9-phenyl-N-(4-methylphenyl)-9H-carbazole-3-amine | 1002762-74-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 9-phenyl-N-(4-methylphenyl)-9H-carbazole-3-amine
• 英文别名: 9-phenyl-N-(p-tolyl)-9H-carbazol-3-amine；N-(4-methylphenyl)-9-phenylcarbazol-3-amine
• CAS: 1002762-74-4
• 化学式: C₂₅H₂₀N₂
• 分子量: 348.447
• InChiKey: ZKWNVHPZTUAEGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  27
• 可旋转键数：
  3
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.04
• 拓扑面积：
  17
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  9-phenyl-N-(4-methylphenyl)-9H-carbazole-3-amine 、 4-溴-4'-碘联苯 在 copper(l) iodide 、 18-冠醚-6 、 三叔丁基膦 、 palladium diacetate 、 potassium carbonate 、 sodium t-butanolate 作用下， 以 N,N-二甲基乙酰胺 、 甲苯 为溶剂， 反应 72.0h， 生成
  参考文献：
  名称：

  三芳胺类衍生物及其制备方法、应用和器件

  摘要：

  本发明属于光电材料应用科技技术领域，具体涉及三芳胺类衍生物及其制备方法和应用。本发明所提供的三芳胺类衍生物，以三芳胺与芴并咔唑为基本结构单元，进行修饰后得到不对称结构，构成一类富含空穴并具有高玻璃化温度的化合物。当其作为空穴传输材料使用时，与现有技术中常用的空穴传输材料如N,N'‑二苯基‑N,N'‑二(3‑甲基苯基)‑1,1'‑联苯‑4,4'‑二胺(TPD)相比较，空穴传输能力有明显提高，在有机电致发光器件中，该系列化合物与传统的空穴传输材料相比在启动电压及玻璃化温度方面都有显著的提高，是理想的空穴传输材料。此外，该系列化合物作为出光层材料使用时，有机电致发光器件的效率大幅度提高，是理想的出光层材料。

  公开号：

  CN109970623B
• 作为产物：
  描述：

  p-叠氮甲苯 、 N-苯基-3-咔唑硼酸 在 nickel(II) triflate 、 fac-tris(2-phenylpyridinato-N,C2')iridium(III) 、 1,10-菲罗啉 、 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 四氢呋喃 为溶剂， 以38 %的产率得到9-phenyl-N-(4-methylphenyl)-9H-carbazole-3-amine
  参考文献：
  名称：

  芳基叠氮化物和芳基硼​​酸的镍/光氧化还原双催化 Chan-Lam 偶联

  摘要：

  不对称二芳基胺是许多药物和功能材料的关键成分。在这项研究中，我们介绍了一种有效的 Chan-Lam 交叉偶联方法，该方法在氧化还原中性环境中利用苯基硼酸和芳基叠氮化物作为偶联剂，并通过协同镍/光氧化还原催化系统实现。该方法利用质子耦合电子转移机制绕过与芳基叠氮化物相关的典型氮烯途径，该途径容易发生分子内重排、CH胺化和还原氢化。值得注意的是，我们的方法与各种官能团（包括源自药物的官能团）表现出广泛的兼容性，证明了其在有机合成和药物修饰方面的多功能潜力。

  DOI：

  10.1002/cjoc.202400276

文献信息

• ORGANIC COMPOUND, ANTHRACENE DERIVATIVE, AND LIGHT-EMITTING ELEMENTS, LIGHT-EMITTING DEVICES, ELECTRONIC DEVICES, AND LIGHTING DEVICES USING THE ANTHRACENE DERIVATIVE
  申请人：OGITA Kaori

  公开号：US20100156957A1

  公开（公告）日：2010-06-24

  To provide a novel anthracene derivative which exhibit blue to blue green light emission, provide a light-emitting element which emits blue to blue green light, provide a light-emitting element which emits blue to blue green light with a long lifetime, and provide a light-emitting element which emits blue to blue green light with high emission efficiency, an anthracene derivative represented by General Formula (G1) is provided. In addition, a light-emitting element which emits blue to blue green light can be obtained by using the anthracene derivatives represented by General Formula (G1). Further, a light-emitting element which emits blue to blue green light with high emission efficiency and/or high reliability can be obtained by using the anthracene derivatives represented by General Formula (G1).

