Bis(2-quinolinecarboxylato-|EN1,|EO2)copper | 24476-79-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: Bis(2-quinolinecarboxylato-|EN1,|EO2)copper
• 英文别名: copper;quinoline-2-carboxylate
• CAS: 24476-79-7
• 化学式: C₂₀H₁₂CuN₂O₄
• 分子量: 407.872
• InChiKey: JLOULEJYJNBUMX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.19
• 重原子数：
  27
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  106
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  Bis(2-quinolinecarboxylato-|EN1,|EO2)copper 、 氯磺酸 、 氨 以82%的产率得到
  参考文献：
  名称：

  ESKSTEIN Z.; KANIK B.; LESZCZYNKSA E.; LIPEZYNSKA-KOCHANY E.; PAJAK J.; Z+, POL. J. CHEM., 1979, 53, NO 11, 2373-2377

  摘要：

  DOI：
• 作为产物：
  描述：

  quinaldinic acid, Na-salt 以 水 为溶剂， 生成 Bis(2-quinolinecarboxylato-|EN1,|EO2)copper
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B4, 118, page 1702 - 1704

  摘要：

  DOI：

文献信息

• Process for the preparation of pyridine-2,3-dicarboxylic acid
  申请人：Ruetgers-Nease Chemical Co., Inc.

  公开号：US04754039A1

  公开（公告）日：1988-06-28

  Pyridine-2,3-dicarboxylic acid can be prepared by oxidizing quinoline with a chlorate salt in an aqueous acidic medium. The oxidation can be conducted in the presence of cupric ions generated from an acid-soluble cupric compound.

  吡啶-2,3-二羧酸可以通过在水溶性酸性介质中使用氯酸盐氧化喹啉制备。在酸溶性铜化合物的存在下，氧化可以在产生的铜离子的存在下进行。
• ANTIFOULING PAINT COMPOSITIONS
  申请人：Mitsubishi Rayon Co., Ltd.

  公开号：EP1006156A1

  公开（公告）日：2000-06-07

  An antifouling paint composition comprising, as a vehicle, a copolymer from a monomer mixture comprising of (a1) a metal-containing polymerizable monomer having two unsaturated groups and (a2) a metal-containing polymerizable monomer represented by the following formula (I): wherein R1 represents a hydrogen atom or a methyl group; M represents Mg, Zn or Cu; and R2 represents an organic acid residue. An antifouling paint composition comprising, as a vehicle, a copolymer from a monomer mixture comprising (a) a metal-containing polymerizable monomer and (b) a polymerizable monomer represented by the following formula (II): wherein R3 reprsents a hydrogen atom or a methyl group: R4 represents an alkyl group having 1 to 10 carbon atoms, a cycloalkyl group or a phenyl group; and R5 represents an alkyl having 1 to 10 carbon atoms, a cycloalkyl group or a phenyl group.

  一种防污漆组合物，包括作为载体的由以下单体混合物组成的共聚物：(a1) 具有两个不饱和基团的含金属可聚合单体和(a2) 由下式(I)表示的含金属可聚合单体： 其中 R1 代表氢原子或甲基；M 代表镁、锌或铜；R2 代表有机酸残基。一种防污漆组合物，包括作为载体的由单体混合物制成的共聚物，该单体混合物包括(a) 含金属的可聚合单体和(b)由下式(II)代表的可聚合单体： 其中 R3 代表氢原子或甲基：R4 代表具有 1 至 10 个碳原子的烷基、环烷基或苯基；R5 代表具有 1 至 10 个碳原子的烷基、环烷基或苯基。
• Metal-containing monomer dissolved mixture, metal-containing resin and antifouling paint composition
  申请人：MITSUBISHI RAYON CO., LTD.

  公开号：EP1167398A2

  公开（公告）日：2002-01-02

  A metal-containing monomer dissolved mixture comprising a reaction product of an inorganic metal compound with a carboxyl group-containing radical polymerizable monomer, an organic solvent including at least an alcohol-based solvent, and water, wherein the water content is from 0.01 to 30% by weight; a metal-containing resin obtained by copolymerizing the metal-containing monomer (A) in this dissolved mixture with the other radical-polymerizable unsaturated monomer (B); an antifouling paint composition obtained by using this metal-containing resin; and an antifouling paint composition comprising a divalent metal-containing resin (C), a compound (D) of R1-SH (wherein, R1 represents an organic group having 1 to 30 carbon atoms.), and copper oxide (E), are disclosed.

