2-(10-undecenyl)-tridec-12-en-1-ol | 274920-05-7

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• 英文名称: 2-(10-undecenyl)-tridec-12-en-1-ol
• 英文别名: 2-Undec-10-enyltridec-12-en-1-ol
• CAS: 274920-05-7
• 化学式: C₂₄H₄₆O
• 分子量: 350.629
• InChiKey: VOXLERWKGFPACK-UHFFFAOYSA-N

物化性质

• 沸点：
  439.3±14.0 °C(Predicted)
• 密度：
  0.849±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  25
• 可旋转键数：
  21
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(10-undecenyl)-tridec-12-en-1-ol 在 ammonium hexafluorophosphate 、 四溴化碳 、 三苯基膦 作用下， 以 四氢呋喃 、 二氯甲烷 、 丙酮 为溶剂， 生成
  参考文献：
  名称：

  Synthesis of Precision Ionic Polyolefins Derived from Ionic Liquids

  摘要：

  DOI：

  10.1021/ma9024174
• 作为产物：
  描述：

  10-十一烯-1-醇 在 吡啶 、 4-二甲氨基吡啶 、 lithium aluminium tetrahydride 、 水 、 sodium hydride 、 potassium hydroxide 、 萘烷 作用下， 以 四氢呋喃 、 乙醇 为溶剂， 生成 2-(10-undecenyl)-tridec-12-en-1-ol
  参考文献：
  名称：

  Synthesis of Precision Ionic Polyolefins Derived from Ionic Liquids

  摘要：

  DOI：

  10.1021/ma9024174

文献信息

• Polyethylene Based Bioactive Agents
  申请人：Leonard James Klein

  公开号：US20100255050A1

  公开（公告）日：2010-10-07

  The present invention concerns an acyclic diene metathesis (ADMET) chemistry-based method of making polymers incorporating biologically active molecules, and the polymers formed thereby. Functionalized polymers prepared by this method can be used to produce a broad range of commercially important products such as drag delivery agents (prodrugs), chromatography reagents (e.g., for use in separatory reagents), biomimetics, and biodegradable synthetic polymers.

  本发明涉及一种基于无环二烯重排(ADMET)化学的方法，用于制备包含生物活性分子的聚合物，以及由此形成的聚合物。通过该方法制备的功能化聚合物可用于生产广泛的商业重要产品，如药物输送剂(前药)，色谱试剂(例如，用于分离试剂)，仿生学和可生物降解的合成聚合物。
• Modeling Branched Polyethylene:  Copolymers Possessing Precisely Placed Ethyl Branches
  作者：John C. Sworen、Jason A. Smith、Jessica M. Berg、Kenneth B. Wagener

  DOI：10.1021/ja047850p

  日期：2004.9.1

  A structural investigation of precise ethylene/1-butene (EB) copolymers has been completed using step polymerization chemistry. The synthetic methodology needed to generate four model copolymers is described; their primary and higher level structure is characterized. The copolymers possess an ethyl branch on every 9th, 15th, and 21st carbon along the backbone of linear polyethylene. Melting points and heats of fusion decrease with increased branch frequency. Differential scanning calorimetry and infrared spectroscopy show highly disordered crystal structures favoring ethyl branch inclusion. On the other hand, the EB copolymers contain high concentrations of kink and gauche defects independent of branch frequency. These model copolymers are compared with random copolymers produced using traditional chain chemistry and previously synthesized ADMET EP copolymers.
• Precision Ionomers: Synthesis and Thermal/Mechanical Characterization
  作者：Brian S. Aitken、C. Francisco Buitrago、Jason D. Heffley、Minjae Lee、Harry W. Gibson、Karen I. Winey、Kenneth B. Wagener

  DOI：10.1021/ma202304s

  日期：2012.1.24

  Six perfectly regioregular polyethylene (PE)-based ionomers containing 1-methylimidazolium bromide groups on exactly every 9th, 15th, or 21st carbon (precision ionomers) and two regiorandom analogues have been synthesized and characterized via dynamic mechanical analysis (DMA) and differential scanning calorimetry (DSC). Because these materials were synthesized by a postpolymerization functionalization route, their number-average molecular weights (M(n)s) and polydispersity indices (PDIs) could be accurately calculated based on measurements of the preionized polymers; M(n)s range from 36 to 53 kDa with PDIs all close to 2. Thermal gravimetric analysis (TGA) indicates stability up 250 degrees C, and DSC measurements indicate that crystallinity is a function of the polymer backbone spacer length. T(m)s range from similar to 80 to 106 degrees C, with longer spacer lengths inducing semicrystallinity. DSC measured glass transition temperatures (T(g)s) range from -1.6 to 26.8 degrees C and appear to be dependent on both spacer length and crystallinity. DMA data loosely mirror the DSC results, but with transitions occurring at lower temperatures that we attribute to differences in the thermal history and/or the different heating ramp rates used.
• [EN] POLYETHYLENE BASED BIOACTIVE AGENTS<br/>[FR] AGENTS BIOACTIFS À BASE DE POLY(ÉTHYLÈNE)
  申请人：UNIV FLORIDA

  公开号：WO2009015274A2

  公开（公告）日：2009-01-29

  The present invention concerns an acyclic diene metathesis (ADMET) chemistry- based method of making polymers incorporating biologically active molecules, and the polymers formed thereby. Functionalized polymers prepared by this method can be used to produce a broad range of commercially important products such as drag delivery agents (prodrugs), chromatography reagents (e.g., for use in separatory reagents), biomimetics, and biodegradable synthetic polymers.