(R)-methylphenyl-(8-quinolyl)phosphine | 80183-97-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: (R)-methylphenyl-(8-quinolyl)phosphine
• 英文别名: (R)-methyl-phenyl-quinolin-8-ylphosphane
• CAS: 80183-97-7
• 化学式: C₁₆H₁₄NP
• 分子量: 251.268
• InChiKey: NNPSBKICJUNOQS-GOSISDBHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 (R)-methylphenyl-(8-quinolyl)phosphine 在 Na₂CO₃ 、 HCl 作用下， 以 甲醇 为溶剂， 以85%的产率得到{SP-4-3-(S)}-(+)dichloro{methylphenyl(8-quinolyl)phosphine-P,N}platinum(II)-dichloromethane
  参考文献：
  名称：

  Salem, Geoffrey; Wild, S. Bruce, Inorganic Chemistry, 1992, vol. 31, # 4, p. 581 - 586

  摘要：

  DOI：

文献信息

• Biaryl ligands, methods of making biaryl ligands, and methods of use thereof
  申请人：University of Florida Research Foundation, Inc.

  公开号：US10618922B2

  公开（公告）日：2020-04-14

  Embodiments of the present disclosure provide for biaryl ligands (also referred to herein as “biaryl compound”), biaryl complexes, methods of making biaryl compounds, methods of making single enantiomers of these biaryl compounds, methods of use (e.g., catalysis), and the like.

  本公开的实施方案提供了双芳基配体（此处也称为 "双芳基化合物"）、双芳基络合物、双芳基化合物的制造方法、这些双芳基化合物的单一对映体的制造方法、使用方法（例如催化）等。
• Biaryl ligands, methods of making biarlyl ligands, and methods of use thereof
  申请人：University of Florida Research Foundation, Inc.

  公开号：US11198701B2

  公开（公告）日：2021-12-14

  Embodiments of the present disclosure provide for biaryl ligands (also referred to herein as “biaryl compound”), biaryl complexes, methods of making biaryl compounds, methods of making single enantiomers of these biaryl compounds, methods of use (e.g., catalysis), and the like.

  本公开的实施方案提供了双芳基配体（此处也称为 "双芳基化合物"）、双芳基络合物、双芳基化合物的制造方法、这些双芳基化合物的单一对映体的制造方法、使用方法（例如催化）等。
• BIARYL LIGANDS
  申请人：THE UNIVERSITY OF FLORIDA RESEARCH FOUNDATION INC.

  公开号：US20160222041A1

  公开（公告）日：2016-08-04

  Embodiments of the present disclosure provide for biaryl ligands (also referred to herein as “biaryl compound”), biaryl complexes, methods of making biaryl compounds, methods of making single enantiomers of these biaryl compounds, methods of use (e.g., catalysis) and the like.
• BIARYL LIGANDS, METHODS OF MAKING BIARYL LIGANDS, AND METHODS OF USE THEREOF
  申请人：University of Florida Research Foundation, Inc.

  公开号：US20180282355A1

  公开（公告）日：2018-10-04

  Embodiments of the present disclosure provide for biaryl ligands (also referred to herein as “biaryl compound”), biaryl complexes, methods of making biaryl compounds, methods of making single enantiomers of these biaryl compounds, methods of use (e.g., catalysis), and the like.
• BIARYL LIGANDS, METHODS OF MAKING BIARLYL LIGANDS, AND METHODS OF USE THEREOF
  申请人：University of Florida Research Foundation, Inc.

  公开号：US20200223878A1

  公开（公告）日：2020-07-16

  Embodiments of the present disclosure provide for biaryl ligands (also referred to herein as “biaryl compound”), biaryl complexes, methods of making biaryl compounds, methods of making single enantiomers of these biaryl compounds, methods of use (e.g., catalysis), and the like.