these complexes can be packed through them. Moreover, all these complexes are exhibit fluorescence.

  DOI：

  10.1080/03610918.2013.767739