  提供一种新型蒽衍生物，其具有蓝色至蓝绿色光发射特性，提供一种发射蓝色至蓝绿色光的发光元件，提供一种具有长寿命的发射蓝色至蓝绿色光的发光元件，以及提供一种具有高发射效率的发射蓝色至蓝绿色光的发光元件，其中提供一种由通式（G1）表示的蒽衍生物。此外，使用通式（G1）表示的蒽衍生物可以获得发射蓝色至蓝绿色光的发光元件。进一步地，使用通式（G1）表示的蒽衍生物可以获得具有高发射效率和/或高可靠性的发射蓝色至蓝绿色光的发光元件。
• Compound for forming organic film, and organic light emitting device and flat panel display device including the same
  申请人：Samsung Mobile Display Co., Ltd.

  公开号：EP2093271A1

  公开（公告）日：2009-08-26

  A compound for use in an organic light emitting device is represented by Formula 1 The compound has excellent electrical properties and charge transporting characteristics, and is therefore useful as a material for a hole injection layer, a hole transport layer, and an emission layer of phosphorescent and fluorescent devices for emitting light of all colors, including red, green, blue, and white. Organic light emitting devices using the compounds have high efficiency, low driving voltages, and high brightness.

  一种用于有机发光器件的化合物由式 1 表示 该化合物具有优异的电性能和电荷传输特性，因此可用作磷光和荧光器件的空穴注入层、空穴传输层和发射层的材料，用于发射包括红、绿、蓝和白在内的各种颜色的光。使用这些化合物的有机发光器件效率高、驱动电压低、亮度高。
• Silanylamine-based compound, method of preparing the same and organic light emitting device including organic layer comprising the silanylamine-based compound
  申请人：Samsung Mobile Display Co., Ltd.

  公开号：EP1921082B1

  公开（公告）日：2010-04-14
• SILANYLAMINE-BASED COMPOUND, METHOD OF PREPARING THE SAME AND ORGANIC LIGHT EMITTING DEVICE INCLUDING ORGANIC LAYER COMPRISING THE SILANYLAMINE-BASED COMPOUND
  申请人：Hwang Seok-Hwan

  公开号：US20080106188A1

  公开（公告）日：2008-05-08

  Silanylamine-based compounds represented by Formula 1 are provided. Methods of preparing the compounds and organic light emitting devices including organic layers comprising the silanylamine-based compounds are also provided. The silanylamine-based compounds have excellent electrical stability and electron transporting capabilities. Thus, the silanylamine-based compounds may be effectively used for red, green, blue, and white fluorescent and phosphorescent materials used to form hole injection layers, hole transport layers, and emissive layers in organic light emitting devices. Organic light emitting devices using these compounds have high efficiency, low driving voltages, high luminance and long lifetimes.
• COMPOUND FOR FORMING ORGANIC FILM, AND ORGANIC LIGHT EMITTING DEVICE AND FLAT PANEL DISPLAY DEVICE INCLUDING THE SAME
  申请人：Hwang Seok-Hwan

  公开号：US20090200928A1

  公开（公告）日：2009-08-13

  A compound for use in an organic light emitting device is represented by The compound has excellent electrical properties and charge transporting characteristics, and is therefore useful as a material for a hole injection layer, a hole transport layer, and an emission layer of phosphorescent and fluorescent devices for emitting light of all colors, including red, green, blue, and white. Organic light emitting devices using the compounds have high efficiency, low driving voltages, and high brightness.