| 1309666-51-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1309666-51-0
• 化学式: C₁₆H₁₄O₃
• 分子量: 254.285
• InChiKey: GDIQYRIQWDIXFS-HNNXBMFYSA-N

反应信息

• 作为产物：
  描述：

  3-(2-hydroxy-4-methoxyphenyl)-1-(phenyl)propan-1-one 在 C₄₄H₃₂N⁽¹⁺⁾*I^(1-) 、 双氧水 、 sodium dodecyl-sulfate 作用下， 以 水 、 甲苯 为溶剂， 反应 1.0h， 以99%的产率得到
  参考文献：
  名称：

  Enantioselective Cycloetherification in a Micellar Catalysis System

  摘要：

  The enantioselective cycloetherification of substituted keto phenols into their corresponding dihydrobenzofuran derivatives was carried out using hydrogen peroxide and chiral quaternary ammonium iodide in micellar media. This approach increased the conversion rate of cycloetherification and also widened the scope of this particular reaction for various substituted keto phenols with electron withdrawing as well as electron donating functionalities. The use of a surfactant in the cycloetherification reaction increased the yield of the corresponding enantioselective dihydrobenzofuran four times. The conversion rate of keto phenols into their corresponding dihydrobcnzofuran derivatives was proportional to the concentration of the surfactant used in the reaction.

  DOI：

  10.1016/s1872-2067(10)60169-6