11,11,12,12,13,13,14,14,14-nonafluoro-9-iodotetradecan-1-ol | 1224621-47-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 11,11,12,12,13,13,14,14,14-nonafluoro-9-iodotetradecan-1-ol
• 英文别名: 11,11,12,12,13,13,14,14,14-nonafluoro-9-iodo-1-tetradecanol
• CAS: 1224621-47-9
• 化学式: C₁₄H₂₀F₉IO
• 分子量: 502.202
• InChiKey: OLEIYGXRNKCBOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.5
• 重原子数：
  25
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  11,11,12,12,13,13,14,14,14-nonafluoro-9-iodotetradecan-1-ol 在 lithium aluminium tetrahydride 、 四丁基溴化铵 、 三苯基膦 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 14.0h， 生成 11,11,12,12,13,13,14,14,14-nonafluorotetradecyl bromide
  参考文献：
  名称：

  用于全氟萘烷的新型荧光胶凝剂

  摘要：

  使用化学合成的氟胶凝剂制备全氟萘烷（PFD）的荧光凝胶。为了增强胶凝剂的亲氟性，将氟烷基链引入已知胶凝剂的烷基链中。合成的含氟代烷基的蒽醌形成PFD凝胶。所制备的PFD凝胶用于细胞培养，并鉴于其潜在的生物医学应用对其凝胶的细胞毒性进行了评估。

  DOI：

  10.1016/j.jfluchem.2019.04.008
• 作为产物：
  描述：

  9-十烯-1-醇 、 全氟碘代丁烷 在 sodium dithionate 、 碳酸氢钠 作用下， 以 水 、 乙腈 为溶剂， 反应 4.0h， 以96.9%的产率得到11,11,12,12,13,13,14,14,14-nonafluoro-9-iodotetradecan-1-ol
  参考文献：
  名称：

  用于全氟萘烷的新型荧光胶凝剂

  摘要：

  使用化学合成的氟胶凝剂制备全氟萘烷（PFD）的荧光凝胶。为了增强胶凝剂的亲氟性，将氟烷基链引入已知胶凝剂的烷基链中。合成的含氟代烷基的蒽醌形成PFD凝胶。所制备的PFD凝胶用于细胞培养，并鉴于其潜在的生物医学应用对其凝胶的细胞毒性进行了评估。

  DOI：

  10.1016/j.jfluchem.2019.04.008

文献信息

• Indium-mediated radical addition of perfluoroalkyl iodide in water
  作者：Toshiyuki Takagi、Toshiyuki Kanamori

  DOI：10.1016/j.jfluchem.2011.03.001

  日期：2011.6

  Reaction of perfluoroalkyl groups with carbon–carbon unsaturated compounds using indium in water proceeded smoothly to provide the addition products in high yields.

  在水中使用铟，全氟烷基与碳-碳不饱和化合物的反应进展顺利，从而以高收率提供了加成产物。
• Metal-Free Activation of C–I Bonds and Perfluoroalkylation of Alkenes with Visible Light Using Phosphine Catalysts
  作者：Lucas Helmecke、Michael Spittler、Kai Baumgarten、Constantin Czekelius

  DOI：10.1021/acs.orglett.9b02812

  日期：2019.10.4

  An efficient metal-free, photomediated iodo perfluoroalkylation under mild conditions was developed. Using catalytic amounts (10 mol %) of phosphines and blue light irradiation, various olefins are transformed into the corresponding addition products within short reaction times. For this purpose, a modular and convenient 3D printed photoreactor was constructed, which is presented as an open source model. The reaction presumably proceeds upon generation of perfluoroalkyl radicals, which are formed by catalyst-induced absorption enhancement.
• LIQUID CRYSTALLINE BLENDS, DEVICE THEREOF AND METHOD THEREOF
  申请人：Li Quan

  公开号：US20110023946A1

  公开（公告）日：2011-02-03

  The invention provides liquid crystalline blends, a device such as a photovoltaic cell using the blend and method thereof. A liquid crystalline blend comprises at least an electron donor and at least an electron acceptor with a weight or molar ratio in the range of from about 1:20 to about 20:1. Another liquid crystalline blend comprises at least an electron donor and at least an electron acceptor, wherein the electron donor, the electron acceptor, or both is (are) halo-substituted such as F-substituted. The donor or the electron acceptor can be excited by an electromagnetic radiation such as solar light to induce electron transfer between the donor and the acceptor. The photovoltaic cell is improved in that favorable molecular arrangement in the blend gives more interfaces between the donor and the acceptor and thus a viable path for dissociation and electrons and/or holes; as well as larger light-harvesting area toward the coming light.
• US8241522B2
  申请人：——

  公开号：US8241522B2

  公开（公告）日：2012-08-14
• [EN] LIQUID CRYSTALLINE BLENDS, DEVICE THEREOF AND METHOD THEREOF<br/>[FR] MÉLANGES DE CRISTAUX LIQUIDES, DISPOSITIF ET PROCÉDÉ ASSOCIÉS
  申请人：UNIV KENT STATE OHIO

  公开号：WO2010047864A1

  公开（公告）日：2010-04-29

  The invention provides liquid crystalline blends, a device such as a photovoltaic cell using the blend and method thereof