5-mercapto-1-methyltetrazole N-tetramethylammonium salt | 1358553-81-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 唑类
• 英文名称: 5-mercapto-1-methyltetrazole N-tetramethylammonium salt
• CAS: 1358553-81-7
• 化学式: C₂H₃N₄S*C₄H₁₂N
• 分子量: 189.285
• InChiKey: VQZTWWMWXCBNAN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.56
• 重原子数：
  12.0
• 可旋转键数：
  0.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  43.6
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  四甲基氢氧化铵 、 1-甲基-5-巯基-1H-四氮唑 以 甲醇 为溶剂， 反应 12.0h， 以95%的产率得到5-mercapto-1-methyltetrazole N-tetramethylammonium salt
  参考文献：
  名称：

  Efficient Dye-Sensitized Photovoltaic Wires Based on an Organic Redox Electrolyte

  摘要：

  An organic thiolate/disulfide redox couple with low absorption in the visible region was developed for use in fabricating novel dye-sensitized photovoltaic wires with an aligned carbon nanotube (CNT) fiber as the counter electrode. These flexible wire devices achieved a maximal energy conversion efficiency of 7.33%, much higher than the value of 5.97% for the conventional I-/I-3(-) redox couple. In addition, the aligned CNT fiber also greatly outperforms the conventional Pt counter electrode with a maximal efficiency of 2.06% based on the thiolate/disulfide redox couple.

  DOI：

  10.1021/ja405012w