[Ni(N,N-dipentyldithiocarbamate)(1,10-phenanthroline)2]ClO4 | 1008532-76-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: [Ni(N,N-dipentyldithiocarbamate)(1,10-phenanthroline)2]ClO4
• 英文别名: [Ni(Pe2dtc)(phen)2]ClO4
• CAS: 1008532-76-0
• 化学式: C₃₅H₃₈N₅NiS₂*ClO₄
• 分子量: 750.993
• InChiKey: JOOIXUDWLZLXLP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,10-菲罗啉 、 lithium perchlorate trihydrate 、 [Ni(N,N-dipentyldithiocarbamato)2] 以 甲醇 为溶剂， 以81%的产率得到[Ni(N,N-dipentyldithiocarbamate)(1,10-phenanthroline)2]ClO4
  参考文献：
  名称：

  Novel octahedral nickel(II) dithiocarbamates with bi- or tetradentate N-donor ligands: X-ray structures of [Ni(Bzppzdtc)(phen)2]ClO4· CHCl3 and [Ni(Bz2dtc)2(cyclam)]

  摘要：

  A series of novel octahedral nickel(II) dithiocarbamate complexes involving bidentate nitrogen-donor ligands (phen = 1, 10-phenanthroline, bpy = 2,2'-bipyridine) or a tetradentate ligand (cyclam = 1,4,8,11-tetraazacycloteradecane) of the composition [Ni(BzMetdtc)(phen)(2)]ClO(4) (1), [Ni(Pe(2)dtc)(phen)(2)]ClO(4) (2), [Ni(Bzppzdtc)(phen)(2)]ClO(4) center dot CHCl(3) (3), [Ni(Bzppzdtc)(phen)(2)](SCN) (4), [Ni(BzMetdtc)(bpy)(2)]ClO(4) center dot 2H(2)O (5), [Ni(Pe(2)dtc)(cyclam)]ClO(4) (6), [Ni(BzMetdtC)(2)(cyclam)] (7), [Ni(Bz(2)dtC)(2)(cyclam)] (8) and [Ni(Bz(2)dtC)(2)(phen)] (9) (BzMetdtc = N,N-benzyl-methyldithiocarbamate(1-) anion, Pe(2)dtc = N,N-dipentyldithiocarbamate(1-) anion, Bz(2)dtc = N,N-dibenzyldithiocarbamate(1-) anion, Bzppzdtc = 4-benzylpiperazinedithiocarbamate(1-) anion), have been synthesized. Spectroscopic (electronic and infrared), magnetic moment and molar conductivity data, and thermal behaviour of the complexes are discussed. Single crystal X-ray analysis of 3 and 8 confirmed a distorted octahedral arrangement in the vicinity of the nickel atom with a N(4)S(2) donor set. They represent the first X-ray structures of such type complexes. The catalytic influence of complexes 2, 3, 6, and 7 on graphite oxidation was studied and discussed. (C) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.09.024