2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl 2,2,2-trichloroacetimidate | 324041-49-8

分子结构分类

有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物

中文名称

——

中文别名

——

英文名称

2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl 2,2,2-trichloroacetimidate

英文别名

2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl trichloroacetimidate；2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl,trichloroacetamidate；Bz(-3)[Bz(-4)][Bz(-6)]Man2Ac(a)-O-C(NH)CCl3；[(2R,3R,4S,5S,6R)-5-acetyloxy-3,4-dibenzoyloxy-6-(2,2,2-trichloroethanimidoyl)oxyoxan-2-yl]methyl benzoate

2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl 2,2,2-trichloroacetimidate化学式

CAS

324041-49-8

化学式

C₃₁H₂₆Cl₃NO₁₀

mdl

——

分子量

678.907

InChiKey

IMYOEWKGDPJXJQ-SSBCBVQQSA-N

BEILSTEIN

——

EINECS

——

计算性质

辛醇/水分配系数(LogP)：

7.5
重原子数：

45
可旋转键数：

14
环数：

4.0
sp3杂化的碳原子比例：

0.26
拓扑面积：

148
氢给体数：

1
氢受体数：

11

上下游信息

上游原料

中文名称	英文名称	CAS号	化学式	分子量
——	1,2-di-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranose	374078-96-3	C₃₁H₂₈O₁₁	576.557
——	2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranose	374078-97-4	C₂₉H₂₆O₁₀	534.519
——	3,4,6-tri-O-benzoyl-1,2-O-[(RS)-1-methoxyethane-1,1-diyl]-β-D-mannopyranose	324041-25-0	C₃₀H₂₈O₁₀	548.546
——	2,3,4,6-Tetra-O-benzoyl-α-D-mannopyranosyl bromide	——	C₃₄H₂₇BrO₉	659.487

下游产品

中文名称	英文名称	CAS号	化学式	分子量
——	methyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->6)-2,3-di-O-benzoyl-α-D-mannopyranoside	618106-80-2	C₅₀H₄₆O₁₇	918.905
——	methyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-α-D-mannopyranoside	618106-81-3	C₅₇H₅₀O₁₈	1023.01
——	allyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1-> 6)-3-O-benzoyl-2-O-chloroacetyl-α-D-mannopyranoside	743432-00-0	C₄₇H₄₅ClO₁₇	917.317
——	allyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranoside	324041-42-1	C₃₂H₃₀O₁₀	574.584
——	methyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->3)-4,6-O-isopropylidene-α-D-mannopyranosyl-(1->3)-4,6-O-isopropylidene-α-D-mannopyranoside	539824-98-1	C₄₈H₅₆O₂₀	952.961
——	methyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->3)-2-O-acetyl-4,6-O-isopropylidene-α-D-mannopyranosyl-(1->3)-2-O-acetyl-4,6-O-isopropylidene-α-D-mannopyranoside	539824-99-2	C₅₂H₆₀O₂₂	1037.04
——	allyl (2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranoside	324041-19-2	C₅₉H₅₂O₁₈	1049.05
——	methyl 3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->6)-2,4-di-O-benzoyl-α-D-mannopyranoside	334697-24-4	C₄₈H₄₄O₁₆	876.868
——	methyl 3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->6)-2,3,4-tri-O-benzoyl-α-D-mannopyranoside	618106-82-4	C₅₅H₄₈O₁₇	980.976
——	octyl 2,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranoside	697765-22-3	C₆₂H₆₂O₁₇	1079.16
——	octyl 3,4,6-tri-O-benzoyl-α-D-mannopyranoside	697765-15-4	C₃₅H₄₀O₉	604.697
——	(2R,3S,4S,5R,6R)-6-((((2S,3S,4S,5R,6R)-3-acetoxy-4,5-bis(benzoyloxy)-6-((benzoyloxy)methyl)tetrahydro-2H-pyran-2-yl)oxy)methyl)tetrahydro-2H-pyran-2,3,4,5-tetrayl tetrabenzoate	879126-25-7	C₆₃H₅₂O₁₉	1113.09
——	allyl (3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranoside	324041-21-6	C₅₇H₅₀O₁₇	1007.01
——	8-azidooctyl (3,4,6-tri-O-benzoyl-α-D-mannopyranosyl)-(1->6)-2,3,4-tri-O-benzoyl-α-D-mannopyranoside	1283579-24-7	C₆₂H₆₁N₃O₁₇	1120.18
——	octyl 2,4,6-tri-O-benzoyl-3-O-(4-methoxybenzyl)-α-D-mannopyranosyl (1->2)-3,4,6-tri-O-benzoyl-α-D-mannopyranoside	697765-21-2	C₇₀H₇₀O₁₈	1199.32
——	Bz(-3)[Bz(-4)][Bz(-6)]Man(a1-6)[Bz(-2)][Bz(-3)][Bz(-4)]Man(a)-O-Bz	879126-26-8	C₆₁H₅₀O₁₈	1071.06
——	methyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->6)-2,4-di-O-benzoyl-3-O-tert-butyldimethylsilyl-α-D-mannopyranoside	334697-23-3	C₅₆H₆₀O₁₇Si	1033.17
——	phenyl 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1->2)-3,4,6-tri-O-benzoyl-1-thio-α-D-mannopyranoside	1332524-19-2	C₆₂H₅₂O₁₇S	1101.15

反应信息

作为反应物：

描述：

2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl 2,2,2-trichloroacetimidate 在盐酸、三氟甲磺酸三甲基硅酯作用下，以甲醇、二氯甲烷为溶剂，生成 Bz(-3)[Bz(-4)][Bz(-6)]Man(a1-6)[Bz(-2)][Bz(-3)][Bz(-4)]Man(a)-O-Bz

参考文献：

名称：

从克氏锥虫的脂质中含有不饱和脂肪酸的生物活性糖基磷脂酰肌醇的化学合成。

摘要：