17-(4-methoxyphenoxy)-3,6,9,12,15-pentaoxaheptadecan-1-ol | 1123221-87-3

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 17-(4-methoxyphenoxy)-3,6,9,12,15-pentaoxaheptadecan-1-ol
• CAS: 1123221-87-3
• 化学式: C₁₉H₃₂O₈
• 分子量: 388.458
• InChiKey: UAOTVPFYBNDRAU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.15
• 重原子数：
  27.0
• 可旋转键数：
  19.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.68
• 拓扑面积：
  84.84
• 氢给体数：
  1.0
• 氢受体数：
  8.0

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 17-(4-methoxyphenoxy)-3,6,9,12,15-pentaoxaheptadecan-1-ol 、 溶剂黄146 在 硫酸 、 sodium bromide 作用下， 反应 360.0h， 以44%的产率得到
  参考文献：
  名称：

  Highly Uniaxial Orientation in Oligo(p-phenylenevinylene) Films Induced During Wet-Coating Process

  摘要：

  Highly uniaxial alignment of pi-conjugated oligo(p-phenylenevinylene)s was spontaneously achieved in the as-cast films by simply spin-coating the solution onto mechanically rubbed polymer alignment layers such as poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonic acid) (PEDOT:PSS) film, resulting in a high dichroic ratio (A(//)/A(perpendicular to)) of 41.0 and an order parameter ([A(//) - A(perpendicular to)]/[A(//) + 2A(perpendicular to)]) of 0.93 estimated from the polarized absorption spectra of the films, and its application to organic photovoltaic devices was also demonstrated to achieve a high anisotropy in photosensitivity.

  DOI：

  10.1021/ja810123b
• 作为产物：
  描述：

  toluene-4-sulfonic acid 2-[2-(2-{2-[2-(2-hydroxy-ethoxy)-ethoxy]-ethoxy}-ethoxy)-ethoxy]-ethyl ester 、 4-甲氧基苯酚 在 18-冠醚-6 、 potassium carbonate 作用下， 以 乙腈 为溶剂， 反应 24.0h， 以83%的产率得到17-(4-methoxyphenoxy)-3,6,9,12,15-pentaoxaheptadecan-1-ol
  参考文献：
  名称：

  Highly Uniaxial Orientation in Oligo(p-phenylenevinylene) Films Induced During Wet-Coating Process

  摘要：

  Highly uniaxial alignment of pi-conjugated oligo(p-phenylenevinylene)s was spontaneously achieved in the as-cast films by simply spin-coating the solution onto mechanically rubbed polymer alignment layers such as poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonic acid) (PEDOT:PSS) film, resulting in a high dichroic ratio (A(//)/A(perpendicular to)) of 41.0 and an order parameter ([A(//) - A(perpendicular to)]/[A(//) + 2A(perpendicular to)]) of 0.93 estimated from the polarized absorption spectra of the films, and its application to organic photovoltaic devices was also demonstrated to achieve a high anisotropy in photosensitivity.

  DOI：

  10.1021/ja810123b