[Mn(salicylideneglycine(-2H))(bis(benzylidene)ethylenediamine)(H2O)] | 798573-19-0

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: [Mn(salicylideneglycine(-2H))(bis(benzylidene)ethylenediamine)(H2O)]
• 英文别名: [Mn(salgy(-2H))(benen)(H2O)]
• CAS: 798573-19-0
• 化学式: C₂₅H₂₅MnN₃O₄
• 分子量: 486.429
• InChiKey: DKYLSEXZHNDSHO-RBOCZMIQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Mn(salicylideneglycine(-2H))(bis(benzylidene)ethylenediamine)(H2O)] 以 neat (no solvent) 为溶剂， 生成 水合锰
  参考文献：
  名称：

  Preparation and Thermal, Spectroscopic, and Antibacterial Studies of Some Mixed‐Ligand Complexes

  摘要：

  The present investigation reports the synthesis, characterization, and antibacterial activities of some mixed-ligand complexes of the type [ML(SB)H2O], where M = Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Cd(II), SB1 = bis(benzylidene)ethylenediatmine (benen) or SB2 = bis(acetophenone)ethylenediamine (acphen) and KHL = potassium salt of salicylideneglycine (salgly). Their structures have been elucidated on the basis of elemental analyses, thermogravimetric analyses, magnetic measurements, reflectance spectra, and IR spectra. The results are in accord with an octahedral environment around the central metal ion. The mixed-ligand complexes of Mn(II), Co(II), Ni(II), and Cu(II) are paramagnetic while the Zn(II) and Cd(H) complexes are diamagnetic. The mixed-ligand complexes have been tested against bacteria and the results are compared with a standard drug (tetracycline) and control (dimethyl sulfoxide).

  DOI：

  10.1081/sim-120039268
• 作为产物：
  描述：

  manganese(II) chloride tetrahydrate 、 N,N-双(苯基亚甲基)-1,2-乙二胺 、 水 、 potassium 2-((2-hydroxybenzylidene)amino)acetate 以 甲醇 、 水 为溶剂， 以35%的产率得到[Mn(salicylideneglycine(-2H))(bis(benzylidene)ethylenediamine)(H2O)]
  参考文献：
  名称：

  Preparation and Thermal, Spectroscopic, and Antibacterial Studies of Some Mixed‐Ligand Complexes

  摘要：

  The present investigation reports the synthesis, characterization, and antibacterial activities of some mixed-ligand complexes of the type [ML(SB)H2O], where M = Mn(II), Co(II), Ni(II), Cu(II), Zn(II), and Cd(II), SB1 = bis(benzylidene)ethylenediatmine (benen) or SB2 = bis(acetophenone)ethylenediamine (acphen) and KHL = potassium salt of salicylideneglycine (salgly). Their structures have been elucidated on the basis of elemental analyses, thermogravimetric analyses, magnetic measurements, reflectance spectra, and IR spectra. The results are in accord with an octahedral environment around the central metal ion. The mixed-ligand complexes of Mn(II), Co(II), Ni(II), and Cu(II) are paramagnetic while the Zn(II) and Cd(H) complexes are diamagnetic. The mixed-ligand complexes have been tested against bacteria and the results are compared with a standard drug (tetracycline) and control (dimethyl sulfoxide).

  DOI：

  10.1081/sim-120039268