2e,6e-di(p-chlorobenzoyl)-4,4-dicyano-3e,5e-di(p-methylphenyl)thiane | 1214885-11-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2e,6e-di(p-chlorobenzoyl)-4,4-dicyano-3e,5e-di(p-methylphenyl)thiane
• CAS: 1214885-11-6
• 化学式: C₃₅H₂₆Cl₂N₂O₂S
• 分子量: 609.576
• InChiKey: CAZRIXGDEYGLIU-JDYLGNGMSA-N

反应信息

• 作为产物：
  描述：

  1-(4-chlorophenyl)-2-[3-(4-chlorophenyl)-1-(4-methylphenyl)-3-oxoprop-1-en-2-yl]sulfanyl-3-(4-methylphenyl)prop-2-en-1-one 、 丙二腈 在 sodium ethanolate 作用下， 反应 0.08h， 以92%的产率得到2e,6e-di(p-chlorobenzoyl)-4,4-dicyano-3e,5e-di(p-methylphenyl)thiane
  参考文献：
  名称：

  A Diastereoselective Synthesis of Novel Multifunctional Thianes

  摘要：

  The reaction of 2,2'-thiobis(1,3-diarylprop-2-en-1-ones) with malononitrile in the presence of sodium ethoxide under both thermal and solvent-free microwave conditions afforded a series of hitherto unknown 2e, 6e-diaroyl-3e,5e-diaryl-4,4-dicyanothianes diastereoselectively in good yields via a double Michael addition. The structures of all the compounds have been elucidated by IR, (1)H NMR, (13)C NMR, and elemental analysis.

  DOI：

  10.1080/10426500802625727