[cyclopenta-2,4-dien-1-yl(hydroxymethyl)phosphanyl]methanol;iron(2+) | 406462-26-8

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: [cyclopenta-2,4-dien-1-yl(hydroxymethyl)phosphanyl]methanol;iron(2+)
• CAS: 406462-26-8
• 化学式: C₁₄H₂₀FeO₄P₂
• 分子量: 370.105
• InChiKey: MROMOBHEPGSSPC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  selenium 、 [cyclopenta-2,4-dien-1-yl(hydroxymethyl)phosphanyl]methanol;iron(2+) 以 甲醇 为溶剂， 以48%的产率得到[cyclopenta-2,4-dien-1-yl(hydroxymethyl)phosphinoselenoyl]methanol;iron(2+)
  参考文献：
  名称：

  Ferrocenyl hydroxymethylphosphines (η5-C5H5)Fe[η5-C5H4P(CH2OH)2] and 1,1′-[Fe{η5-C5H4P(CH2OH)2}2] and their chalcogenide derivatives

  摘要：

  The ferrocenyl hydroxymethylphosphines FcP(CH2OH)(2) [Fc = (eta(5)-C5H5)Fe(eta(5)-C5H4)] and 1,1'-Fc'[P(CH2OH)(2)](2) [Fc' = Fe(eta(5)- C5H4)(2)] were prepared by reactions of the corresponding primary phosphines FcPH(2) and 1,1'-Fc'(PH2)(2) with excess aqueous formaldehyde. The crystal structure of FcP(CH2OH)(2) was determined and compared with the known ferrocenyl hydroxymethylphosphine FcCH(2)P(CH2OH)(2). The chalcogenide derivatives FcP(E)(CH2OH)(2) and 1,1'-Fc'[P(E)(CH2OH)(2)](2) (E = O, S, Se) were prepared and fully characterised. Crystal structure determinations on FcP(O)(CH2OH)(2) and FcP(S)(CH2OH)(2) were performed, and the hydrogen-bonding patterns are compared with related compounds. The sulfide shows no hydrogen-bonding involving the phosphine sulfide group, in contrast to other reported ferrocenyl hydroxymethylphosphine sulfides. The platinum complex cis-[PtCl2{FcP(CH2OH)(2)}(2)] was prepared by reaction of 2 mol equivalents of FcP(CH2OH)(2) with [PtCl2(1,5-cyclo-octadiene)], and was characterised by P-31-NMR spectroscopy and negative ion electrospray mass spectrometry, which gave a strong [M+Cl](-) ion. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01651-0
• 作为产物：
  描述：

  聚合甲醛 、 1,1'-bis(phosphine)ferrocene 以 四氢呋喃 、 水 为溶剂， 以98%的产率得到[cyclopenta-2,4-dien-1-yl(hydroxymethyl)phosphanyl]methanol;iron(2+)
  参考文献：
  名称：

  Ferrocenyl hydroxymethylphosphines (η5-C5H5)Fe[η5-C5H4P(CH2OH)2] and 1,1′-[Fe{η5-C5H4P(CH2OH)2}2] and their chalcogenide derivatives

  摘要：

  The ferrocenyl hydroxymethylphosphines FcP(CH2OH)(2) [Fc = (eta(5)-C5H5)Fe(eta(5)-C5H4)] and 1,1'-Fc'[P(CH2OH)(2)](2) [Fc' = Fe(eta(5)- C5H4)(2)] were prepared by reactions of the corresponding primary phosphines FcPH(2) and 1,1'-Fc'(PH2)(2) with excess aqueous formaldehyde. The crystal structure of FcP(CH2OH)(2) was determined and compared with the known ferrocenyl hydroxymethylphosphine FcCH(2)P(CH2OH)(2). The chalcogenide derivatives FcP(E)(CH2OH)(2) and 1,1'-Fc'[P(E)(CH2OH)(2)](2) (E = O, S, Se) were prepared and fully characterised. Crystal structure determinations on FcP(O)(CH2OH)(2) and FcP(S)(CH2OH)(2) were performed, and the hydrogen-bonding patterns are compared with related compounds. The sulfide shows no hydrogen-bonding involving the phosphine sulfide group, in contrast to other reported ferrocenyl hydroxymethylphosphine sulfides. The platinum complex cis-[PtCl2{FcP(CH2OH)(2)}(2)] was prepared by reaction of 2 mol equivalents of FcP(CH2OH)(2) with [PtCl2(1,5-cyclo-octadiene)], and was characterised by P-31-NMR spectroscopy and negative ion electrospray mass spectrometry, which gave a strong [M+Cl](-) ion. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01651-0