  一种含金属单体的溶解混合物，包括无机金属化合物与含羧基可自由基聚合单体的反应产物、有机溶剂（至少包括醇基溶剂）和水，其中水含量为 0.本发明公开了一种无机金属化合物与含羧基的可自由基聚合单体和水的混合物，其中水含量为 0.01 至 30% (重量)；一种含金属树脂，通过将该溶解混合物中的含金属单体 (A) 与另一种可自由基聚合的不饱和单体 (B) 共聚而获得；一种防污漆组合物，通过使用该含金属树脂而获得；以及一种防污漆组合物，包括二价含金属树脂 (C)、R1-SH 的化合物 (D) (其中，R1 代表具有 1 至 30 个碳原子的有机基团。) 和氧化铜 (E)。
• POLISHING COMPOUND COMPOSITION, METHOD FOR PRODUCING SAME AND POLISHING METHOD
  申请人：Seimi Chemical Co., Ltd.

  公开号：EP1544901A1

  公开（公告）日：2005-06-22

  A polishing compound for chemical mechanical polishing of a substrate, which comprises (A) abrasive grains, (B) an aqueous medium, (C) tartaric acid, (D) trishydroxymethylaminomethane and (E) at least one member selected from the group consisting of malonic acid and maleic acid, and more preferably, which further contains a compound having a function to form a protective film on the wiring metal surface to prevent dishing at the wiring metal portion, such as benzotriazole. By use of this polishing compound, the copper wirings on the surface of a semiconductor integrated circuit board can be polished at a high removal rate while suppressing formation of scars as defects in a polishing step. Particularly in a first polishing step of polishing copper wirings having a film made of tantalum or a tantalum compound as a barrier film, excellent selectivity will be obtained, dishing and erosion due to polishing are less likely to occur, and an extremely high precision flat surface of a semiconductor integrated circuit board can be obtained.

  一种用于基板化学机械抛光的抛光剂，它包括（A）磨粒、（B）水介质、（C）酒石酸、（D）三羟甲基氨基甲烷和（E）至少一种从丙二酸和马来酸组成的组中选出的成员，更优选的是，它还含有一种化合物，具有在布线金属表面形成保护膜的功能，以防止布线金属部分的剥离，如苯并三唑。通过使用这种抛光剂，半导体集成电路板表面的铜配线可以以较高的去除率进行抛光，同时在抛光步骤中抑制作为缺陷的疤痕的形成。特别是在抛光铜导线的第一道抛光步骤中，如果铜导线上有一层由钽或钽化合物制成的薄膜作为阻挡膜，则可获得极佳的选择性，不易发生因抛光而造成的分层和侵蚀，并可获得半导体集成电路板的极高精度的平整表面。
• METHOD FOR PRODUCING RESIN DISPERSION FOR ANTIFOULING COATING
  申请人：Mitsubishi Rayon Co., Ltd.

  公开号：EP2520620A1

  公开（公告）日：2012-11-07

  It is an object of the present invention to provide an antifouling coating resin dispersion which has excellent storage stability and water resistance in sea water, can exhibit an antifouling effect over a long period of time, and has self-polishing properties with excellent adhesiveness. A method for producing the antifouling coating resin dispersion according to the present invention includes the steps of: producing a polymer (A) containing a divalent metal; and dispersing the polymer (A) in a dispersion medium containing water or a mixture of water and an organic solvent. The polymer (A) containing a divalent metal is obtained by subjecting 1 to 40% by mass of a divalent-metal-containing ethylenically unsaturated monomer (a1), 0 to 8% by mass of a carboxyl-group-containing ethylenically unsaturated monomer (a2), 0 to 40% by mass of a hydroxyl-group-containing ethylenically unsaturated monomer (a3), and 99 to 22% by mass of another ethylenically unsaturated monomer (a4) to solution polymerization in a multi-stage which includes two or more stages.

  本发明的目的是提供一种防污涂料树脂分散体，该分散体在海水中具有优异的贮存稳定性和耐水性，可长期显示防污效果，并具有自抛光性能和优异的粘附性。根据本发明生产防污涂料树脂分散体的方法包括以下步骤：生产含有二价金属的聚合物（A）；将聚合物（A）分散在含有水或水与有机溶剂混合物的分散介质中。含二价金属的聚合物(A)是通过以下方法获得的：1-40%（质量）的含二价金属的乙烯基不饱和单体(a1)，0-8%（质量）的含羧基的乙烯基不饱和单体(a2)、0 至 40%（质量百分比）的含羟基的乙烯基不饱和单体（a3）和 99 至 22%（质量 百分比）的另一种乙烯基不饱和单体（a4）进行溶液聚合。