| 1129430-29-0

• 分子结构分类: 有机化合物 - 有机氧化合物
• CAS: 1129430-29-0
• 化学式: C₁₂H₁₆O₂
• 分子量: 192.258
• InChiKey: VQFHMMNYBNZAEN-SNAWJCMRSA-N

物化性质

• 沸点：
  327.8±22.0 °C(predicted)
• 密度：
  1.058±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为产物：
  描述：

  巴豆醛 、 5,5-二甲基-1,3-环己二酮 在 L-脯氨酸 作用下， 反应 0.17h， 以81%的产率得到
  参考文献：
  名称：

  Efficient organocatalyzed solvent-free selective synthesis of conjugated enones

  摘要：

  A series of conjugated dienones and enones were synthesized by a reaction of both conjugated and simple aldehydes, respectively, with 1,3-dicarbonyl compounds. and aldehydes Under solvent-free conditions at room temperature in the presence of 10 mol % of L-profine as catalyst. The selective formation of one isomer was, observed exclusively with most of the 1,3-dicarbonyl compounds and aldehydes. The most commonly formed xanthene derivative from the cyclic diketones is inhibited with our protocol, with the exclusive formation of conjugated dienones only. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.12.036